Silicon - In this work the reverse flotation as beneficiation process for high-purity silica valorization from Draissa quartz deposits (Algeria) is studied as a potential raw material for... 相似文献
Morphological characterization was investigated by agro-morphological criteria related to carob seed size in four different moroccan regions collected in 2018 and 2019. There was no significant difference (p ≤ 0.05) on the seeds lengths and widths. However, a significant difference between seeds thickness and total seeds weight per pod (p ≤ 0.05) were observed between these four populations. The fatty acid, sterol, tocopherol, hydrocarbon, and the unoxygenated composition of carob seed extracts (Ceratonia siliqua L.) were studied. The mean fat yield of the seeds obtained is 1.53%–2.17%, 2.14%–2.15%, 1.61%–1.62%, 1.71%–1.75% for, respectively, the P1 (Meknes), P2 (Fez), P3 (Khemisset), and P4 (Marrakech) in 2018 and 2019. The seed oil was extracted with hexane and the analysis of the fatty fraction was performed by gas chromatography–mass spectrometry (GC–MS). Results show that the major fatty acids for 2018 and 2019 are linoleic acid (61.48%–61.52%, 52.12%–52.14%, 57.76%–58.15%, 61.33%–61.52%), palmitic acid (15.78%–15.81%, 16.44%–16.45%, 19.11%–18.37%, 20.24%–20.32%), oleic acid (11.03%–11.04%, 8.72%–8.82%, 8.51%–8.61%, 8.41%–8.53%), stearic acid (4.35%–3.14%, 5.40%–5.43%, 3.12%–3.13%, 0.96%–1.56%), and cerotic acid (0.62%–0.53%, 4.51%–4.52%, 4.03%–4.06%, 3.84%–3.87%). The unsaturated fatty acids (69.39% in 2018 and 69.68% in 2019) are the most dominant in the four seed extracts compared to the saturated fatty acids. In addition, the oil carob seeds analysis revealed the presence of γ-tocopherol, α-tocopherol and four sterols that included campesterol, stigmasterol, and β-sitosterol. Moreover, the determination of hydrocarbon and un-oxygenated compounds confirmed the existence of major compounds such as heptadecane, 2-methyltriacontane, 1-iodo hexadecane and 1-iodo octadecane. The hierarchical analysis based on the morphological and chromatographic characterization of the seeds allowed the identification of three groups. Consequently, the first group consisted of populations from Marrakesh (P4) and Khemisset (P3), the second group consisted of the P1 from Meknes, and the P2 from Fez constituted the third group. 相似文献
Styrene as a monomer was emulsified in water using several magnetite nanoparticles concentration and pH values. Emulsified styrene drops were used as templates for polymerization, in presence of water soluble free radical initiator, and formation of composite particles. Styrene template drops stabilization was verified by light as well as scanning electron microscopy imaging, which ensured the participation of the particles in building up a mechanical barrier to stop oil drops coalescence. Furthermore, the produced polystyrene composites were strongly attracted to an external magnet. The difference in particles size as a function of pH was elucidated using zeta potential measurements, which indicated dominance of pH on the hydrophilicity of the particles and consequently the extent of emulsification, which in turn affected the size of the obtained microspheres. Under some circumstances, capsules were formed instead of particles. Thereby, it can be concluded that the magnetic microspheres are optimally formed at pH 2.3 independently of the magnetite content used. 相似文献
In this study, the effect of the chemical nature of different calcium (Ca)-based minerals as flame retardant additives in combination with ammonium polyphosphate (APP), in 1:1 proportions, on the flame retardancy behavior and performance of ethylene vinyl acetate copolymer was discussed. Combining APP with partly and completely hydrated calcium oxide led to superior flame-retardant function detected in mass loss calorimeter measurements with respect to the corresponding system containing carbonated calcium. This privileged character was attributed to the higher reactivity of hydrated Ca-based fillers toward APP in comparison with Ca carbonate, which induced the formation of an intumescent residue. The difference between reactivity potential of hydrated and dry Ca was demonstrated by the newly formed thermally stable species, and further evidenced by thermogravimetric analysis performed on APP/fillers blends. Moreover, the presence of more crystalline domains in the Ca/phosphorus-based compounds was evidenced by XRD analysis of the mass loss calorimeter test residues. The results of this work highlight the role of blend additive systems on the performance of flame retardancy of polymer materials. 相似文献
One of the most important analysis in many hydrological and agricultural studies is to convert the daily rainfall data into sub-daily (hourly) because in many rainfall stations, only the daily rainfall data are available and for a comprehensive rainfall analysis, these data should be converted to sub-daily. Many experimental and analytical methods are available for this conversion but one of the simplest yet accurate ones has been proposed by the Indian Meteorological Department (IMD). Since the IMD method has shown low accuracy in some regions, in this study, the IMD method is modified to a single parameter equation, called Modified Indian Meteorological Department (MIMD) in order to improve the accuracy of the conversion. For this reason, the parameter is calibrated so that the maximum correlation between observed and estimated values is achieved. Five stations in different regions with different climatic conditions were selected so that the daily and sub-daily rainfall data were available in each of them. Then, the parameter of the MIMD method was derived for each station. The results were compared with both observed data and IMD method and it was shown that the mean correlation coefficient of MIMD and IMD methods were 0.9 and 0.73 respectively for 12-h rainfall depth which indicated that the accuracy of the MIMD method in estimation of sub-daily rainfall depths was significantly increased. Moreover, the results showed that the accuracy of the MIMD method decreases as rainfall duration decreases.
The perchloroethylene coal desulfurization process has unique advantages as a precombustion coal cleaning process, that include high cleaning efficiencies, mild process conditions, minimal output of undesirable byproducts, and cost effectiveness. However, the use of perchloroethylene in the process renders an important process engineering problem of complete recovery and reuse of perchloroethylene. thus requiring a “zero discharge” condition of the solvent. Therefore, the treated coal must be stripped of any residual perchloroethylene. Carbon dioxide (CO2) in its supercritical state has been investigated for its ability to remove chlorine from Indiana 5 coal, that has been desulfurized by the perchloroethylene (PCE) process. The reduction of CI contenttffrom a PCE treated and filtered coal has been as high as 78% The exprements have been carried out. following a statistical experimental design and the discerning characteristics of the process been identified. The solvent density and extraction conditions can be tailored in such a way as to optimally remove CI from the coal without any detrimental effects on the coal matrix. The supercritical CO2 extraction process can be successfully implemented to the PCE coal cleaning process by replacing energy intensive steps of steam stripping and vacuum dying 相似文献