Oxidation behavior and mechanism of aluminum oxynitride (AlON) at elevated temperatures

The oxidation behavior and mechanism of aluminum oxynitride (AlON) powder exposed to air at elevated temperatures between 800°C and 1300°C was investigated by X-ray diffractometry (XRD), scanning electron microscope (SEM), electron spin resonance (ESR), nuclear magnetic resonance (NMR), and simultaneous thermogravimetry, differential thermal analysis, and mass spectrometry techniques (TG-DTA-MS). The weight of AlON gradually increases to a maximum value at 1150°C and then decreases with further heating. Meanwhile, AlON powder undergoes chemical changes, as evidenced by lattice expansion, and turns eventually into alumina. ESR spectra reveal the occurrence of lone pair electrons in the oxidized products and the intensity of corresponding resonance signal increases before disappearing with the increase in temperature. Combined with the results of NMR and TG-DTA-MS, the measured data suggest that Al-N in [AlO₃N] tetrahedron and [AlO₅N] octahedron are gradually oxidized into Al-O-N group with lone pair electrons, which causes continuous weight gain and lattice expansion. Further oxidation at higher temperatures results in alumina and N₂.     

用双层辉光等离子法在钛表面制备的Ti-Pd合金层性能研究

采用双层辉光等离子冶金技术在纯钛表面制备了Ti—Pd合金层。其深度大约为90μm，Pd含量呈梯度变化，并出现了TiPd3，TiPd2，Ti2Pd3，Ti3Pd5，TiPd，Ti4Pd等6种化合物相和Pd相。合金层在100℃的NaCl饱和溶液＋HCl溶液以及40℃的8．6％H2SO4溶液中的耐缝隙腐蚀性能优于Ti0．2Pd合金；在室温80％H2SO4的溶液中，腐蚀速率仅为0．682mm／a，是Ti0．2Pd合金的18．2％：在室温30％HCl的溶液中，表面Ti—Pd的腐蚀速率仅为0．004mm／a，是Ti0．2Pd合金的12．5％。     

中厚板轧机工作辊失效分析及对策

介绍了济钢中厚板厂使用国外高镍铬和高铬工作辊的主要失效形式 ,并对该工作辊的断裂和裂纹产生原因进行了分析 ,同时针对所存在的问题提出了对策和具体改进措施。     

THERMODYNAMICS AND PHASE EQUILIBRIUM OF Cu－Y－O，Cu－Y－S，Cu－Y－O－S LIQUID SOLUTIONS

ＴＨＥＲＭＯＤＹＮＡＭＩＣＳＡＮＤＰＨＡＳＥＥＱＵＩＬＩＢＲＩＵＭＯＦＣｕ－Ｙ－Ｏ，Ｃｕ－Ｙ－Ｓ，Ｃｕ－Ｙ－Ｏ－ＳＬＩＱＵＩＤＳＯＬＵＴＩＯＮＳ￥Ｄｕ，Ｔｉｎｇ；Ｌｉ，Ｇｕｏｄｏｎｇ（ＣｅｎｔｒａｌＩｒｏｎａｎｄＳｔｅｅｌＲｅｓｅａｒｃｈｉｎｓｔｉｔ...     

隔直电容在弧焊逆变器中抗偏磁能力的分析

本文采用状态平均法建立了隔直电容在知式焊接逆变器中抗偏磁的动态模型，并进行了动态分析，为焊接逆变器的设计提供了理论依据。     

铜金粉的颜色及其影响因素

利用分光光度计对国内外铜金粉的颜色进行了测试，研究了铜金粉的成分、微观状态对颜色的影响。结果表明：铜金粉颜色可以用色彩三要素进行描述，其中铜金粉的色相只与合金成分有关，而与铜金粉片的大小、形状及粒度分布无关；明度和纯度与铜金粉片在油墨层中定向排列状态、片的大小、形状及粒度分布有关，而与成分无关；合金成分的微小波动不会引起铜金粉色相的明显改变。     

基于Excel VBA的职称评审专家抽取系统的设计与实现

通过对职称评定过程中专家抽取流程和原则的分析,针对人工抽取的弊端,使用Excel及VBA设计实现了一个操作简单、维护方便的专家抽取系统。实践证明该系统运行可靠性强,有效提高了工作效率,真正实现了专家抽取的公开、公正和公平性。     

Generalized incremental frequency method for topological designof continuum structures for minimum dynamic compliance subject to forced vibration at a prescribed low or high value of the excitation frequency

The application of multidisciplinary design optimisation is mostly confined to bi-disciplinary systems such as fluid-structure interaction problems. High fidelity models of three disciplines involving electromagnetic-thermal-structural designs are rare. Here, the multidisciplinary optimisation of such a design is presented. The device comprises a C-shaped iron core and a single coil. The problem is decomposed using a monolithic multidisciplinary feasible architecture. The multidisciplinary analyses involve a single three-dimensional finite element mesh for transient non-linear electromagnetic, non-linear-static thermal, and linear-static structural models. During each multidisciplinary iteration the mesh is linearly morphed. A gradient based optimisation algorithm in combination with a multi-start routine is applied to the constrained mass minimisation problem. Multidisciplinary feasibility is ensured by convergence of a single coupling parameter i.e. air-gap deformation. In conclusion, some multidisciplinary optimisation, analyses, and decomposition considerations are discussed.