全文获取类型
收费全文 | 1883篇 |
免费 | 69篇 |
国内免费 | 24篇 |
专业分类
电工技术 | 81篇 |
综合类 | 1篇 |
化学工业 | 429篇 |
金属工艺 | 61篇 |
机械仪表 | 66篇 |
建筑科学 | 39篇 |
能源动力 | 79篇 |
轻工业 | 107篇 |
水利工程 | 4篇 |
石油天然气 | 1篇 |
无线电 | 203篇 |
一般工业技术 | 368篇 |
冶金工业 | 335篇 |
原子能技术 | 55篇 |
自动化技术 | 147篇 |
出版年
2023年 | 13篇 |
2022年 | 52篇 |
2021年 | 64篇 |
2020年 | 33篇 |
2019年 | 38篇 |
2018年 | 44篇 |
2017年 | 34篇 |
2016年 | 51篇 |
2015年 | 39篇 |
2014年 | 60篇 |
2013年 | 120篇 |
2012年 | 76篇 |
2011年 | 124篇 |
2010年 | 88篇 |
2009年 | 77篇 |
2008年 | 84篇 |
2007年 | 56篇 |
2006年 | 59篇 |
2005年 | 62篇 |
2004年 | 46篇 |
2003年 | 48篇 |
2002年 | 48篇 |
2001年 | 31篇 |
2000年 | 24篇 |
1999年 | 40篇 |
1998年 | 120篇 |
1997年 | 82篇 |
1996年 | 54篇 |
1995年 | 36篇 |
1994年 | 34篇 |
1993年 | 37篇 |
1992年 | 15篇 |
1991年 | 24篇 |
1990年 | 13篇 |
1989年 | 26篇 |
1988年 | 18篇 |
1987年 | 12篇 |
1986年 | 10篇 |
1985年 | 9篇 |
1984年 | 9篇 |
1983年 | 13篇 |
1982年 | 7篇 |
1981年 | 8篇 |
1980年 | 3篇 |
1978年 | 3篇 |
1977年 | 9篇 |
1976年 | 9篇 |
1973年 | 2篇 |
1967年 | 4篇 |
1966年 | 4篇 |
排序方式: 共有1976条查询结果,搜索用时 15 毫秒
61.
Chantamanee Poonjarernsilp Noriaki Sano Tawatchai Charinpanitkul Hiroki Mori Takeyuki Kikuchi Hajime Tamon 《Carbon》2011,(14):4920-4927
Single-walled carbon nanohorns (SWCNHs) hybridized with palladium (Pd) nanoparticles were synthesized by a single-step gas-injected arc-in-water method (GI-AIW) with a Pd wire inserted inside the anode hole. In the arc zone, carbon and Pd were vaporized simultaneously, leading to the formation of hybrid material of SWCNHs and Pd nanoparticles due to effective quenching. Based on TEM and CO chemisorption analyses, Pd nanoparticles were found to be embedded inside SWCNH aggregates. The size of Pd nanoparticles, determined by X-ray diffraction, was in the range of 3–6 nm when Pd wires with diameters of 0.1 and 0.3 mm were used. Using a Pd wire with a diameter larger than 0.5 mm results in larger Pd nanoparticles which tend to be exposed to the outer surface of the hybrid material. According to thermogravimetric analyses, the weight fraction of Pd nanoparticles is increased by increasing the Pd wire diameter although the yield of Pd nanoparticles decreased. SWCNHs hybridized with dispersed Pd nanoparticles, synthesized with 0.1 mm Pd wire, exhibited strong anti-oxidation resistance with a highly graphitic structure. 相似文献
62.
63.
