Sulfur exchange on Co---Mo/Al2O3 hydrodesulfurization catalyst using S radioisotope tracer

A commercial Co---Mo/Al₂O₃ catalyst was labeled with the radioisotope ³⁵S in hydrodesulfurization (HDS) of ³⁵S-labeled dibenzothiophene (³⁵S-DBT) in a high-pressure flow reactor at 50 kg/cm². Then, HDS of 4-methyldibenzothiophene (4-MDBT) and 4,6-dimethyldibenzothiophene (4,6-DMDBT) or sulfur exchange of H₂S were carried out on the labeled catalyst at 50 kg/cm² and 260–360°C. The amounts of labile sulfur participating in the reaction were determined from the radioactivity of ³⁵S---H₂S released from the ³⁵S-labeled catalyst. In the HDS reactions, the amount of labile sulfur participating in the reaction decreased in the order: DBT> 4-MDBT> 4,6-DMDBT. In the sulfur exchange reaction with H₂S, the adsorption of H₂S on the catalyst reached saturation above a H₂S partial pressure of 0.36 kg/cm². It was suggested that the release of H₂S from the labile sulfur may be the rate determining step of the HDS reaction.     

基于密度调整的改进自适应谱聚类算法

针对谱聚类存在构造相似度矩阵时对尺度参数敏感以及处理多重尺度数据集效果不理想的缺陷, 提出一种基于密度调整的改进自适应谱聚类算法. 该算法将样本点所处领域的密度引入谱聚类, 利用密度差来调整样本点之间的相似度, 使其更符合实际簇类中样本点间的内在关系, 在一定程度上解决了多尺度聚类问题; 同时, 通过样本点的近邻距离自适应得到尺度参数, 使算法对尺度参数相对不敏感. 仿真实验验证了所提出算法的有效性和优越性.

     

Mg:Mn:Fe:LiNbO3晶体的全息存储性能

在同成分铌酸锂晶体中掺入0.03?2O3和0.1%MnO2(质量分数),分别掺入0,1%,3%,4.5%,6%的MgO(摩尔分数),用提拉法生长了一系列Mg:Mn:Fe:LiNbO3晶体.检测了Mg:Mn:Fe:LiNbO3晶体的红外光谱和抗光损伤能力.掺0,1%,3%,4.5%Mg的Mg:Mn:Fe:LiNbO3晶体的OH-红外振动峰位于3484cm-1,而掺6%Mg的Mg:Mn:Fe:LiNbO3晶体红外振动峰移到3 535gm-1.采用波长为632nm的He-Ne激光器作为光源,通过二波耦合方法测试晶体的全息存储性能.结果表明:Mg:Mn:Fe:LiNbO3晶体的写入时间和动态范围随掺镁量的增加而显著减小,而光折变灵敏度略有上升,抗光损伤性能增强,其中掺镁量为3%Mg:Mn:Fe:LiNbO3晶体更适合作为全息存储介质.     

PE基聚硅氧烷/改性SiO2超疏水薄膜的构筑

使用十八烷基三甲氧基硅烷(OTMS)对纳米SiO2进行表面疏水改性,将得到的改性纳米SiO2(OTMS-SiO2)添加到有机硅树脂(SI)中,然后采用两步法在聚乙烯(PE)薄膜表面固化制备了复合涂层SI/OTMS-SiO2.通过FTIR、1HNMR、29SiNMR、TGA对OTMS-SiO2及复合涂层进行了表征,采用接触角测量仪、SEM、AFM对复合涂层疏水特性和形貌进行了测试和观察,最后对复合涂层的耐磨性和附着力进行了分析.结果表明,SiO2表面成功引入了OTMS,且OTMS-SiO2均匀附着在硅树脂涂层上,增加了表面粗糙度,得到了PE基固化超疏水复合涂层.当OTMS-SiO2添加量为正己烷质量的8％时,制得的复合涂层的水接触角为154°,滚动角为7°,并具有良好的耐磨性,其附着力可达4A等级.     

