废催化剂中钯的回收

用硫酸溶解载体－盐酸＋氧化剂浸出－离子交换提取３１－１Ａ催化剂（含Ｐｂ０．０３１％）中的钯，可获得纯度９９．９７％Ｐｄ产品，实收率〉９７％。     

基于FPGA的无线接入点硬件平台的设计与实现*

基于认证、安全及QoS等方面的研究需要,提出了基于FPGA的HostAP设计方案,并搭建了无线接入点的硬件平台,在此平台上进行了硬件的裁减与集成;设计和实现了无线接入点的硬件电路,完成了无线接入点的高速PCB布局布线.在PCB布局布线的过程中,重点解决了高速印制电路板设计中的传输线效应问题,最后进行了实际的系统测试.     

Effect of supports on the redox performance of pyrite cinder in chemical looping combustion

Chemical looping combustion (CLC) is a clean and efficient flame-free combustion technology,which combust the fuels by lattice oxygen from a solid oxygen carrier with inherent CO2 capture.The develop-ment of oxygen carriers with low cost and high redox performance is crucial to the whole efficiency of CLC process.As the solid by-product from the sulfuric acid production,pyrite cinder presented excellent redox performance as an oxygen carrier in CLC process.The main components in pyrite cinder are Fe2O3,CaSO4,Al2O3 and SiO2 in which Fe2O3 is the active component to provide lattice oxygen.In order to sys-tematic investigate the functions of supports (CaSO4,Al2O3 and SiO2) in pyrite cinder,three oxygen car-riers (Fe2O3-CaSO4,Fe2O3-Al2O3 and Fe2O3-SiO2) were prepared and evaluated in this study.The results showed that Fe2O3-CaSO4 displayed high redox activity and cycling stability in the multiple redox cycles.However,both Fe2O3-Al2O3 and Fe2O3-SiO2 experienced serious deactivation during redox reactions.It indicated that the inert Fe-Si solid solution (Fe2SiO4) was formed in the spent Fe2O3-SiO2 sample,which decreased the oxygen carrying capacity of this sample.The XPS results showed that the oxygen species on the surface of Fe2O3-CaSO4 could be fully recovered after the 20 redox cycles.It can be concluded that CaSO4 is the key to the high redox activity and cycling stability of pyrite cinder.     

A New Recycled Al–Si–Mg Alloy for Sustainable Structural Die Casting Applications

Metallurgical and Materials Transactions A - The use of secondary aluminum for structural components in the automotive industry is limited by the high Fe contents in recycled alloys which often...     

Low-Temperature Superplastic Deformation of Cold-Rolled Fe–5.6Mn–1.1Al–0.2C Steel

Metallurgical and Materials Transactions A - A cold-rolled low Al-added medium Mn steel was employed to investigate the low-temperature superplastic deformation at a relatively high initial strain...     

Effect of Heat Treatment on Microstructure and Mechanical Properties of Extruded PM Ti–6Al–4V Alloy With Deformation Flowlines

Metallurgical and Materials Transactions A - Two heat treatments, namely 955°C/2h/AC (AC = air cooling) and 955°C/4h/FC (FC = furnace cooling), were carried out on...     

Characterization of ultrafine La x Sr1−x MnO3 powder prepared by spray pyrolysis

The characterization of La _x Sr_1−x MnO₃ powders produced by spray pyrolysis using scanning electron microscopy (SEM) and transmission electron microscopy (TEM) observation, specific surface area (Brunauer-Emett-Teller), and particle size distribution measurements shows that the resultant large particles are loose agglomerates consisting of many small particles. However, the sintered tiny particles can form hard agglomerates, and the particle size increases remarkably. The structures of the powders before and after sintering were identified by x-ray diffraction (XRD). The study of the electrical property of the powder shows that the powder is a metallic conductor. In a reducing atmosphere, the powder can be decomposed. When the powder is cofired with yttria-stabilized zirconia 5% (YSZ) powder at 1200 °C for 5 h, no new phase is produced, and the powder remains a single provskite hexagonal-rhombohedral structure.     

含硫氰酸盐、硫化物固体废物中总氰化合物测定方法

实验建立了含硫氰酸盐、硫化物固体废物中总氰化合物的测定方法,采用硝酸银滴定法、异烟酸-吡唑啉酮分光光度法分别测定总氰化合物含量高、低的样品。通过条件实验优化了前处理方式、称样量和干扰去除方法。该方法测定结果的相对标准偏差为0.43%～1.33%,加入标准物质回收率为91.5%～101.5%,精密度和准确度良好,符合测定要求。     

含砷氰化尾矿回填利用污染控制技术试验研究

针对某黄金生产企业含砷氰化尾矿污染特征,开展了搅拌洗涤法、臭氧氧化法、酸化溶砷法、铁盐固砷法等多种无害化方法联合处理试验研究,旨在将该含砷氰化尾矿处理至满足氰渣规范回填利用污染控制要求。结果表明：该含砷氰化尾矿回填利用污染控制技术工艺为压滤调浆搅拌洗涤+臭氧氧化+酸化溶砷+铁盐固砷,最佳参数为原矿浆压滤后加水调浆,矿浆浓度40%,臭氧投加量0.66 g/L,酸化溶砷pH值3、曝气量0.1 m³/h、反应时间2 h,铁盐固砷七水合硫酸亚铁投加量20.0 g/L、反应时间1 h。研究结果为该黄金生产企业含砷氰化尾矿回填利用提供了技术支撑。