Purification,surface modification of coal ash silica and its potential application in rubber composites

This article reports the purification and surface modification of coal ash silica and afterwards its utilization as reinforcing filler in solution‐styrene‐butadiene rubber/butadiene rubber (S‐SBR/BR). The coal ash silica free of unwanted metal ions/mineral oxides was obtained using phosphoric acid. The chemical composition of the purified coal ash silica in comparison to impure coal ash indicates the presence of characteristic hydroxyl functional group at 3440 cm^?1 and an increase in the oxygen content as determined with the help of Fourier Transform Infrared and x‐ray photoelectron spectroscopy, respectively. The contact angle analysis shows that after purification the polar part of the surface energy increased to 17.5 from 12 m Jm^?2. While the surface area increased to an order of magnitude, i.e., 11.6 to 110.5 m² g^?1. The modification of purified silica particles with bis(3‐triethoxysilylpropyl) tetrasulfane reveal the functionalization of hydroxyl to ‐Si‐O‐R groups as detected at 1560 cm^?1. As a consequence, the modified silica based S‐SBR/BR composite resulted in improved mechanical properties due to enhanced silica‐rubber interaction. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010     

Cavitation erosion of electroplated nickel composite coatings

The cavitational wear resistance of electroplated nickel composite layers was tested following ASTM G32. Particles of different hardness (titania and silicon carbide) and different sizes from micro-scale to nano-scale were incorporated up to 30 vol.% into a nickel matrix. Martens hardness is improved by grain refinement via particle incorporation. Compared to pure electroplated nickel films the composite layers strengthened by submicro-scale silicon carbide particles exhibit a decreased mass loss of one order of magnitude after 8 h testing time. Remarkably, layers with nano-scaled titania particles show a similar performance.

Apart from particle adherence failures, reduced mass loss of the composite layers correlate with improved hardness of the composite due to grain refinement of the matrix and dispersion hardening effects.     

Mechanical, rheological, and thermal behavior assessments in HDPE/PA-6/EVOH ternary blends with variable morphology

Visco-elastic and dielectric spectra of multiwalled carbon-nanotube reinforced silicon elastomer nanocomposites were used to study relaxation behavior. SEM photomicrographs shows well dispersion of MWCNT in elastomer matrix. In visco-elastic analysis primary relaxation was studied as a function of temperature (?100 to 100 °C) at frequency 1Hz and strain 1 %. The effect of MWCNT loadings on storage modulus, loss modulus, and loss tangent has been studied. The non-linearity in loss tangent, storage modulus and loss modulus was explained on the basis of MWCNT-elastomer interaction and the inter-aggregate attraction of MWCNT. The secondary β relaxation was studied using dielectric relaxation spectra in the frequency range of 0.1 Hz to 10⁶ Hz. The effect of MWCNT loadings on the complex and real parts of impedance was distinctly visible which has been explained on the basis of interfacial polarization of fillers in a heterogeneous medium and relaxation dynamics of polymer chains in the vicinity of fillers. The dielectric formalism has been utilized to further investigate the conductivity and relaxation phenomenon. The ‘percolation limit’ of the MWCNT in the silicon elastomer was found to be in the range of 4 phr loading.     

Einfluss von Aluminium auf die Karbidbildung im Schnellarbeitsstahl

Aluminum as an alloying element in high-speed steel was investigated for the first time during the Second World War at the Montanuniversität Leoben. At this time there was an enormous consumption or rather a shortage of molybdenum and especially of tungsten worldwide. Tungsten was not only used for the high-speed steel production but was also very much needed for the war industry. Attempts were made in order to replace these alloying elements in high-speed steels with cheaper elements. It was found that a certain percentage of tungsten and molybdenum in high-speed steel can be replaced or substituted by an aluminium content of 0.3 up to 1.4 mass-% without any loss of cutting performance. However, no detailed metallurgical investigations were carried out to explain and clarify this behaviour of aluminium. The influence of aluminium in high-speed steels is highly controversial, due to the fact that aluminium compared to tungsten and molybdenum is not a carbide-forming element, but the special properties of high-speed steels are mainly gained by the presence of carbides. Despite several works in this field, there is no clear understanding of how aluminium can affect the properties of high-speed steel. In the present work, standard and modern examination methods, such as scanning electron microscope, energy dispersive X-ray spectroscopy, and atom probe tomography, were used to investigate the effect of aluminium on the primary and secondary hardening carbides in high-speed steels. The investigations were conducted on three high-speed steel grades with varying the aluminium content only.     

