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51.
Chemical absorption of carbon dioxide into phenyl glycidyl ether solution containing THA-CP-MS41 catalyst 总被引:1,自引:0,他引:1
Young-Son Choe Kwang-Joong Oh Min-Chul Kim Sang-Wook Park 《Korean Journal of Chemical Engineering》2010,27(6):1868-1875
Carbon dioxide was absorbed into the phenyl glycidyl ether (PGE) solution within a range of 0–2.0 kmol/m3 in a stirred batch tank with a planar gas-liquid interface at 333–363 K and 101.3 kPa. Trihexylamine-immobilized on chloropropyl-functionalized
MCM-41 (THA-CP-MS41) was used as a mesoporous catalyst, dispersed in organic liquid for the reaction between carbon dioxide
and PGE. The measured absorption rates were analyzed to obtain the reaction kinetics of the consecutive chemical reactions
which consisted of two steps using the mass transfer mechanism based on film theory. The overall reaction kinetics, analyzed
with the pseudo-first-order reaction constant in the consecutive reaction model, was equivalent to the consecutive reaction
kinetics. Effects of polar solvent, such as N, N-dimethylacetamide, N-methyl-2-pyrrolidinone, and dimethyl sulfoxide, on the reaction rate constants were observed using the solubility parameter
of the solvent. 相似文献
52.
Youngson Choe Kwang-Joong Oh Seong-Soo Kim Sang-Wook Park 《Korean Journal of Chemical Engineering》2010,27(3):962-969
Carbon dioxide was adsorbed onto mesoporous adsorbent of butylene diamine immobilized CP-MS41 (BDA-CP-MS41), which was synthesized
by chloropropyl functionalized MCM-41 (CP-MS41) with butylene diamine in a laboratory-scale packed-bed. The adsorber was operated
batchwise with the charge of adsorbent in the range of 1–3 g to obtain the breakthrough curves of CO2. Experiments were carried out at different adsorption temperatures (20–40 °C) and flow rates of nitrogen (10–20 cm3/min) to investigate the effects of these experimental variables on the breakthrough curves. The deactivation model was tested
for these curves by combining the adsorption of CO2 and the deactivation of adsorbent particles. The observed values of the adsorption rate constant and the deactivation rate
constant were evaluated through analysis of the experimental breakthrough data using a nonlinear least squares technique.
The experimental breakthrough data fitted very well to the deactivation model than the adsorption isotherm models in the literature. 相似文献
53.
Dae Hyun Hwang Deokkyu Lee Hosub Lee Dongcheol Choe Sang Hoon Lee Kangtaek Lee 《Korean Journal of Chemical Engineering》2010,27(4):1087-1092
We have synthesized SBA-15 particles and functionalized their surface with different functional groups (amine, diamine, and sulfonic acid groups) to use them as carrier materials in drug delivery. Scanning electron microscopy (SEM), transmission electron microscopy (TEM), nitrogen sorption, and zeta potential measurements were used to characterize the synthesized particles. After surface functionalization, the surface of the sulfonic acid-functionalized particles was more acidic than that of the other particles. Using ibuprofen as a model drug, we found that the release rate increased at higher pH. Furthermore, the particles with the sulfonic acid groups exhibited higher release rate than those with the amine and diamine groups. We explained the difference in the release rate using different electrostatic interaction between drug and particle surface that was caused by the surface functionalization. These results should enable design of drug carrier materials based on the SBA-15 particles with the desired release rate. 相似文献
54.
Junhyeong Ban Kijung Kim Hyejun Jung Soonja Choe 《Journal of Industrial and Engineering Chemistry》2010,16(6):246-1049
The polystyrene spherical particles with homogeneously distributed magnetites were prepared using the conventional miniemulsion polymerization. In the first, the magnetite nanoparticles were coated with oleic acid in aqueous Fe3+/Fe2+ solution using excess ammonium hydroxide via co-precipitation method. In the second, the miniemulsion polymerization of styrene was carried out using various concentrations of potassium persulfate (KPS) as an initiator, H-08E as an emulsifier, hexadecane as a co-emulsifier and acrylic acid as a dispersing agent in the presence of oleic acid coated magnetite at 70 °C for 24 h. The particle size and its distribution of the homogeneously embedded magnetites were influenced by the concentration of the initiator (KPS) and acrylic acid (AAc). In addition, the emulsifier, H-08E, affects the size and the shape of the PS particles. The optimum conditions for the homogeneously distributed magnetite in the spherical PS particles with the narrow distribution were 5 wt.% styrene, 0.2 g KPS, 0.2 g AAc, and 0.12 g H-08E by inducing 364 nm in diameter, 12.04% in the coefficient of variation (Cv) and 22.1% of the maximum magnetite content. 相似文献
55.
Yunsung Kim Hyelim Choi Hyoungjoo Lee Dongjun Shin Jeongtak Moon Heeman Choe 《Journal of Materials Science》2011,46(21):6897-6903
Copper-cored solder can be regarded as the next-generation solder for microelectronic semiconductors exposed to harsh operating
conditions owing to its excellent sustainability under extreme thermal conditions, e.g., in microelectronic semiconductors
used in transportation systems. Cu-cored solder joints with two different coating layers, Sn–3.0Ag and Sn–1.0In, were compared
with the baseline Sn–3.0Ag–0.5Cu solder. The fracture strength and failure mode were examined using the high-speed ball-pull
and normal-speed shear tests. The Cu-cored solder joint with the Sn–1.0In plating layer exhibited the highest ball-pull and
shear strengths. In addition, it showed a much lower percentage of interface fracture between the Cu-core and plating layer
than the interface fracture percentage in the Sn–3.0Ag plating layer due to the improved wettability between the Cu-core and
Sn–1.0In plating layer. 相似文献
56.
In industrial multivariable plants, it is often the case that the plant outputs are detected not simultaneously but serially. The problem of estimating the state vector of the plant based on the data obtained from such a detection scheme is considered, and a special type of observer (referred to as a serial-sampling type) which renews its internal state whenever new data are obtained is proposed. The constructability of a serial-sampling observer and the stability of the closed-loop system which includes such an observer are theoretically studied 相似文献
57.
58.
Treatment of estrogen receptor (ER)-negative MDA-MB-468 human breast cancer cells with 10 nM 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD) induced formation of a nuclear aryl hydrocarbon (Ah) receptor complex as determined by ligand-binding and gel electrophoretic mobility shift assays. TCDD also induced CYP1A1-dependent activity in MDA-MB-468 cells, which represents the first ER-negative Ah receptor-positive human breast cancer cell line that has been identified. Treatment of this cell line with TCDD and related compounds also caused a 50% inhibition of cell growth, which resembled the growth inhibitory effects previously reported for epidermal growth factor (EGF). However, EGF expression is minimal in this cell line and is not induced by TCDD; moreover, EGF and TCDD induced a different pattern of oncogene expression and apoptosis in MDA-MB-468 cells. In contrast, TCDD caused a rapid and sustained induction of transforming growth factor alpha (TGF alpha) gene expression and secreted protein (nearly 2-fold); moreover, the growth-inhibitory effects of TCDD could be blocked by antibodies to the EGF receptor. In a separate experiment, it was shown that TGF alpha also inhibited growth of MDA-MB-468 cells. The results of this study indicate that the mechanism of growth inhibition of MDA-MB-468 cells by TCDD is due to induction of TGF alpha, which is a potent antimitogen in this cell breast cancer line. 相似文献
59.
60.
Multiresolution Random Accessible Mesh Compression 总被引:2,自引:0,他引:2