Pentadecane functionalized graphite oxide sheets as a tool for the preparation of electrical conductive polyethylene/graphite oxide composites

Covalent functionalization of pentadecane-decorated thermally reduced graphite oxide (GO) sheets has been studied as a tool for the preparation of polyethylene/GO composites exhibiting rheological and electrical percolation thresholds. It was accomplished through pentadecane based radical addition onto unsaturated bonds located on the GO sheets' surface using dicumyl peroxide as hydrogen abstractor. This chemical functionalization influences the affinity of the formed pentadecane grafted GO sheets for various solvents. Then, the compounding of the composites pentadecane grafted GO/PE was performed at a processing temperature of 140 °C with 25, 20, 15, 10, 8 and 5 wt% loadings. Rheological and electrical percolation thresholds were found between 10 and 15 wt% for polyethylene/pentadecane functionalized graphene oxide composites while the composite graphite/PE at the same loading percentage did not reach any percolation threshold.     

Defect structure evolution and electrical properties of BaTiO3-based ferroelectric ceramics

Relaxor perovskite ferroelectric 0.1Bi(Zn_1/2Zr_1/2)O₃-0.9BaTiO₃(0.1BZZ-0.9BT) ceramics were successfully prepared, whose powders synthesized by the sol-gel process, with average grain size about 1.29 μm. 1.75 J/cm³ discharge energy density and good dielectric stability were obtained over a wide temperature range from 25°C to 140°C. The pulse discharge capability of 0.1BZZ-0.9BT ceramics was tested under different electric fields. The discharge time was 2.13 μs, which proved its ability to charge and discharge quickly. Complex impedance analysis and thermally stimulated depolarization current tests were applied to investigate the defect types and activation of 0.1BZZ-0.9BT ceramics. The evolution process of composite defects and oxygen vacancies profoundly affects the dielectric temperature stability of 0.1BZZ-0.9BT ceramics’ energy storage property.     

Polysilazane derived micro/nano Si3N4/SiC composites

The pyrolised polysilazanes poly(hydridomethyl)silazane NCP 200 and poly(urea)silazane CERASET derived Si–C–N amorphous powders were used for preparation of micro/nano Si₃N₄/SiC composites by hot pressing. Y₂O₃–Al₂O₃ and Y₂O₃–Yb₂O₃ were used, as sintering aids. The resulting ceramic composites of all compositions were dense and polycrystalline with fine microstructure of average grain size <1 μm of both Si₃N₄ and SiC phases. The fine SiC nano-inclusions were identified within the Si₃N₄ micrograins. Phase composition of both composites consist of , β modifications of Si₃N₄ and SiC. High weight loss was observed during the hot pressing cycle, 12 and 19 wt.% for NCP 200 and CERASET precursors, respectively. The fracture toughness of both nanocomposites (NCP 2000 and CERASET derived) was not different. Indentation method measured values are from 5 to 6 MPa m^1/2, with respect to the sintering additive system. Fracture toughness is slightly sensitive to the SiC content of the nanocomposite. Hardness increases with the content of SiC in the nanocomposite. The highest hardness was achieved for pyrolysed CERASET precursor with 2 wt.% Y₂O₃ and 6 wt.% Yb₂O₃, HV 23 GPa. This is a consequence of the highest SiC content as well as the chemical composition of additives.     

Extraction of oleic acid from soybean oil and jojoba oil-phase diagrams

Formamide,N-methylformamide,N-dimethylformamide, dimethylsulfoxide, 1,2-butanediol, and 2-butane-1,4-diol were considered as potential extractants of fatty acids from soybean and jojoba oils. Ternary liquid-liquid phase diagrams at 298.15 K, distribution, and selectivity coefficients of oleic acid are reported. Of the investigated solvents, onlyN-methylformamide and 1,2-butanediol have desirable extraction characteristics.     

An end‐to‐end alternative to TCP PEPs: Initial Spreading,a TCP fast start‐up mechanism

While Transmission Control Protocol (TCP) Performance Enhancing Proxy (PEP) solutions have long been undisputed to solve the inherent satellite problems, the improvement of the regular end‐to‐end TCP congestion avoidance algorithms and the recent emphasis on the PEPs drawbacks have opened the question of the PEPs sustainability. Nevertheless, with a vast majority of Internet connections shorter than ten segments, TCP PEPs continue to be required to counter the poor efficiency of the end‐to‐end TCP start‐up mechanisms. To reduce the PEPs dependency, designing a new fast start‐up TCP mechanism is therefore a major concern. But, while enlarging the Initial Window (IW) up to ten segments is, without any doubt, the fastest solution to deal with a short‐lived connection in an uncongested network, numerous researchers are concerned about the impact of the large initial burst on an already congested network. Based on traffic observations and real experiments, Initial Spreading has been designed to remove those concerns whatever the load and type of networks. It offers performance similar to a large IW in uncongested network and outperforms existing end‐to‐end solutions in congested networks. In this paper, we show that Initial Spreading, taking care of the satellite specificities, is an efficient end‐to‐end alternative to the TCP PEPs. Copyright © 2015 John Wiley & Sons, Ltd.     