基于PTS的视频流集群同步显示技术

针对集群大屏拼接显示系统各节点机独立解码、视频流显示不同步的问题,本文分析了集群拼接显示系统的特点,提出了利用PTS信息实现集群内各节点机同步显示视频流的机制,研究了组播接收模块、Ts流拆包模块、视频解码模块和同步控制模块和拼接屏显示模块等视频流同步显示实现技术．研究试验结果证明了基于PTS的视频流集群同步显示技术的有效性．     

TCR+FC型无功补偿技术在矿井提升系统中的应用

提升机是采矿企业广泛使用的大功率、高耗能的生产设备之一,矿井提升系统普遍采用电力电子器件构成的整流装置对其直流电机进行供电和控制。提升机在采矿过程中需要频繁地启动、停机,对电网的无功冲击和谐波污染使供电系统的安全稳定性受到严重影响。本文以国内某铅锌矿盲主井提升系统为研究对象,提出晶闸管控制电抗器(Thyristor Controlled Reactors,TCR)和固定电容器组(Fixed Capacitors,FC)相结合的无功补偿与谐波治理方法。针对提升机运行过程的特殊性和复杂性,给出无功补偿装置的具体电路设计、参数计算等的方法。提出的无功补偿与谐波治理技术对无功补偿装置的工程研究和开发提供一定的参考和指导,对提高电网的供电质量,保障矿井安全、稳定、高效生产具有十分重要的意义。     

Preparation and characterization of a series of polyamides with long alkylene segments: Nylons 12 20, 10 20,s 20,6 20, 4 20 and 2 20

Summary A series of nylons with long alkylene segments between amide groups were newly prepared by step-heating melt-polycondensation of 1,lS-octadecanedicarboxylic acid with various diamines. The prepared polyamides were characterized carefully. The results show that many properties of the prepared nylons change regularly with the length of methylene segments in diamines. In addition, nylon 2 20 has a relatively low molecular weight and much different melting and thermal decomposition behaviors in comparison with other nylons. Received: 21 June 2OO2/Revised version: 18 September 2002/ Accepted: 18 September 2002 Correspondence to Deyue Yan E-mail: dyyan@mail.sjtu.edu.cn Tel: 0086-21-54742863 Fax: 0086-21-54741297     

环己烷在Au-Co/SBA-15上选择性氧化的研究

以沉积-沉淀法制备了Au-Co/SBA-15催化剂,在没有任何有机溶剂或助剂的条件下,研究了以空气为氧化剂的环己烷选择性氧化。当Au-Co/SBA-15催化剂中金的质量百分含量为1.0%,催化反应在423 K 3.0 MPa下进行120 m in时,催化效果最好,此时环己烷的转化率为22.7%,环己酮和环己醇的总选择性为95.2%,酮醇比为2.9,且催化剂重复使用五次后活性基本不变。     

Charge/discharge characteristics of sulfur composite cathode materials in rechargeable lithium batteries

The charge and discharge characteristics of lithium batteries with sulfur composite cathodes have been investigated. The sulfur composites showed novel electrochemical characteristics. The analysis of the differential capacity indicated that the discharge process showed two voltage plateaus of 2.10 V and 1.88 V, and the charge process also presented two voltage plateaus of 2.22 V and 2.36 V. The overcharge test showed that the composite cannot be charged over 4.0 V, the voltage always stopped at about 3.9 V during charging, indicating that the composite presented the intrinsic safety for the overcharge of lithium batteries. The overcharge can cause serious safety problem for the conventional Li-ion batteries. The overcharge test also showed that the batteries with sulfur composite were destroyed when the upper cut-off voltage was over 3.6 V. However, the composite presented good reversible capacity after it was deep discharged even to 0 V. It showed stable cycleability and high cycling capacity of 1000 mAh g⁻¹ when cycling between 0.1 V and 3.0 V, indicative of the different characteristic from the conventional oxide cathode materials. The prototype polymer battery with the composite cathode material presented the energy density of 246 Wh kg⁻¹ and 401 Wh L⁻¹.     

领军人才在科技创新团队建设中的核心作用

在论述领军人才的概念、特点和科技创新团队特征的基础上,针对科技创新团队的生命周期及其成员的动态组合规律,论述了领军人才在科技创新团队建设中的核心作用。