Biodegradable fraction of organic carbon estimated under oxic and anoxic conditions

The biodegradability of water samples is usually estimated with bioassays under oxic conditions. In order to overcome some of the drawbacks linked to the incubation of the samples in aerobic batches, a new protocol is proposed and tested, which is based on an organic carbon (OC) balance after a 45 days incubation under anoxic conditions with excess nitrate. The biodegradable fractions of organic matter obtained with the anoxic protocol are slightly lower than those obtained under oxic conditions. Several possible reasons for a systematic underestimation of the biodegradable organic matter under anoxic conditions are evaluated and discussed: a reduced microbial metabolic potential, significantly reduced degradation rates for the slowly biodegradable organic matter, an additional production of refractory organic compounds during the incubation, or the inhibition of the recycling of the organic matter stored in bacterial biomass. Nevertheless, the 7% difference observed on the biodegradable total OC estimations keeps low enough so that the anoxic protocol can be proposed as a convenient alternative to the oxic one.     

Network-controlled mobility within radio access networks based onWLAN technologies

This article presents a network-controlled approach of user terminal mobility within anIP based WirelessLAN Access Network. In a first part, this article makes a review of the mobility support, on the subject of emergingWLAN technologies asHIPERLAN/2 andIEEE 802.11, on the one hand, and, regardingIP networks as currently studied withinIETF, on the other hand. Both types ofIP mobility protocols are presented, either global mobility protocols such as MobileIP, or local mobility management protocols (micro mobility). In the next part, the overall principles of our mobility management approach are explained; this approach is based on the implementation of a new network entity dedicated to the control of user terminal mobility. The last part details a practical implementation of this approach. The implementation is carried out on the basis of Hierarchical MobileIPv6 (HMIPv6). The experimental results confirm the importance to carefully plan and control the user terminal mobility within largeIP based Access Networks, as this brings benefit to the user as well as to the operator.     

Temporal fairness guarantee in multi-rate wireless LANs for per-flow protection

Wireless LAN technologies such as IEEE 802.11a and 802.11b support high bandwidth and multi-rate data transmission to match the channel condition (i.e., signal to noise ratio). While some wireless packet fair queuing algorithms to achieve the per-flow throughput fairness have been proposed, they are not appropriate for guaranteeing QoS in multi-rate wireless LAN environments. We propose a wireless packet scheduling algorithm that uses the multi-state (multi-rate) wireless channel model and performs packet scheduling by taking into account the channel usage time of each flow. The proposed algorithm aims at per-flow protection by providing equal channel usage time for each flow. To achieve the per-flow protection, we propose a temporally fair scheduling algorithm called Contention-Aware Temporally fair Scheduling (CATS) which provides equal channel usage time for each flow. Channel usage time is defined as the sum of the packet transmission time and the contention overhead time due to the CSMA/CA mechanism. The CATS algorithm provides per-flow protection in wireless LAN environments where the channel qualities of mobile stations are dynamic over time, and where the packet sizes are application-dependent. We also extend CATS to Decentralized-CATS (D-CATS) to provide per-flow protection in the uplink transmission. Using an NS-2 simulation, we evaluate the fairness property of both CATS and D-CATS in various scenarios. Simulation results show that the throughput of mobile stations with stable link conditions is not degraded by the mobility (or link instability) of other stations or by packet size variations. D-CATS also shows less delay and less delay jitter than FIFO. In addition, since D-CATS can coordinate the number of contending mobile stations, the overall throughput is not degraded as the number of mobile stations increases. This work was supported in part by the Brain Korea 21 project of Ministry of Education and in part by the National Research Laboratory project of Ministry of Science and Technology, 2004, Korea.     

用于敞开式变电站的特高压开关设备

作为1 100 kV的UHV(特高压)输电,面临技术--生态环境的巨大挑战.变电站的UHV开关装置模块,需要的是可靠、成本/效益比好、环境友好、可维护的方案.对于这些所需的参数以及技术规范的验证,采用AIS(空气隔离变电所)技术能完全满足这些需要.介绍由瓷柱式断路器、隔离开关和NCIT(非传统互感器)所组成的UHV模块.这些装置是根据模块原理预先设计好的,其中的设备间的连接肯定允许快速安装.在变电站设备控制和检测方面,模块是预制标准化.加拿大和德国的试验站对断路器、隔离开关等独立的开关元件,在1 100 kV上做BIL、SIL和工频等绝缘试验,性能表现非常优越.因为对于特高压电压等级,IEC标准至今尚未规定,所以将根据外推法和现场数据作合理解释.瓷柱式断路器采用了最新复合绝缘体技术,在安全方面有所改进.AIS方案其他的关键技术,例如环境保护和成本,在可比的功能间,根据市场估计价值,与GIS解决方法作了比较.     