Eiichi Obataya Yuhzo Furuta Yoshitaka Ohno Misato Norimoto Bunichiro Tomita 《应用聚合物科学杂志》2002,83(11):2288-2294
The effects of aging and moisture on the dynamic viscoelastic properties of three oriental lacquer films were investigated. With aging over 1000 days at room temperature, the glass‐transition temperature of the lacquer films (Tα) shifted to higher temperatures, the maximum loss tangent (tanδα) decreased, and the storage modulus at 20°C (E) increased. These changes were analogous irrespective of lacquers. With increasing moisture content, E decreased and tanδ increased at room temperature. Although the equilibrium moisture content of the virgin lacquer (sap) film was higher than that of the clear lacquer film, its E and tanδ were more stable with an increase of moisture content. It was speculated that the polysaccharides aggregated in the sap film did not effectively contribute to the mechanical properties of the film, while their hygroscopicity resulted in higher moisture content. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 83: 2288–2294, 2002 相似文献
64.
MAMMOS(Magnetic Amplifying Magneto- Optical System:磁畴扩大磁光系统 )是实现高密度磁光盘的有效方法。不仅能得到不依赖于磁畴长度的较大的读出信号振幅,而且还能实现超出光学系统衍射极限的分辨率。过去,为实现磁畴的复印与扩大,要对记录膜面施加垂直方向的外部磁场。而现在得知,同时施加垂直磁场和水平方向的磁场,可大幅度地提高微小磁畴的读出特性。确认采用施加水平磁场的方法,在λ =635 nm, NA=0.55的条件下, 0.15μ m的连续磁畴也能获得 BER=2× 10- 4的读出效果。 相似文献
65.
Hironao Ogura Hiroki Ishida Ryuta Yokooji Hiroyuki Kage Yoshizo Matsuno Arun S. Mujumdar 《Drying Technology》2001,19(7):1461-1477
The authors have been studying Chemical Heat Pumps (CHP) from the viewpoints of energy saving and environmental impact. The CHP can store thermal energy in the form of chemical energy by an endothermic reaction, and release it at various temperature levels during heat demand periods by exo/endothermic reactions. The authors have proposed in an earlier study a novel chemical heat pump (CHP) system for environmentally-friendly effective utilization of thermal energy in drying as a chemical heat pump dryer (CHPD). In this exploratory study, we test the effectiveness of operating the proposed CHPDs experimentally. Basic experiments on the CHPDs such as hot dry air production for convective drying are performed on lab-scale CHPD apparatuses using gas-solid reactions in calcium oxide/calcium hydroxide reactant beds. The proposed CHPDs are found to produce hot air by CHP operation for drying. The temperature levels of the produced hot air and the reaction rates/conversions are as good as in the case of hot water supply system using basically same CHP operation. The cold heat for air dehumidification is also found to be generated/recovered by the same CHPD system. The generated heat amounts can be increased by changing the operating conditions although the heat recovery must be enhanced for practical application of CHPDs. 相似文献
66.
67.
Paresh Parekh Sayaka Ohno Shin‐ichi Yusa Chao Lv Binyang Du Debes Ray Vinod Kumar Aswal Pratap Bahadur 《Polymer International》2020,69(11):1113-1121
Poly(ethylene oxide)–poly(propylene oxide)–poly(ethylene oxide) (PEO–PPO–PEO) triblock copolymer (Pluronic F127) was modified by introducing poly(N‐isopropylacrylamide) (PNIPAM) at both the PEO ends, and the pentablock copolymer (PNIPAM41–F127–PNIPAM41, PN41) so prepared was characterized using gel permeation chromatography and 1H NMR spectroscopy. The degree of polymerization of NIPAM blocks at the two ends was 41. The solution behaviour and microstructure of PN41 aggregates in water were examined using UV–visible spectroscopy, micro‐differential scanning calorimetry and small‐angle neutron scattering (SANS) and compared with F127. Two lower critical solution temperatures (LCSTs) were observed for the pentablock copolymer, corresponding to PPO and PNIPAM blocks, respectively. The adsorption of PN41 on thiol‐grafted hydrophobic gold surfaces at various temperatures was investigated using a quartz crystal microbalance. It was found that the adsorption behaviour and mechanism of PN41 were mainly determined by the interactions of the pentablock copolymers with different chain conformations in dilute aqueous solutions at various temperatures. SANS measurements were used to determine the temperature‐dependent structural evolution of polymer micelles in aqueous solution. A NOESY study revealed that above the LSCT of PNIPAM, the interaction of PPO and PNIPAM protons increases and the distance between PPO and PNIPAM decreases. © 2019 Society of Chemical Industry 相似文献
68.
