SBA-15 mesoporous silica modified with rhodium by MDD method and its catalytic role for N<Subscript>2</Subscript>O decomposition reaction

SBA-15 mesoporous silicas modified with rhodium were studied as catalysts for the N₂O decomposition reaction. Rhodium was deposited on SBA-15 by the Molecular Designed Dispersion (MDD) method using Rh(acac)₃ as a precursor of active phase. The same method was used for the deposition of Cu, Fe, Al and Ti. The SBA-15 support modified with metals were characterized with respect to metal loading (EPMA), structure (XRD), texture (BET), morphology (SEM), Rh dispersion (oxygen chemisorption), surface acidity (pyridine adsorption) and chemical nature of introduced copper and iron species (UV–vis-DRS). The rhodium-containing SBA-15 samples were found to be active catalysts for the N₂O decomposition reaction. Deposition of Al on the Rh-loaded catalyst increased its activity. An opposite effect was observed for the samples modified with Cu and Fe.     

Experimental investigation of the effect of fuel nozzle geometry on the stability of a swirling non-premixed methane flame

An experimental investigation on the stability of a swirling non-premixed methane flame is reported in this paper. Methane gas is supplied through a central nozzle, and combustion (co-flow) air is supplied through an annulus surrounding the nozzle. Two main parameters were varied independently, which are the nozzle geometry and swirl strength; however the exit velocity of the central (fuel nozzle) jet and co-airflow were also varied to provide a wide range of test conditions. Two nozzles were tested: a contracted circular (referred to hereafter as CCN) and a rectangular (referred to hereafter as RN), which have similar equivalent diameter, D_e (defined as the diameter of a round slot having the same exit area as the nozzle geometry). The contracted circular nozzle has a diameter of 4.82 mm, and the rectangular nozzle has a diameter of 4.71 with an aspect ratio of 2:1. The swirl strength of the co-flow was varied by changing the vanes’ angle. The main results obtained from this study show that the rectangular nozzle exhibits higher entrainment and jet spreading rates compared with its CCN counterpart. In addition, the results revealed that increasing the swirl strength creates a flow recirculation zone which is larger with the RN compared with that of the corresponding CCN. These flow features associated with the RN lead to an enhanced mixing which consequently promotes better flame stability compared with its CCN counterpart.     

Synthesis,modification, and porous properties of new glycidyl methacrylate copolymers

Synthesis, copolymerization, and physicochemical properties of new, of different degrees of crosslinker tetrafunctional bis[4(2‐hydroxy‐3‐methacryloyloxypropoxy)phenyl]sulfide and glycidyl methacrylate copolymers are presented. The monomers were used for the synthesis of porous microspheres in the presence of pore‐forming diluents, decan‐1‐ol, and toluene. Influence of diluents composition on their porous structures was studied. Porous structure of the obtained microspheres in dry (from nitrogen adsorption–desorption measurements) states was studied. Their chemical structures were studied by the use of Fourier transform infrared. The number of epoxy groups of the obtained copolymers, their thermal properties (thermogravimetric analysis), and swelling characteristics in 10 solvents of different chemical nature were examined. Selected copolymers were modified by amines in the epoxide ring‐opening reaction. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011     

Taking advantage of the quasiharmonic polynomials for analysis of stationary electromagnetic fields by Trefftz's method

Contents In the paper quasi-harmonic polynomials have been applied for solving the Laplace and Poisson equations by means of Trefftz's method. These polynomials are a generalization of the commonly used harmonic polynomials for field theoretic problems of axial symmetry. The proposed method is illustrated by examples of the analysis of scalar and vector fields having axial symmetry.

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Anwendung der quasiharmonischen Polynome zur Analyse der stationären elektromagnetischen Felder mit Hilfe der Trefftzschen Methode

Übersicht In der Arbeit wird die Anwendung der sogenannten quasiharmonischen Polynome zur Lösung von Aufgaben, die mit Hilfe der Laplaceschen und Poissonschen Gleichungen beschrieben werden, nach der Methode von Trefftz vorgeschlagen. Diese Polynome sind eine Erweiterung der bisher verwendeten harmonischen Polynome auf axialsymmetrische Felder.Die vorgeschlagene Methode wird mit Hilfe von Beispielen über die Analyse von axialsymmetrischen Skalar- und Vektorfeldern veranschaulicht.

     

Synthesis and Interfacial Activity of Novel Heterogemini Sulfobetaines in Aqueous Solution

Three new heterogemini sulfobetaines and their chloride salts were synthesised. The interfacial activities of the obtained chlorides in aqueous solution were studied by equilibrium and dynamic surface tension measurements. The critical micelle concentration, surface excess concentration, minimum area per surfactant molecule and standard Gibbs energy of adsorption as well as micelle lifetime and diffusion coefficient were determined. The adsorption properties and micelle lifetime of these compounds significantly depend on the length of alkyl chain. The critical micelle concentration decreases with increasing chain length of the compounds considered. The values of the diffusion coefficient of N‐alkyl‐N‐methyl‐N‐(3‐sulfopropyl)‐6‐(N‐alkyl‐N‐methylamino)hexylammonium chloride tend to decrease as the concentration is increased.     

