Synthesis and characterization of poly(siloxane-urethane)s

A series of polyurethane block copolymers based on hydroxy-terminated polydimethylsiloxane and poly(propylene glycol) soft segments of molecular weights 1818 and 2000, respectively, were synthesized. The hard segments consisted of 4,4′-diphenylnethane diisocyanate and 1,4-butanediol as the chain extender. Samples with different molar ratios were prepared. We tried to synthesize polydimethylsiloxane-based polyurethanes (PDMS-PU) containing a hard block as major fraction and a soft block as minor fraction for preparing toughened rigid systems. After a study of the pure polydimethylsiloxane-based polyurethane and poly(propylene glycol)-based polyurethane (PPG-PU), (mixed polyol)-based block copolymers and blends of PDMS-PU and PPG-PU were synthesized, and characterized by means of differential scanning calorimetry, tensile testing and scanning electron microscopy. In (mixed polyol)-based copolymers and lower hard-segment content blends, macro-phase separation occurred, but blends with higher hard-segment contents showed significant reduction in amounts of phase separation.     

“镍”催化酰氯和有机锡试剂交叉偶联反应的研究

镍络合物催化酰氯与有机锡试剂交叉偶联合成有机酮的反应,其反应选择性强,反应彻底,转化率高,工艺简单。在有机锡过量的情况下,对不同催化剂的催化活性和包括投料比,反应温度,反应时间,反应溶剂等反应条件进行了考察。     

The effects of plasma etching induced gate oxide degradation onMOSFET's 1/f noise

The effects of the plasma etching process induced gate oxide damages on device's low frequency noise behavior are investigated on MOSFET's fabricated with different field plate perimeter to gate area ratio antennas. Abnormal 1/f noise spectrum with a shoulder centered in the frequency range of 100 and to 1 kHz was frequently observed in small geometry devices, and it is attributable to a nonuniform distribution of oxide traps induced by plasma etching process     

能量"三环节"理论在原油蒸馏装置扩能改造中的应用

中国石化扬子石化股份有限公司炼油厂在第一套常减压蒸馏装置扩能改造中，使用了多项节能技术以实现能量的优化利用。本文以标定数据为基础，运用能量“三环节”理论对该装置的用能状况进行了计算和分析，从能量利用角度对装置的扩能改造效果进行了评价，并为装置的进一步优化能量利用提出了相应措施。     

鱼雷罐喷粉预处理优化研究

在已经得到的描述鱼雷罐喷粉处理基本参数具体表达式的基础上，运用多目标非线性优化方法，对工艺操作参数进行优化。     

Numerical modeling of near corona wire electrohydrodynamic flow in a wire-plate electrostatic precipitator

Numerical modelling of the flow velocity fields for the near corona wire electrohydrodynamic (EHD) flow was conducted. Solutions of the steady, two-dimensional momentum equations have been computed for a wire-plate type electrostatic precipitator (ESP). The equations were solved in the conservative finite-difference form on a fine uniform rectilinear grid of sufficient resolution to accurately capture the momentum boundary layers. The numerical procedure for the differential equations was used by SIMPLEST algorithm. The CFD code coupled with Poisson's electric field, ion transport equations and the momentum equation with electric body force, was used for the numerical simulation with the Chen-Kim k-epsiv turbulent model. The numerical results show that EHD secondary flow was clearly visible in the downstream regions of the corona wire despite the low Reynolds number for the electrode (Re _cw=12.4). Secondary flow vortices caused by the EHD increases with increasing discharge current or EHD number, hence pressure drop of ESP increases     

西安市水问题现状分析与节水对策研究

西安市是严重缺水的城市,水资源紧缺已经成为制约其发展的因素之一。本文通过调查研究,对西安市水问题进行了现状分析,并从节约用水、推广使用再生水、开发利用雨水等三个方面提出可行的节水对策。     

部分可渗透直立圆柱的消波作用研究

本文导出了线性波浪作用于上部可渗透的直立刚性圆柱体上的水动力的解析解。在线性有势流的假定下，用特征函数展开方法求出了内部和外部流场的解。给出了不同波浪要素及结构尺寸参数下的数值结果。由结果可知，提高可渗透性可以有效消减波幅。