Dalia Heggo Shinichi Ookawara Teruhisa Ohno Toru Nakai Yoshihisa Matsushita Mona Gamal Eldin Masahiro Ohshima 《加拿大化工杂志》2020,98(1):119-126
Dense photocatalyst slurry was employed for the synthesis of p-anisaldehyde under solar light irradiation. An Fe-modified rutile TiO 2 (Fe-TiO 2, 34.5 m 2/g) photocatalyst was used as a visible-light-responsive photocatalyst. A conventional TiO 2 (P25, 35 m 2/g) photocatalyst was also examined as a reference catalyst. XRD patterns and diffuse reflectance spectra showed that Fe-TiO 2 consists of 100 % rutile phase and absorbs more visible light compared to P25, respectively. The catalyst powder was suspended in an ethyl acetate solution of p-methoxytoluene in the mini-reactor, with oxygen bubbling, under a solar simulator, visible light, and UV LEDs. p-anisaldehyde, as a reaction product, was analyzed by sampling using gas-chromatograph. Regardless of the light source, Fe-TiO 2 always outperformed P25 in terms of both generation rates (GR) of p-anisaldehyde and energy requirements (ER). It was demonstrated that the highly dense Fe-TiO 2 slurry was efficient for the synthesis under solar light owing to the small size of the reactor. The small amount of Pt and ZrO 2 cocatalysts significantly enhanced the GR under solar light. By adopting a visible light responsive Fe-TiO 2 photocatalyst, the mini slurry-bubble reactor under solar light achieved a high GR per catalyst mass (CM), which is one to two orders higher than that reported by most previous studies with high-power lamps. 相似文献
69.
Meng Guo Masakoto Kanezashi Hiroki Nagasawa Liang Yu Kazuki Yamamoto Takahiro Gunji Toshinori Tsuru 《American Institute of Chemical Engineers》2020,66(4):e16850
Fine-tuned, molecular-composite, organosilica membranes were fabricated via the co-condensation of organosilica precursors bis(triethoxysilyl)acetylene (BTESA) and bis(triethoxysilyl)benzene (BTESB). Fourier transform infrared and UV–vis spectra confirmed the co-condensation behaviors of BTESA and BTESB. The evolution of the network structure indicated that the incorporated BTESB decreased the membrane pore size, which was determined by a modified gas translation model according to the steric effect of the phenyl groups. The incorporation of BTESB to BTESA finely tuned the membrane structure and endowed the resultant composite membrane with improved separation properties. The BTESAB 9:1 membrane (molar ratio of BTESA/BTESB was 9:1) exhibited high C3H6 permeance at 4.5 × 10−8 mol m−2 s−1 Pa−1 and a C3H6/C3H8 permeance ratio of 33 at 50°C. One of the most important developments of this study involved clearly defining the relationship between membrane pore size and C3H6/C3H8 separation performance for organosilica membranes in single and binary separation systems. 相似文献
70.
A novel saccharide sensor that displays a distinct color change resembling a “traffic signal” was developed. By copolymerizing boronic acid and amine monomers on a glass plate, a boronic acid‐containing thin film was obtained. Anionic blue and yellow dyes were adsorbed on the thin film, and the film was immersed in aqueous saccharide solutions containing a cationic red dye. With increase in the saccharide concentration in the solution, the thin film changes color from green to red via yellow. The observed distinct changes in color were attributed to a stepwise release and binding of dyes. The sensitivity of the saccharide sensor was dependent on the monomer composition of the thin film and increased with increasing the boronic acid content. The pH of the saccharide solution was another key factor affecting the sensing behavior, and glucose‐responsive color changes were significantly enhanced at pH 7.8. By optimizing these conditions, significant color changes in response to glucose were achieved. Saccharide selectivity was found to be in the following order: fructose > glucose > galactose = mannose > sucrose. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 42679. 相似文献