Adsorption,Electrokinetic and Stabilizing Properties of the Guar Gum/Surfactant/Alumina System

The adsorption of non‐ionic polysaccharide guar gum (GG) in the presence of surfactants (anionic SDS, non‐ionic TX‐100, cationic CTAB and their equimolar mixtures) from their NaCl solutions onto an alumina surface (Al₂O₃) was studied spectrophotometrically. This study is important in light of the many disagreements concerning the structure and behaviour of mixtures containing polymers and surfactants at the surface of an adsorbent. The presence of surfactant caused an increase in the GG adsorption in all studied systems as a consequence of the formation of complexes. Among the single surfactants the highest increase in the GG adsorption was observed in the presence of CTAB. However, the usage of mixtures of the surfactants caused a much more effective increase in the GG adsorption on the alumina surface because of the synergistic effect of the surfactants. In order to get some information on the structure of the electrical double layer (edl), the surface charge density of alumina was determined and zeta potential measurements were conducted. The obtained data showed that the adsorption of GG or GG/surfactant complexes on the metal oxide surface strongly influences a diffused part of the edl, whereas a compact part of the edl is not affected. The colloidal stability of the alumina suspensions was measured in the presence and absence of GG and surfactants. It was found that GG and the mixtures of GG and surfactants can improve the stability of the suspensions.     

The Impact of Zeta Potential and Physicochemical Properties of TiO2‐Based Nanocomposites on Their Biological Activity

The aim of this research was to observe the relationship between zeta potential, morphology, surface area, porosity, chemical composition, and ecotoxicity of nanocomposite powders such as Au/TiO₂, Ag₂O/TiO₂, PdO/TiO₂, Ag/TiO₂/SiO₂, Ag/N(C)TiO₂, and SiO₂/TiO₂ from which Ag₂O/TiO₂, Ag/N(C)/TiO_2, and Ag/TiO₂/SiO₂ were exhibiting good antimicrobial properties. It was observed, that nanomaterials characterized by similar morphology and zeta potential revealed the similar toxic behavior. The samples of higher agglomeration and higher zeta potential, especially Ag/TiO₂/SiO₂ xerogel and TiO₂/SiO₂ aerogel were generally less ecotoxic to water organisms and plants. They were also not genotoxic in concentrations up to 500 and 250 mg/L, respectively.     

Effect of the structure of polymer inclusion membranes on zn(II) transport from chloride aqueous solutions

This article presents application of polymer inclusion membranes (PIM) containing polymer matrices: cellulose triacetate (CTA) or poly(vinyl) chloride (PVC), o‐nitrophenyloctyl ether (NPOE) as a plasticizer and phosphonium ionic liquids, i.e., trihexyltetradecylphosphonium chloride (Cyphos IL 101), bis(2,4,4‐trimethylpentyl)phosphinate (Cyphos IL 104) and tributyltetradecylphosphonium chloride (Cyphos IL 167), as carriers for Zn(II) transport from chloride medium. Cyphos IL167 application as an ion carrier in PIMs is reported for the first time. The membrane composition is found to affect Zn(II) transport significantly. SEM and AFM images show the differences in the surface morphology of PVC and CTA based membranes. Better transport abilities of CTA membranes (Zn(II) recovery factors exceed 80%) compared with those of PVC, indicate that the structural differences between the two polymers play a crucial role for the membrane permeability. The best initial flux and permeability coefficient are obtained for the membranes with Cyphos IL 101 and Cyphos IL 104 as carriers. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 42319.     

Application of the SIMS Method in Studies of Cr Segregation in Cr-Doped CoO: I, Aspects of Quantitative Analysis

Aspects of calibration of intensities of SIMS secondary ions vs concentration as well as sputtering time vs depth are considered for Cr-doped CoO. Advantages and limitations of the SIMS method in quantitative analysis of segregation-induced concentration profiles in oxide crystals are discussed. The studies indicate a substantial effect due to charging the surface during sputtering. The depth calibration was performed by using the Ta₂O₅/Ta system as a standard. Good depth resolution was revealed. The calibration dependence of Cr intensities on concentration is characterized by a wide scatter of data caused by charging the surface. Very good shape reproducibility of the intensity ratio vs depth profiles was revealed. Therefore, normalized intensity ratios can be used for calibration.     

Detonation combustion of gas mixtures using a hypervelocity projectile

This paper considers, from a unified point of view, problems of initiation of detonation combustion of a gaseous mixture using a hypervelocity projectile (HVP), The consideration is based on the energy criterion forHVP-induced detonation initiation. Experimental results are given that support the correctness of the criterion in a wide range of diameters (5–250 mm),HVP velocities (800–3500m/sec), and compositions of explosive mixtures (from active fuel-oxygen to hard-to-detonate fuel-air mixtures). The processes ofHVP interaction with an explosive mixture are classified. The previously unknown effect of jet formation of a detonation wave from a ballistic wave (at velocities less than the detonation velocities) was discovered for anHVP with a plane bow. Lavrentśev Institute of Hydrodynamics, Siberian Division, of the Russian Academy of Sciences, Novosibirsk 630090. Translated from Fizika Goreniya i Vzryva, Vol. 33, No. 5, pp. 85–102, September–October, 1997.