搅拌槽中垂直列管外壁的传热膜系数分布

在一内径为 12 0 0mm容积为 1.5m3 的搅拌槽中 ,使用CBY螺旋桨、 4 5°斜叶桨和六直叶涡轮桨 ,对牛顿流体采用量热法 ,研究了列管外壁的局部传热膜系数的分布情况。实验结果表明 ,对轴向流桨和径向流桨 ,列管外壁的局部传热膜系数有不同的分布 ;列管外壁各点的局部传热膜系数均与ε0 .197成正比。此外 ,文中还研究了桨叶离底距离、桨径等因素对列管外壁局部传热膜系数的影响。     

煤矸石混合材对标准稠度影响的灰色关联分析

利用灰色关联分析的数学方法,对利用煤矸石作水泥混合材所产生的标准稠度用水量改变的影响,做了分析。论述了不同细度水泥条件下,煤矸石粒径分布范围对水泥需水量的影响。发现了在水泥较细时,在粒径范围<5 μm下的煤矸石颗粒,对标准稠度用水量影响最大;在水泥较粗时,粒径范围在5～10 μm下的煤矸石颗粒,对标准稠度用水量影响最大。     

磺化聚芳醚酮酮催化合成顺丁烯二酸二丁酯

以交联的聚芳醚酮酮和20％发烟硫酸合成了磺化聚芳醚酮酮树脂，并用于顺丁烯二酸酐和正丁醇的催化酯化，最佳条件：醇：酐为2．5：1（物质的量比）；催化剂用量为2．5g，反应温度140－150℃，反应时间7h ，酯化率96．4％。气相色谱分析结果：顺丁烯二酸二丁酯的含量达99．96％，催化剂易回收且可重复使用。     

可双固化树枝形聚酰胺-胺树脂的合成及其涂膜性能研究

探讨了以乙二胺与丙烯酸甲酯交替反应，制备了1．5，2．5代树枝形聚酰胺一胺树脂（PAMAM），对其用甲基丙烯酸缩水甘油酯（GMA）和γ-氨丙基三乙氧基硅烷进行了改性，使其能够紫外光固化和潮气固化。热分析考查了玻璃化温度和热稳定性，并进行了硬度、光泽、光固化速度、潮气固化速度、附着力、柔韧性等测试。     

3D Shape Segmentation and Labeling via Extreme Learning Machine

We propose a fast method for 3D shape segmentation and labeling via Extreme Learning Machine (ELM). Given a set of example shapes with labeled segmentation, we train an ELM classifier and use it to produce initial segmentation for test shapes. Based on the initial segmentation, we compute the final smooth segmentation through a graph‐cut optimization constrained by the super‐face boundaries obtained by over‐segmentation and the active contours computed from ELM segmentation. Experimental results show that our method achieves comparable results against the state‐of‐the‐arts, but reduces the training time by approximately two orders of magnitude, both for face‐level and super‐face‐level, making it scale well for large datasets. Based on such notable improvement, we demonstrate the application of our method for fast online sequential learning for 3D shape segmentation at face level, as well as realtime sequential learning at super‐face level.     

Preparation and properties of compatibilized PVC/SMA‐g‐PA6 blends

The morphology and mechanical properties of PVC/SMA‐g‐PA6 blends were investigated in this paper. Graft to polymer SMA‐g‐PA6 was prepared via a solution graft reaction between SMA and PA6. FTIR test evidences the occurrence of the graft reaction between SMA and PA6. DSC analysis shows that SMA‐g‐PA6 has a lower melting point of 187°C, which may result in a decrease in crystallinity of PA6 and thus enable efficient blending of SMA‐g‐PA6 and PVC. Compatibilization was evidenced by the dramatic increase in mechanical properties, the smaller particle size and finer dispersion of PA6 in PVC matrix, and, further, a cocontinuous morphology at 16 wt % SMA‐g‐PA6 content. SMA‐g‐PA6 from the solution graft reaction can toughen and reinforce PVC material. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 94: 432–439, 2004     

Ultrasound as a Tool to Synthesize Nano-Sized Silica–Alumina Catalysts with Controlled Mesoporous Distribution by a Novel Sol–Gel Process

A novel sol–gel process is used to synthesize mesoporous silica–alumina catalysts with controlled pore size distribution without using templates or pore-regulating agents. The nitrogen sorption analysis shows that the synthesized materials have high specific surface area in the range 587–692 m²/g and similar mesoporous distribution within 2–11 nm. Ultrasound is applied to prepare precursor silica–alumina sol with narrow particle diameter distribution. By calculation, it is found that ultrasonic treatment is able to provide 22.94 kJ/mol energy, which is just in accordance with the weak bond's bonding energy. Based on the calculation result, it is proposed that the role of ultrasonic treatment followed by acid peptization is to provide energy to break down the weak bonds. After gelation, the regular and close packing of similar-sized sol particles is capable of formation of controlled-sized interstices which are the precursors of mesopores. Solid-state ²⁷Al MAS NMR and TEM are used to characterize the samples' structure and particle morphology. They show that most of the aluminum is located in the tetrahedral position in the present materials. According to TEM results, it is shown that the synthesized materials have spherical particles with size of about 15 nm.     

MH对EBA阻燃及热降解行为影响

采用极限氧指数法、热重分析和差示扫描量热分析等技术和手段研究了氢氧化镁（MH）对乙烯-丙烯酸丁酯共聚物（EBA）的阻燃性能、力学性能及热降解行为的影响。结果表明：EBA／MH复合材料的拉伸强度、断裂伸长率和熔体流动速率均随着MH用量的增加而降低；当MH的质量分数为60％时，复合材料的极限氧指数可达34．3％；MH通过分解吸热可提高EBA的热稳定性；MH表面羟基与EBA的反应性基团发生相互作用，以及EBA发生酯裂解后形成的羧酸与MH反应形成热稳定性更高的离聚物，均可提高EBA在高温下的热稳定性，并改变EBA的热降解历程。MH的“热阱”机理对EBA的阻燃起着很重要的作用。     

影响建陶产品生命周期因素的分析与探讨

本文从建陶产品生命周期缩短的现象入手，应用产品生命周期理论和相关的数学模型，对建陶产品生命周期的各个影响因素进行了分析和探讨。