High temperature lithium cells using conversion oxide electrodes

Oxidized stainless steel electrodes containing chromium oxides without any conducting additives or binder have been successfully cycled at high temperatures (up to 100 °C) in organic solvent-based electrolytes with high reversibility. Cycling at high temperature results in an enhancement of the capacity at lower voltages, which is maintained upon cycling. After studying different electrolyte candidates, the best results were obtained using lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) dissolved in ethylene carbonate.     

Effects of polypyrrole modified electrode functionalization on potentiometric pH responses

Two functionalized polypyrrole films, poly(11-N-pyrrolylundecanoic) acid and poly(N-undecylpyrrole), were used as sensitive layers for pH sensors. The functionalized pyrrole monomers were first synthesized before carrying out their electropolymerization onto non-oxidizable electrodes. The deposits were characterized by SEM imaging, XPS and PM-IRRAS to study surface structure and composition. Poly(11-N-pyrrolylundecanoic) acid coating yielded very promising results as sensitive layer in pH sensors. Indeed, the potentiometric responses from pH 4.0 to 9.0 appeared linear, reversible, stable in time over a period of 1 month and highly selective for H⁺ ions. This behavior was attributed to carboxylic acid groups which are sensitive to proton concentration changes. This was confirmed by the fact that poly(N-undecylpyrrole) film led to potentiometric responses being pH dependent only from pH 6.0 to 9.0 with low sensitivity. Poly(11-N-pyrrolylundecanoic) acid is thus promoted to be used as sensitive layer in pH sensors.     

Outils de CAO pour I’étude des circuits autonomes non linéaires: Détermination de I’état établi et du spectre du bruit résultant

This paper presents two new algorithms for non linear autonomous circuitscad. The first software is an extension of harmonic-balance method to oscillators analysis, this one allows to determine the frequency oscillation and the steady state of all non linear oscillators. The second algorithm is based on the conversion matrix method, which allows to simulate the field effect transistor non linear oscillators phase and amplitude noise spectra. These oscillators can be realised with distributed or lumped elements.     

myo-Inositol trispyrophosphate: a novel allosteric effector of hemoglobin with high permeation selectivity across the red blood cell plasma membrane

myo‐Inositol trispyrophosphate (ITPP), a novel membrane‐permeant allosteric effector of hemoglobin (Hb), enhances the regulated oxygen release capacity of red blood cells, thus counteracting the effects of hypoxia in diseases such as cancer and cardiovascular ailments. ITPP‐induced shifting of the oxygen–hemoglobin equilibrium curve in red blood cells (RBCs) was inhibited by DIDS and NAP‐taurine, indicating that band 3 protein, an anion transporter mainly localized on the RBC membrane, allows ITPP entry into RBCs. The maximum intracellular concentration of ITPP, determined by ion chromatography, was 5.5×10^?3 M , whereas a drop in concentration to the limit of detection was observed in NAP‐taurine‐treated RBCs. The dissociation constant of ITPP binding to RBC ghosts was found to be 1.72×10^?5 M . All data obtained indicate that ITPP uptake is mediated by band 3 protein and is thus highly tissue‐selective towards RBCs, a feature of major importance for its potential therapeutic use.     

Biomonitoring of the adverse effects induced by the chronic exposure to lead and cadmium on kidney function: usefulness of alpha-glutathione S-transferase

A successful prevention of renal diseases induced by occupational exposure to lead (Pb) and/or cadmium (Cd) largely relies on the capability to detect nephrotoxic effects at a stage when they are still reversible or at least not yet compromising renal function. Hence, the aim of this cross-sectional study was to evaluate the usefulness of a set of early biological markers of oxidative stress or nephrotoxicity for the biomonitoring of workers occupationally exposed to Pb and/or Cd in a non-ferrous metal smelter, and gender, age, socioeconomic status, smoking habits, and drug use-matched control individuals. In exposed subjects, mean levels of Pb in blood and urine were also 387.1+/-99.1 microg Pb/L (1.868+/-0.478 micromol Pb/L) and 217.7+/-117.7 microg Pb/g creatinine (1.051+/-0.568 micromol Pb/g creatinine), and mean levels of Cd in blood and urine were 3.26+/-2.11 microg Cd/L (0.029+/-0.019 micromol Cd/L) and 2.51+/-1.89 microg Cd/g creatinine (0.022+/-0.017 micromol Cd/g creatinine), suggesting thereby relatively low occupational exposure levels. Statistically significant variations in zinc protoporphyrin, malondialdehyde, retinol binding protein, alpha-glutathione S-transferase, and urinary protein levels were reported between the two groups, and were closely correlated with Pb and/or Cd exposure levels. Variations in alphaGST levels were closely associated with Pb exposure. Taken together, these results suggest the use of alpha-glutathione S-transferase excretion in urine as a hallmark of early changes in the proximal tubular integrity.