Magnetic properties and thermal stability of CoFeNi-based amorphous films

CoNiFe-based amorphous films were magnetron-sputtered to investigate their structural and magnetic properties, including annealing-induced effects and interfacial influence from additional layers of Ta and Cu. The amorphous structure was confirmed by diffraction experiments. The magnetic measurements showed a well-defined uniaxial anisotropy in plane, arising possibly from atom oblique incidence effects competing with the stray field of the magnetron. The anisotropy could be influenced by using a Ta buffer layer, though the interfacial reaction gives rise to a dead layer. A coercive force H _c of 1–2 Oe and a magnetization of 680 emu/cm³ were measured at room temperature; properties which show promise for application in magnetotunneling junction devices. Thermal analyses showed a two-stage crystallization behavior, which started at 400°C and ended at about 600°C. The Curie temperature of the amorphous phase was estimated to be about 440°C.     

Hydrogen gas pick-up mechanism of Al-alloy melt during Lost Foam Casting

The hydrogen gas pick-up problem that can occur during Lost Foam Casting was investigated with reduced pressure tests and real castings.The initial hydrogen concentration of the melt and the contact time between melt and polystyrene had a main effect on the hydrogen gas pick-up of Al melt. The hydrogen gas pick-up of Al alloy depended also on pouring temperature and a proper metal front temperature gave the minimum hydrogen pick-up. At a low pouring temperature, the hydrogen went into the melt mainly from entrapped liquid product of polystyrene but at high pouring temperature it was by the gas as well as the liquid product. The mold flask evacuation down to 710 torr decreased the gas porosity down by around 0.4 vol%. The permeability of coating thickness had a great effect because it affects the filling time and the easy removal of liquid polystyrene.     

The mechanochemical processing of aerospace metals

The status of mechanochemical processing of aerospace metals (aluminum and titanium) is reviewed. It is demonstrated that the activation of chemical reactions by mechanical energy can lead to many interesting applications including production of advanced materials with novel constitutional and microstructural effects leading to enhanced mechanical properties.     

Decreasing the number of test specimens by utilizing both fracture stress and fracture location for the estimation of Weibull parameter

In a bending load test for brittle materials, such as ceramics for spacecraft and aircraft, decreasing the number of test specimens required is a crucial problem. This paper discusses the effectiveness of using the information of both fracture stress and fracture location to decrease the number of specimens required to obtain the same precision as the Weibull estimator. The following results were obtained: It was found that by adding the fracture location information, the precision of the Weibull parameter estimation under the optimal design became 1.5–1.9 times better compared with the case of using only the fracture stresses. This means the number of samples necessary to attain the same precision becomes 1/1.5–1/1.9. Tables and figures which give information on the number of samples necessary to attain the required precision are given.     

Synthesis and thermal stability of ball-milled and melt-quenched amorphous and nanostructured Al-Ni-Nd-Co alloys

In this work the Al₈₅Ni₉Nd₄Co₂ alloy was used as a starting point for examining the possibility of forming bulk glassy Al-based materials by combining rapid quenching and ball milling techniques. Fine glassy powders were obtained by ball milling melt-spun amorphous ribbons using a severe cryogenic processing regime. The thermal stability data of the powders as obtained by constant-rate heating and isothermal DSC experiments together with viscosity measurements are discussed with respect to feasible consolidation conditions. The powder compaction was done by two methods (uni-axial hot pressing and extrusion) at 513 K for up to 15 min. Only the uni-axial hot pressing led to bulk Al₈₅Ni₉Nd₄Co₂ samples with similar glassy structure and Vickers microhardness values comparable to those of the initial melt-spun ribbons.