Hematite solid and hollow spindles: Selective synthesis and application in gas sensor and photocatalysis

Hematite solid spindles and hollow spindles have been selectively synthesized by a template-free, economical hydrothermal method, using FeCl₃·6H₂O as the starting materials and NaOH as the homogeneous precipitant. XRD analyses indicated that the products consisted of α-Fe₂O₃. SEM and TEM measurements showed that the morphologies of products were in the shape of solid spindles and hollow spindles, respectively. A possible formation process based on the nucleation-oriented aggregation-recrystallization mechanism is proposed. Moreover, the as-prepared hollow spindle-like α-Fe₂O₃ exhibits a good response and reversibility to some organic gas, such as 2-propanol and acetone. Compared with other hematite nanostructures, the porous hollow hematite spindles show outstanding performance in gas sensing due to their large surface area and porous hollow structure. Because of the unique porous hollow structures of the samples, the photocatalytic property of the spindle-like α-Fe₂O₃ was also investigated.     

ZnCl2-assisted Synthesis of ZnSe Polycrystal

A chemical-assisted element direct-reaction method is developed to synthesize ZnSe compound semiconductor material at a relatively low temperature (～1000 C). ZnSe polycrystal was obtained in the closed-tube systems with Zn-Se, Zn-Se-Zn(NH3)2Cl2, Zn-Se-NH4Cl and Zn-Se-ZnCl2. The as-synthesized samples were tested by X-ray diffraction (XRD), thermogravimetric analysis (TGA) and analyzed by thermodynamic numerical method. The results demonstrate that the synthesis efficiency is higher than 99.96% for Zn-Se-ZnCl2 system at around 1000 C for 3 weeks. It also exhibits that not only temperature, but also low apparent ratio of volume and surface area of the source materials and higher ZnCl2 content are required to achieve high synthesis efficiency. A SeCl transporting reaction synthesis process is proposed based on the thermodynamic analysis.     

Coating of TiO2 nanoparticles with PbS thin films and preparation of PbS nanoparticles using a one-pot sonochemical reaction under the multibubble sonoluminescence conditions

Preparations of PbS-coated titanium dioxide (TiO₂) and lead sulfide (PbS) nanoparticles under ultrasonic field at the multibubble sonoluminescence (MBSL) conditions were tested in water solutions. Under the optimal MBSL conditions (20 kHz and 220 W power input), PbS nanoparticles (diameter = 40-50 nm) were prepared by treating lead nitrate and thioacetamide for 20 min in water solutions. The size of PbS nanoparticles was found to be easily increased to about 90 nm in diameter by increasing the reactant concentration twice. A similar sonochemical reaction with TiO₂ nanoparticles (about 20-30 nm in diameter) gave rise to PbS-coated TiO₂ nanoparticles with a core/shell structure. The PbS thin film coating was quite uniform and the average coating depth of PbS on the TiO₂ nanoparticles was about 2-3 nm under the described conditions. It is interesting to note that the coating depth was found to be controlled to 2-10 nm range by increasing the amounts of reactants for Pb and S twice with a sonication time of 30 min.     

2号高炉高冶强下的指标优化措施

在高冶强的生产状态下,高炉如何优化各项技术经济指标,降低其成本,从而提高产品竞争力,是现代高炉操作者积极探索的问题。梅钢2号高炉通过精料、优化操作、改进工艺措施等的实施,实现了高炉高冶强下的指标优化。     

耐晒大红BBN颜料的工艺改进

通过实验对偶合条件进行调整,使得耐晒大红BBN颜料的耐碱性和着色力得到提高,并且减少了原材料的消耗,新工艺制得的产品质量更好,更适合于油墨制造行业的生产需要.     

基于覆盖次数的叠前振幅归一化处理在大庆油田的应用

振幅一致性处理对连片处理至关重要,尤其对叠前偏移,因为各个区块的施工因素不同,区块间的能量差异很大,这样在叠前偏移处理中会导致严重的偏移噪音(边界划弧现象),影响了成像质量.利用基于覆盖次数的振幅归一化处理技术,对大庆油田松辽盆地徐家围子断陷连片叠前时间偏移的振幅一致性进行处理,在保证原始地震道不丢失的前提下,很好地解决了叠前偏移的能量一致性问题,见到了明显的应用效果.     

Wire-in-Wire TiO2/C Nanofibers Free-Standing Anodes for Li-Ion and K-Ion Batteries with Long Cycling Stability and High Capacity

Wearable and portable mobile phones play a critical role in the market,and one of the key technologies is the flexible electrode with high spe-cific capacity an...     

Structure evolution,dielectric,and conductivity behavior of(K0.5Na0.5)NbO3-Bi(Zn2/3Nb1/3)O3 ceramics

(1-x)K0.5Na0.5NbO3-xBi(Zn2/3Nb1/3)O3 ((1-x)KNN-xBZN,x =0.010,0.015,0.020,0.025,and 0.030) lead-free ceramics were fabricated via a traditional solid-state metho...