Erosion und Korrosion of metallischer Werkstoffe in feststoffhaltigen Wässern

Erosion and corrosion of metallic materials in particle containing aqueous solutions The combined effect and mutual influence, respectively, of erosion and corrosion of metallic materials in particle containing flows was investigated. Materials under investigation are carbon steel of different hardness levels, ferritic chromium steel, austenitic stainless steel and brass. Corrosive medium was deionized water, acid (pH 4.5), alkaline (pH 10) and chloride (3% NaCl) solution. Quartz particles were used as abrasive at various particle concentrations, grain sizes and flow velocities. For comparison, tests were performed with pure water and under conditions of idle corrosion. Mechanical or corrosive influences dominate depending on material and test conditions, in some cases, synergistic effects of both mechanisms cause an increased mass loss.     

Alcohol consumption as a self-handicapping strategy in women.

Assessed whether women self-handicap with alcohol consumption prior to engaging in a social evaluation task, which may be more relevant to their self-esteem than the intellectual tasks used in past self-handicapping studies on substance use. 113 women (aged 19–32 yrs), who were evaluated as normal drinkers, performed either a solvable or an insolvable social judgment task and then received either success feedback or no feedback. Ss received access to alcoholic and nonalcoholic beverages while awaiting a retest. The study terminated before the retest. The self-handicapping hypothesis that noncontingent success would produce relatively greater alcohol consumption was not supported. Regardless of feedback, insolvable test Ss consumed more alcohol than did solvable test Ss. Findings suggest that the hypothesis may be limited as a general model of alcohol consumption in both sexes. (13 ref) (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

IDENTIFICATION OF VOLATILE COMPOUNDS FROM RIPE MAYHAW FRUIT (CRATAEGUS OPACA,C. AESTIVALIS,AND C. RUFULA)1

Steam volatile fractions obtained from three commercial mayhaw cultivars and two native selections were analyzed by GC and GC/MS. Twenty-four compounds were identified. The nine major components, which comprised 70–80% of the volatile fraction, were hexanal, butyl acetate, (E)-2-hexenal, butyl butyrate, linalool, butyl hexanoate, methyl octanoate, pentyl hexanoate, and hexyl hexanoate. Minor constituents included eight esters, four terpenes, two benzenoid compounds and (E)-2-hexenol.     

BerlinTainment: an agent-based context-aware entertainment planning system

Service providers, especially in the mobile entertainment domain, are facing increasing competition. The ability to design, develop, and deploy unique context-aware entertainment services fast and easily as well as the capability to provide intuitive user interfaces becomes essential for market players. Furthermore, today's mobile world is made up of heterogeneous networks accessible via various devices with different characteristics. Progressive users have the desire to utilize the same services and access the same information content on all available devices. At the same time, service providers have to diversify their services in order to remain competitive and attract the various customer segments making up the mass market. We introduce an agent-based serviceware framework to assist service providers in developing innovative services, thus reducing the time to market of the respective applications. The realized serviceware framework offers personalization, location awareness, and the multi-access service platform, a flexible solution for ubiquitous service access. Thus, our solution allows a heterogeneous landscape of end devices to access an application server's mobile services in a multimodal, multilingual, and multimedia-based manner. We describe the utilization of the different modules of the service framework as well as the BerlinTainment application, an entertainment planning system based on the framework.     

Mechanism of the skeletal isomerisation of linear butenes over ferrierite: analysis of side reactions

An investigation of the effect of reaction conditions on product distribution in the skeletal isomerisation reaction of linear butenes has been carried out. The main reaction routes over ferrierite have been identified. Beside the main product isobutene, major by-product formation occurs. The unwanted reactions include dimerisation of butene to form octenes, hydrogen transfer yielding small amounts of saturated C₃ and C₄ hydrocarbons and disproportionation producing propene and pentenes. The most abundant by-products were pentene and propene, though these were not formed in equimolar amounts as could be expected. Oligomerisation experiments of propene over ferrierite produced large amounts of butene and pentene, revealing the presence of adsorbed nonene. The cracking of this surface species to hexene and propene is the most likely reaction route for the excess propene formation. This additional path to propene formation operates mainly at temperatures above 623 K.     

Fast-converging minimum frequency error RLS lattice filter for narrowband interference with discrete frequency steps

This paper discusses the fundamental convergence and frequency tracking properties of the recursive-least-squares (RLS) lattice filter in the presence of narrowband interference (NBI) whose frequency varies in discrete steps. It is shown for filters of this type, that the residual forward energy (RFE) after a frequency transition is a function of the input signal-to-noise ratio (SNR), separation of the sequential frequencies and the filter time constant and is exponentially decaying in nature. Reducing the RFE is important in removing unwanted transient artefacts from the desired signal. The convergence behaviour of the RLS algorithm based on a posteriori estimation errors is analysed under a number of conditions by varying the SNR and frequency step size. In order to limit the impact of the RFE while maintaining a minimum frequency tracking error in steady conditions, a fast-converging minimum frequency error (FCMFE) RLS lattice filter is suggested. For comparison, a least-mean-square (LMS) based gradient-adaptive lattice (GAL) filter is also analysed for this class of narrowband interference.     

Synthesis of 2,7‐Carbazolenevinylene‐Based Copolymers and Characterization of Their Photovoltaic Properties

New electroactive and photoactive conjugated copolymers consisting of alternating 2,7‐carbazole and oligothiophene moieties linked by vinylene groups have been developed. Different oligothiophene units have been introduced to study the relationship between the polymer structure and the electronic properties. The resulting copolymers are characterized by UV‐vis spectroscopy, size‐exclusion chromatography, and thermal and electrochemical analyses. Bulk heterojunction photovoltaic cells from different copolymers and a soluble fullerene derivative, [6,6]‐phenyl‐C₆₁ butyric acid methyl ester, have been fabricated, and promising preliminary results are obtained. For instance, non‐optimized devices using poly(N‐(4‐octyloxyphenyl)‐2,7‐carbazolenevinylene‐alt‐3″,4″‐dihexyl‐2,2′;5′,2″;5″,2″′;5″′,2″″‐quinquethiophenevinylene 1″,1″‐dioxide) as an absorbing and hole‐carrier semiconductor exhibit power conversion efficiency up to 0.8 % under air mass (AM) 1.5 illumination. These features make 2,7‐carbazolenevinylene‐based and related polymers attractive candidates for solar‐cell applications.     

Direct synthesis of copper faujasite

Copper containing faujasite has been successfully prepared for the first time using a direct synthesis method. Faujasite type zeolite can be prepared in the presence of copper species by tuning the synthesis conditions. Ammonium hydroxide was used to form a copper complex that was later mixed with the reacting gel. Sodium is required to obtain copper faujasite. The complete elimination of sodium ions from the starting gel produces amorphous material. Crystallization took place at 358 K for 11 days. Crystallization temperature of 373 K produces ANA type zeolite as an impurity. Increasing by two times the amount of copper complex added to the reacting gel increases the crystallization time of Cu-FAU from 11 to 20 days (the crystallization rate decreases). The copper containing faujasite obtained was characterized by XRD, FESEM, EDX, EPR, FT-IR, TPR, and BET. According to the XRD pattern only FAU type zeolite was obtained. According to TPR experiments, the reduction temperature for Cu²⁺ ions present in Cu-FAU prepared by direct synthesis was 70 K more than for Cu-FAU prepared by ion-exchange. This difference can be due to the different location of the copper ions in the supercages or in the sodalite cages of the faujasite.