N,N''-取代邻苯二胺的合成

通过2-取代苯并咪唑盐的还原开环反应制备了8个N,N′-不同取代的邻苯二胺,并经1HNMR、IR、MS及元素分析表征,其中5个未见文献报道.这是一条由邻苯二胺和羧酸经2.取代苯并咪唑制取该类化合物的简洁合成路线.     

Facile modifications of polyimide via chloromethylation: II. Synthesis and characterization of thermocurable transparent polyimide having methylene acrylate side groups

From chloromethylated polyimide, a useful starting material for modification of aromatic polyimides, a thermocurable transparent polyimide having acrylate side groups was prepared. In the presence of 1,8‐diazabicyclo[5,4,0]undec‐7‐ene, chloromethylated polyimide was esterified with acrylic acid to synthesize poly(imide methylene acrylate). The polymer was soluble in organic solvent, which makes it possible to prepare a planar film by spin coating. The polymer film became insoluble after thermal treatment at 230 °C for 30 min. Optical transparency of the film at 400 nm (for 1 µm thickness) was higher than 98 % and not affected by further heating at 230 °C for 250 min. Adhesion properties measured by the ASTM D3359‐B method ranged from 4B to 5B. Preliminary results of planarization testing showed a high degree of planarization (DOP) value (>0.53). These properties demonstrate that poly(imide methylene acrylate) could be utilized as a thermocurable transparent material in fabricating display devices such as TFT‐LCD. Copyright © 2004 Society of Chemical Industry     

建设群力新区水系工程的初步设想

就水系工程水源的选择、规划设计要点,提出了初步设想。     

16位串行模数转换器MAX1132的特性及应用

MAX1132是美国MAXIM公司生产的16位串行模数转换器，文章介绍了MAX1132的工作原理、接口特点及使用方法，给出了它在数据采集系统中的硬件电路和软件程序。     

软件无线电中采样率转换技术的实现及在3G中的应用

目前移动通信标准繁多,且新旧体制混杂,很难做到统一.为了实现互连互通,目前比较可行的方法是采用软件无线电.采样率转换技术是实现互连互通的关键.文中针对第三代移动通信系统(3G)中不同通信体制的带宽、速率要求,根据分级变换的思想,对3G中的CDMA2000和TDSCDMA的采样率转换方案进行了设计,并对3G中的5种制式的采样率转换方案进行了分析比较.实验表明,这一方案可以在采样率变换的高效网络结构基础上进一步降低滤波运算量和存储量.     

电子商务中的PKI、SSL与SET的技术分析

PKI是目前在电子商务中安全传输方案，SSL和SET两种安全的电子交易协议，在网上交易中有着广泛地应用，是大多数在线支付所采用的支付协议。这里在探讨PKI、SSL、SET技术原理的基础上，对它们各自的作用、技术实现、工作漉程等进行了描述；对它们之间的联系、区别、应用范围进行了深入的分析。     

Influence of nano-scaled dispersed second phase on substructure of deformed dispersion strengthened copper alloy

The deformation behavior of dispersion strengthened copper alloy Cu-Al2O3 was studied by TEM. The results show that nano-scaled dispersed second phase not only increases dislocation density in matrix, but also has an important influence on the dislocation substructure. The presence of fine dispersed Al2 O3 particles results in a uniform and random dislocation distribution in matrix copper and causes the difficulty in formation of dislocation cell structure and the decrease in the amount of cell structure during deformation. Deformation gives rise to much more dislocations and dislocation cells form more difficultly and the decrease in the cell size with the increase of dispersion degree.     

Mutual information-based analysis of JPEG2000 contexts.

Context-based arithmetic coding has been widely adopted in image and video compression and is a key component of the new JPEG2000 image compression standard. In this paper, the contexts used in JPEG2000 are analyzed using the mutual information, which is closely related to the compression performance. We first show that, when combining the contexts, the mutual information between the contexts and the encoded data will decrease unless the conditional probability distributions of the combined contexts are the same. Given I, the initial number of contexts, and F, the final desired number of contexts, there are S(I, F) possible context classification schemes where S(I, F) is called the Stirling number of the second kind. The optimal classification scheme is the one that gives the maximum mutual information. Instead of using an exhaustive search, the optimal classification scheme can be obtained through a modified generalized Lloyd algorithm with the relative entropy as the distortion metric. For binary arithmetic coding, the search complexity can be reduced by using dynamic programming. Our experimental results show that the JPEG2000 contexts capture the correlations among the wavelet coefficients very well. At the same time, the number of contexts used as part of the standard can be reduced without loss in the coding performance.     

EFP战斗部参数优化设计

文中在大量数值仿真的基础上利用正交设计方法对EFP战斗部参数进行了优化设计,通过优化找出EFP飞行速度及长径比与三个影响因素(药型罩曲率半径、装药高度直径比和药型罩厚度)之间的关系,确定了最佳参数组合,在此参数组合下可达到EFP速度和长径比的良好匹配,有效地提高了EFP的飞行性能.     

台州市"20020913"特大暴雨洪水分析及思考

2002年9月13-14日，台州市受18号强热带风暴“黑格比”减弱后的低压环流的外围影响，台州温岭-路桥-黄岩-杜桥-线普降大到特大暴雨，灾情严重。这场暴雨的特征是历时短、强度高、笼罩面积小，是台州历史上罕见的平原大暴雨。通过对这场暴雨洪水特性和水利工程所发挥作用的分析，揭示暴雨的成因和特性，提出几点思考。