Effects of gamma-sterilization on DOC, uranium and arsenic remobilization from organic and microbial rich stream sediments

Organic-rich sediments are known to be effective accumulators for uranium and arsenic. Much is known about the capacity for metal or metalloid fixation by microbes and organic compounds as well as inorganic sediment particles. Experiments investigating the effect of microbes on the process of metal fixation in sediments require sterilized sediments as control treatment which is often realized by gamma-sterilization. Only few studies show that gamma-sterilization has an effect on the remobilization of metal and metalloids and on their physico-chemical properties. These studies deal with sediments with negligible organic content whereas almost nothing is known about organic-rich sediments including a probably high microbial activity. In view of this, we investigated the effect of gamma-sterilization of organic-rich sediments on uranium and arsenic fixation and release. After ten days within an exposure experiment we found a significant higher remobilization of uranium and arsenic in sterile compared to unsterile treatments. In line with these findings the content of dissolved organic carbon (DOC), manganese, and iron increased to even significantly higher concentration in the sterile compared to unsterile treatment. Gamma-sterilization seems to change the physico-chemical properties of organic-rich sediments. Microbial activity is effectively eliminated. From increased DOC concentrations in overlaying water it is concluded that microbes are eventually killed with leaching of cellular compounds in the overlaying water. This decreases the adsorption capacity of the sediment and leads to enhanced uranium and arsenic remobilization.     

The Native Plant Enthusiasm: ecological panacea or xenophobia?

The enthusiasm for the use of so-called native plants and the rejection of so-called exotic plants in 20th-century garden and landscape design is explored. The underlying ideas and ideology are discussed using examples in Germany, particularly from the time of National Socialism, and the United States.     

Contaminants, diet, plasma fatty acids and smoking in Greenland 1999-2005

OBJECTIVES: The purpose of this study is to monitor and assess human exposure to pollution in the Arctic which presents a potential future health risk for the local populations. Epidemiological studies in Greenland have shown that human blood levels of several organic contaminants are very high, especially in the North where people depend on local food. In East Greenland (Ittoqqortoormiit (Scoresbysund)) the population shows the highest blood levels of several persistent organic pollutants found in Arctic countries, especially PCB, the levels of which exceed Canadian guideline levels. As in other Arctic countries, the predominant source of these contaminants is the local diet. However, other factors such as smoking may influence the metabolism and thereby the accumulation of toxic substances. STUDY DESIGN: This project is part of the human health program of the ongoing circumpolar "Artic Monitoring and Assessment Programme". Lifestyle, anthropometric factors, and dietary survey results covering 500 men and women from 6 Greenlandic districts were analyzed along with other factors blood lipids, fatty acid profiles, heavy metals and concentrations of persistent organic pollutants (POPs). RESULTS: The dietary survey showed that the traditional food on the average provided 20-30% of the total energy intake. However, the relative monthly meal intake of seal, whale, polar bear, fish and game, and the composition of imported food, varied between districts. Seal and polar bear intake, and, in particular all the plasma n-3 fatty acids, were significantly correlated with organic contaminant concentrations, (betaHCH, chlordanes, DDTs, Hexachlorobenzene, Mirex, PCBs, and toxaphenes) p<0.01(). After adjusting for age, district, dietary factors or plasma n-3 fatty acids, smoking was significantly correlated with high levels of all the above mentioned POPs. CONCLUSION: The main predictors of high contaminant levels in Greenland were age, district, male gender, smoking and high plasma n-3/n-6 ratio as a marker of high dietary intake of local marine mammals.     

A free radical mechanism for inhibition of arteriosclerosis development with calcium antagonists

Work presents current views on involvement of free radicals in inhibition of development of arteriosclerosis by calcium antagonist (ACa). The importance of other substances, which interferes with calcium ions can contribute to the inhibition of arteriosclerosis development.     

Domain size-induced heterogeneity as performance limitation of small-domain monolithic columns and other LC support types

We have computed the band broadening and the flow resistance in a series of apparently self-similar porous LC support structures, all having the same mean geometric ratios and external porosity, but with a decreasing scale and disturbed by a scale-independent variance on the size and position of the porous solid zone elements. The study shows in a general and qualitative way that each type of LC support that is produced using a manufacturing process displaying a fixed (i.e., domain-size independent) variance on the size and position of the produced solid zone elements will eventually encounter a limit beyond which a further reduction of the domain size can no longer be expected to yield a significant gain in separation speed. This is currently observed in practice for silica monoliths and could also compromise the performance of photolithographically etched columns.     

Failure probability prediction based on condition monitoring data of wind energy systems for spare parts supply

The feasibility of maintenance processes relies on the availability of spare parts. Spare part inventory planning is capital intensive. It is based on demand forecasting, which possesses a high potential in reducing inventories. Even if condition monitoring systems are installed in technical systems, condition monitoring information is barely used to predict the failure probability of units. Therefore, an enhanced forecast model, which integrates SCADA information, has been developed. This leads to more accurate spare part demand forecasts. The approach presented in the paper is based on data mining, the proportional hazards model (PHM) and a binomial distribution. It has been validated with maintenance data of wind energy systems.