圆锥形零件冲压变形与成形载荷的分析

由于悬空侧壁部分的变形状态是圆锥形零件成形的关键，而径向拉应力是实现悬空部分成形的必要条件，同时也是该部分冲压成形成败的关键为此，经力学分析得出了侧壁部分径向拉应力的解析式和造成圆锥形零件破裂的最大径向拉应力的计算式。同时分析了圆锥形零件的成形载荷。     

感光乳剂熔化三要素对熔化供料的影响

本文讨论了温度、搅拌和时间三要素对感光乳剂和工艺过程的影响，指出了上述影响的后果和严格过程控制的重要性，提出克服影响的措施。     

特征X射线能谱法测定Fe^＋注入小麦种子的深度

用１１０ｋｅＶ Ｆｅ＾＋离子束垂直注入小麦种胚后，在扫描电子显微镜上沿种子纵沟剖面，在不同深度上测量Ｆｅ元素被激发出的特征Ｘ射线强度分布，结果表明分布呈指数衰减，与晶体中的热扩散分布相类似，并对此进行了讨论。     

光电微量氧分析仪的改进

简要介绍光电微量氧分析仪的改进。通过仪表几个重要特性的试验数据，概述黄磷反应室三种结构对氧与黄磷反应的影响，并应其反应机理作了理论分析。     

周期性业务流通过ATM复用器的时延抖动分析

ＡＴＭ通信网中需要传送多种业务，其中有一类是具有连续比特流的业务，这种业务的发送信元到达时间是周期性的，本文分析了一种周期性信元流通过ＡＴＭ复用器的排队模型，得出信元流排队时延的概率分布，时延抖动的自相关函数的功率谱。     

Application of Galerkin Method to Dynamical Behavior of Viscoelastic Timoshenko Beam with Finite Deformation

The motion equations governing the dynamical behavior of a viscoelasticTimoshenko beam with finite deformation are derived and simplified byGalerkin method. The viscoelastic material is assumed to obey thethree-dimensional fractional derivative constitutive relation. Thedynamical behaviors of the simplified systems with order 1 and order 2are numerically computed and compared by using the computational methodpresented by the authors. The dynamical behaviors of the systems areuniform qualitatively, but there is a little deviation quantitatively.And the truncated system with order 1 is safer than the one of order 2.It is also shown that the lower order system is reasonable. Theinfluences of the load parameter and the fractional derivative parameter(material parameter) on the deflection of the beam are consideredrespectively. The numerical methods in nonlinear dynamics, such as phasediagram, and Poincaré section, are applied to reveal dynamical behaviorsof the nonlinear viscoelastic Timoshenko beam. There are plenty ofdynamical behaviors, such as periodicity, bifurcation, quasi-periodicityand chaos in the dynamical system.     

A new approach to the mechanism of chlorine evolution: Separate examination of the kinetic steps using ac impedance on a rotating thin ring electrode

In the absence of a bulk diffusion effect, it is shown for the first time that the impedance spectra for the chlorine evolution reaction on a rotating thin ring electrode comprise three consecutive semicircles in the capacitive half of the complex plane. The first (highest frequency) semicircle is due to the charge-transfer resistance for chloride discharge and the simultaneous chlorine adsorption coupled to the double-layer capacitance. The second semicircle (around 5 Hz) is due to the adsorption and desorption of a chlorine intermediate. The third (lowest frequency, around 0.5 Hz) semicircle is due to the relaxation of surface oxygen species. The impedance data allow the steps of the overall reaction to be examined individually. On a Pt surface the rate of chloride discharge and simultaneous chlorine adsorption (the admittance of the first semicircle) is first order with respect to chloride concentration and has a potential-dependence close to 58 mV/decade. The rate of the adsorption and desorption process (the admittance of the second semicircle) is second order with respect to chloride concentration, and has a potential dependence close to 30 mV/decade. The time constant for the adsorption/desorption processes is ca 20 ms, independent of electrode potential in the range studied. These features are consistent with a mechanism in which a faster discharge reaction (Cl⁻ Cl_ad + e) is followed by a slower surface combination reaction (2Cl_ad → Cl₂), but inconsistent with mechanisms in which ion + atom desorption is predominant, the initial chloride discharge is slow, or a unipositively charged chlorine species is involved.     

沸石催化剂在甲苯甲基化中的择形催化形用

综述了影响甲苯甲基化择形催化的因素,讨论了沸石的内外表面酸中心及酸强度、沸石的孔道、反应物和产物的吸附等因素对提高对二甲苯选择性的影响。     

Hydrothermal Synthesis of Acicular Lead Titanate Fine Powders

A pure, acicular lead titanate (PbTiO₃) fine powder with a white color has been prepared by hydrothermal synthesis. It is a new phase of PbTiO₃ with I 4 symmetry, cell parameters of a = 12.358 Å and b = 14.541 Å, and a density of 6.80 g.cm⁻³. The influences of pH (12.5 to 14.4), Pb/Ti ratio (1.0 to 1.6) in the feedstock, reaction temperature (130° to 230°C), time (0.25 to 4 h), starting materials, and additives on the formation of acicular PbTiO₃ under hydrothermal conditions have been investigated. The acicular PbTiO₃ with I 4 symmetry, referred to as the PX phase, can be converted to the perovskite-type (PE phase) of PbTiO₃ at about 605°C while its acicular morphology is essentially unchanged. The preferable conditions for preparing pure acicular PX-phase PbTiO₃ are that the pH is 13.0 to 14.0, Pb/Ti ratio is >1.3, reaction temperature is 170° to 200°C, time is 0.5 to 1.0 h, titanium butoxide (Ti[O(CH₂)₃CH₃]₄) is the starting material, and poly(vinyl alcohol) is an additive. The acicular grain of the PX phase is usually less than 100 nm in diameter and more than 1000 nm in length.     

Antiferroelectric lead zirconate thin films derived from acetate precursors

Antiferroelectric lead zirconate (PbZrO₃) films derived from acetate precursors have been fabricated on Pt/Ti-coated silicon wafers and fused silica at 700 °C with an automatic dip-coating process. Films formed directly on the metallized silicon wafer showed the coexistence of perovskite and pyrochlore phases. A pre-coated titania layer of about 10 nm facilitated the formation of the desired perovskite phase. Films deposited on fused silica exhibited interactions between lead and silica which inhibited the crystallization of the films. In this case, a pre-coated titania layer in the range 50–75 nm acted as a diffusion barrier layer, allowing the formation of the perovskite phase. Antiferroelectricity in the films was confirmed by X-ray superstructure, dielectric double hysteresis loops and d.c. bias behaviour at room temperature. The corresponding transverse electro-optic properties were also measured for films deposited on fused silica.