Zr‐Doped Indium Oxide (IZRO) Transparent Electrodes for Perovskite‐Based Tandem Solar Cells

Parasitic absorption in transparent electrodes is one of the main roadblocks to enabling power conversion efficiencies (PCEs) for perovskite‐based tandem solar cells beyond 30%. To reduce such losses and maximize light coupling, the broadband transparency of such electrodes should be improved, especially at the front of the device. Here, the excellent properties of Zr‐doped indium oxide (IZRO) transparent electrodes for such applications, with improved near‐infrared (NIR) response, compared to conventional tin‐doped indium oxide (ITO) electrodes, are shown. Optimized IZRO films feature a very high electron mobility (up to ≈77 cm² V^?1 s^?1), enabling highly infrared transparent films with a very low sheet resistance (≈18 Ω □^?1 for annealed 100 nm films). For devices, this translates in a parasitic absorption of only ≈5% for IZRO within the solar spectrum (250–2500 nm range), to be compared with ≈10% for commercial ITO. Fundamentally, it is found that the high conductivity of annealed IZRO films is directly linked to promoted crystallinity of the indium oxide (In₂O₃) films due to Zr‐doping. Overall, on a four‐terminal perovskite/silicon tandem device level, an absolute 3.5 mA cm^?2 short‐circuit current improvement in silicon bottom cells is obtained by replacing commercial ITO electrodes with IZRO, resulting in improving the PCE from 23.3% to 26.2%.     

Dark matter searches with H.E.S.S.

WIMP annihilations are required to reproduce the correct dark matter abundance in the Universe. This process can occur in dense regions of our Galaxy such as the Galactic center, dwarf galaxies and other types of sub-haloes. High-energy γ-rays are produced in dark matter particle collisions and can be detected by Cherenkov telescopes such as H.E.S.S. We report here the search for γ-ray signals from the Galactic center and the nearby Sagittarius and Canis Major satellites. In the absence of a convincing signal, modelling the dark matter density within these objects allows to put constraints on the WIMP parameters such as its mass and annihilation cross-section. Beyond these targeted searches, the wide-field survey of the inner Galaxy with H.E.S.S. is used to constrain sub-halo formation models involving intermediate-mass black holes.     

DLTS study of the influence of annealing on deep level defects induced in xenon ions implanted n-type 4H-SiC

In this study, nitrogen-doped 4H-SiC samples were bombarded with 167 MeV xenon ions to a fluence of 1?×?10⁸ cm^?2 at 300 K prior to the fabrication of Schottky barrier diodes. The implanted samples were annealed at approximately 900 °C for 1 h before the resistive evaporation of nickel Schottky barrier diodes. In comparing the current–voltage results of the implanted devices with as-deposited ones, generation-recombination took place in the implanted Schottky barrier diodes. Four defects (100, 120, 170, and 650 meV) were present in as-deposited Schottky barrier diodes when characterized by deep level transient spectroscopy (DLTS). In addition to the defects observed in the as-deposited samples, two additional defects with activation energies of 400 and 700 meV below the conduction band minimum were induced by Xe ions implantation. The two deep level defects present have signatures similar to defects present after irradiated by MeV electron. The two defects present after irradiation disappeared after annealing at 400 °C which indicate instability of the defects after annealing implanted samples.

     

A Highly Efficient Algorithm for Phased-Array mmWave Massive MIMO Beamforming

With the rapid development of the mobile internet and the internet of things (IoT), the fifth generation (5G) mobile communication system is seeing explosive growth in data traffic. In addition, low-frequency spectrum resources are becoming increasingly scarce and there is now an urgent need to switch to higher frequency bands. Millimeter wave (mmWave) technology has several outstanding features—it is one of the most well-known 5G technologies and has the capacity to fulfil many of the requirements of future wireless networks. Importantly, it has an abundant resource spectrum, which can significantly increase the communication rate of a mobile communication system. As such, it is now considered a key technology for future mobile communications. MmWave communication technology also has a more open network architecture; it can deliver varied services and be applied in many scenarios. By contrast, traditional, all-digital precoding systems have the drawbacks of high computational complexity and higher power consumption. This paper examines the implementation of a new hybrid precoding system that significantly reduces both calculational complexity and energy consumption. The primary idea is to generate several sub-channels with equal gain by dividing the channel by the geometric mean decomposition (GMD). In this process, the objective function of the spectral efficiency is derived, then the basic tracking principle and least square (LS) techniques are deployed to design the proposed hybrid precoding. Simulation results show that the proposed algorithm significantly improves system performance and reduces computational complexity by more than 45% compared to traditional algorithms.