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991.
992.
Liang Xu Lei Su Hongjie Wang Min Niu Lei Zhuang Kang Peng Xingyu Fan Hongfei Gao De Lu 《Journal of the American Ceramic Society》2022,105(8):5490-5500
Pursuing novel thermal barrier–coating materials with lower thermal conductivity and high-temperature stability can simultaneously improve the working efficiency and service temperature of a gas turbine. In this study, a series of high-entropy RE2(Y0.2Yb0.2Nb0.2Ta0.2Ce0.2)2O7 (RE = La, Nd, Sm, Gd, Dy, and Er) oxides were prepared though solid-state reaction. Through tuning the rare-earth cations, an order–disorder transition occurs from certain partially ordered weberite structure (C2221) to disordered defective fluorite structure (Fm m). All the high-entropy RE2(Y0.2Yb0.2Nb0.2Ta0.2Ce0.2)2O7 oxides possess low thermal conductivity in the range of 0.91–1.34 W m−1 K−1 at room temperature, which can be attributed to increased lattice anharmonicity and disorder, resulting in additional phonon scattering. Herein, we proved that the incorporation of heterovalent cations at B-sites in high-entropy A2B2O7 crystals is an effective strategy to reduce the thermal conductivity without compromising the decrease of oxygen vacancy. Moreover, the high-entropy RE2(Y0.2Yb0.2Nb0.2Ta0.2Ce0.2)2O7 oxides show the relatively higher thermal expansion coefficients of 10.3–10.7 × 10−6°C−1 and excellent phase stability at elevated temperatures. 相似文献
993.
994.
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996.
溶胶-凝胶法制备的钛酸钡铁电微晶玻璃的显微结构与介电特性 总被引:1,自引:2,他引:1
通过对钛酸钡铁电微晶玻璃的体系选择和成分设计,利用溶胶-凝胶法合成了具有纯钛酸钡结晶相的微晶玻璃。研究了合成过程中凝胶结构变化和析晶行为。结果表明:纯钛酸钡铁电晶体可以在BaO-TiO2-Al2O3-SiO2凝胶中通过调整热处理条件而控制析晶,钛酸钡晶体的析晶活化能为657 kJ/mol。通过控制玻璃体中钛酸钡晶粒的尺寸,利用Raman光谱研究了其铁电本征尺寸效应。结果表明:钛酸钡晶体在玻璃体中的铁电临界尺寸为19nm。 相似文献
997.
A Truncated Sum of Processing‐Times–Based Learning Model for a Two‐Machine Flowshop Scheduling Problem
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Scheduling with learning effects has gained increasing attention in recent years. A well‐known learning model is called “sum‐of‐processing‐times‐based learning” in which the actual processing time of a job is a nonincreasing function of the jobs already processed. However, the actual processing time of a given job drops to zero precipitously when the normal job processing times are large. Moreover, the concept of learning process is relatively unexplored in a flowshop environment. Motivated by these observations, this article addresses a two‐machine flowshop problem with a truncated learning effect. The objective is to find an optimal schedule to minimize the total completion time. First, a branch‐and‐bound algorithm incorporating with a dominance property and four lower bounds is developed to derive the optimal solution. Then three simulated annealing algorithms are also proposed for near‐optimal solution. The experimental results indicated that the branch‐and‐bound algorithm can solve instances up to 18 jobs, and the proposed simulated annealing algorithm performs well in item of CPU time and error percentage. © 2011 Wiley Periodicals, Inc. 相似文献
998.
999.
脱硫石膏粉煤灰胶结材水化硬化机理及耐水性研究 总被引:13,自引:0,他引:13
以火电厂的两种废渣即脱硫石膏和粉煤灰为主要原料制得的胶结材,其强度明显高于普通石膏制品,软化系数大于0.85。采用水化热测定、XRD和pH值测定及SEM/EDXA分析,并结合宏观试验结果,分析了这种胶结材的水化硬化机理和微结构特点,并对其耐水性提高的原因进行了讨论。 相似文献
1000.
Nickel-cobalt and nickel-iron electrodeposits were characterized as hydrogen electrodes in alkaline water electrolysis (6 mol/L KOH, 25°C). The nickel-based codeposits were fabricated with different bath compositions and at different current densities. The hydrogen evolution in water electrolysis on the nickel-based codeposits was apparently enhanced as compared with that on nickel. The improvement of the electrocatalytic behaviour of the hydrogen electrodes is attributed to their composition and an increase of their active surface, which are dependent on the electrodeposition conditions. 相似文献