Cu(Ⅱ)-3,5-diCl-DMPAP-OP 显色反应及其应用研究

研究了在非离子表面活性剂ＯＰ存在下，２－（３，５－二氯－２－吡啶偶氮）－５－二甲氨基苯酚（３，５－ｄｉＣｌ－ＤＭＰＡＰ）与Ｃｕ（Ⅱ）的显色反应。实验表明，在ｐＨ７．５～１０．０的硼砂缓冲介质中，铜（Ⅱ）与试剂形成１∶２的稳定的红色配合物，其表观摩尔吸光系数ε５５８＝９．７×１０４Ｌ·ｍｏｌ－１·ｃｍ－１，铜浓度在０～６．５μｇ／１０ｍＬ范围内符合比尔定律。在柠檬酸三钠和二酮肟的存在下，可直接用于铝合金和纯铝中微量铜的测定，获得满意结果。     

在线Nielsen源的研制

描述如何简单地把标准Ｎｉｅｌｓｅｎ源必建成在线离子源，对它的一些性能进行测试并与标准离子源作了比较，讨论了它们的判别和产生的原因。实验结果表明，两离子源的放电特性无差别，改建后的离子源可考虑用来进行整体靶离子源试验。     

Nitrogen utilization and transformation in red soil fertilized with urea and ryegrass

The influence of fertilization with urea and ryegrass on nitrogen utilization and transformation in red soil has been studied by using ^15N tracer method.When urea and ryegrass were applied alone or in combination,the percentage of N uptaken by ryegrass from labelled urea was 3 and 1.7 times that from labelled ryegrass for the application rate of 200mgN.kg^-1 and 100mgN.kg^-1,respectively;combining application of ryegrass and ureareduced uptake of urea N and increased uptake of ryegrass N by ryegrass plant,but the percentage of N residued in soil increased for urea and decreased for ryegrass.when urea and ryegrass were applied alone,the percentage of N residued in soil from labelled ryegrass was more than 69% while that from labelled urea was less than 25%,and much more ryegrass N was incorporated into humus than urea N.     

安多霖对高功率微波照射大鼠性激素和氧化还原系统的影响

选用SD和Wistar大鼠为研究模型。将SD大鼠分为对照组、模型组、6和12 g/kg给药组,给药组动物安多霖连续灌胃30天,100 mW/cm2微波全身照射10分钟,照后24小时取全血分离血清,放射免疫法检测血清睾酮和卵泡刺激素（FSH）活性。将Wistar大鼠分为模型组、3、6和9 mg/kg给药组,给药组动物安多霖连续给药7天,以100 mW/cm2微波照射15分钟,照后继续给药至照后3、7和10天,取血分离血清,分光光度法检测血清过氧化氢酶（CAT）、谷胱甘肽过氧化物酶（GSH-Px）活性和还原型谷胱甘肽（GSH）含量。结果显示,照后SD雄性大鼠血清睾酮含量较对照组显著降低（p〈0.05）,但给药组降低的幅度低于模型组,如12g/kg组与对照组之间无明显差异。从CAT、GSH-Px和GSH的分析结果看,安多霖可不同程度地提高Wistar大鼠血清CAT、GSH-Px活性和GSH含量,尤其是照后7天,6和9 mg/kg给药组GSH-Px活性较模型组有明显的提升（p〈0.05）。从以上结果可以得出,安多霖对微波辐射损伤的大鼠具有一定的保护作用。     

Radionuclides in primary coolant of a fluoride salt-cooled high-temperature reactor during normal operation

The release of fission products from coated particle fuel to primary coolant,as well as the activation of coolant and impurities,were analysed for a fluoride salt-cooled high-temperature reactor (FHR) system,and the activity of radionuclides accumulated in the coolant during normal operation was calculated.The release rate (release fraction per unit time) of fission products was calculated with STACY code,which is modelled mainly based on the Fick's law,while the activation of coolant and impurities was calculated with SCALE code.The accumulation of radionuclides in the coolant has been calculated with a simplified model,which is generally a time integration considering the generation and decay of radionuclides.The results show that activation products are the dominant gamma source in the primary coolant system during normal operation of the FHR while fission products become the dominant source after shutdown.In operation condition,health-impacts related nuclides such as 3H,and 14C originate from the activation of lithium and coolant impurities including carbon,nitrogen,and oxygen.According to the calculated effective cross sections of neutron activation,6Li and 14N are the dominant 3H production source and 14C production source,respectively.Considering the high production rate,3H and 14C should be treated before being released to the environment.     

离子束技术应用于腐蚀科学

离子束技术(包括离子注入、离子束混合、离子束分析等)在腐蚀科学领域中的应用是近十年来一个引人注目的新发展。 据工业发达国家估计,每年因材料、设备腐蚀造成的直接损失约为当年国民经济总产值的2—4％,例如美国1982年全国因腐蚀而造成的经济损失就高达1260亿美元,我国在1980年估算的腐蚀损失约200亿人民币。随着我国四化建设的迅速发展,金属腐蚀与防护的研究已成为当前一个急待进行的重要课题。     

99Tcm-葡萄糖二酸亲肿瘤显像剂的动物实验

选用＾９９Ｔｃ＾ｍ－葡萄糖二酸（＾９９Ｔｃ＾ｍ－ｇｌｕｃａｒａｔｅ,简称＾９９Ｔｃ＾ｍ－ｇｌｕ）作为肿瘤阳性示踪剂,对肺腺癌小鼠模型进行动物实验,以主要组织器官的放射性摄取百分比及Ｔ／ＮＴ作为统计指标并常规静态及延时显像观察。     

A ctivation measurement of neutron distribution in intermediate energy heavy ion target area

The distribution of neutrons produced by the reaction of 50MeV/u ^12C-ion on a thick Cu target are studied.The neutrons are measured with threshold activation detectors.Al.F,C,Al and In activation samples were used to measure neutrons with energy greater than 7,11,20,50MeV and thermal neutrons,respectively,The fluence rate,energy and angular distributions of neutrons,total neutron yield of 12C-ion and the emission rate in the forward direction of neutrons over 11 and 20MeV were obtained.     

分子介质中的正子素形成几率与辐射保护效应

从辐射化学的观点出发,引入辐射保护函数(F)的概念,根据云团反应的竞争机理,建立了“理想二元体系”中正子素形成几率和保护函数之间的关系式;并且,根据此关系,对正庚烷——正穴清除剂(二噁烷,三乙胺,吡咯烷)体系的I_3值及对一些阴离子(I~-,Br~-,Cl~-,S~(2-),SCN~-和F~-)水溶液中的I_3值随溶质浓度的变化进行了定量地拟合。发现,在正穴清除剂体系中,吡咯烷与其他两者相比,对正庚烷具有较大的辐射保护效应;而对阴离子水溶液体系,阴离子对水的辐射保护效应从大到小的顺序是:I~-,SCN~-,S~(2-),Br~-,Cl~-,F~-。实际上,F~-对水毫无保护作用。     

电弧作用下 AgMeO 触头材料的物理冶金过程分析

本文分析了ＡｇＭｅＯ触头材料电弧侵蚀机理,对电弧的热力作用下触头材料的各种响应从物理冶金本质角度进行全面研究,在此基础上对ＡｇＭｅＯ触头材料组元和组织的优化设计作了完整的分析讨论,提出优化设计判据,最后提出能充分表征触头材料电气使用性能的材料物理性能参数。