Studies on high density polyethylene (HDPE) functionalized by ultraviolet irradiation and its application

The structure and properties of high density polyethylene (HDPE) functionalized by ultraviolet irradiation at different light intensities in air were studied by electron analysis, FTIR spectroscopy, contact angle with water, differential scanning calorimetry and mechanical properties measurement. The results show that oxygen‐containing groups such as C?O, C—O and C(?O)O were introduced onto the molecular chain of HDPE following irradiation, and the rate and efficiency of HDPE functionalization increased with enhancement of irradiation intensity. After irradiation, the melting temperature, contact angle with water and notched impact strength of HDPE decreased, the degree of crystallinity increased, and their variation amplitude increased with irradiation intensity. Compared with HDPE, the yield strength of HDPE irradiated at lower light intensity (32 W m^?2 and 45 W m^?2) increases monotonically with irradiation time, and the yield strength of HDPE irradiated at higher light intensity (78 W m^?2) increases up to 48 h and then decreased with further increase in irradiation time. The irradiated HDPE behaved as a compatibilizer in HDPE/polycarbonate (PC) blends, and the interface bonding between HDPE and PC was ameliorated. After adding 20 wt% HDPE irradiated at 78 W m^?2 irradiation intensity for 24 h to HDPE/PC blends, the tensile yield strength and notched Izod impact strength of the blend were increased from 26.3 MPa and 51 J m^?1 to 30.2 MPa and 158 J m^?1, respectively. Copyright © 2003 Society of Chemical Industry     

农村通信如何"突围"

农村通信作为农村地区信息化的基础，对于全面建设小康具有特殊的重要地位。介绍了我国农村通信的发展现状，分析了农村通信发展的困难压其原因，最后对农村压边远、欠发达地区通信的均衡震展提出了一些建议。     

论建立动态勘探目标评价体系的迫切必要性

从国际上通行的油气勘探评价工作重点,中国石油所面临的"已逐步进入一个不断在老区范围内开展精细勘探、在老区范围内开展新区块、新层系勘探以获得主要的储量增长"的新的勘探形势,现有地质研究中各专题研究与具体勘探目标评价脱节等多个方面,论述了在中国石油内部建立一套动态勘探目标评价体系的迫切必要性;并在此基础上阐述了一个完整的动态勘探目标评价体系应包括的主要内容;最后对该体系的建设进行了可行性分析。     

Monte Carlo simulation of gas phase polymerization of 1,3‐butadiene. Part II: Kinetics optimization and confirmation

Studies on the deactivations and initiations of gas phase polymerizations of 1,3‐butadiene have been achieved by Monte Carlo simulation. Initiation and deactivation control the reaction before and after the peak of the polymerization rate, respectively. The influence of polymerization temperature has been studied. Monte Carlo modeling of polymerization kinetics and mechanism was confirmed by the agreement of experimental data and simulation results of polymerizations run with a temporary evacuation of monomer. The balance of catalysts and active chains is established by both initiation and chain transfer reactions with cocatalyst, which causes a ‘pseudo‐stability’ stage. © 2003 Society of Chemical Industry     

热管传热性能对小型热管换热器散热效能影响

在零重力辅助下,小热管热阻是小型热管换热器散热效能的重要影响因素之一。基于集总参数法对于换热器系统数值计算的高效性思想,建立了热管、热管换热器的集总参数模型。对同一热管换热器选用不同传热性能的热管,在不同传热温差和流体质量流速下,就其散热效能进行了数值计算。计算结果表明,在零重力辅助下,热管换热器管内热阻存在一临界值Rcri。当热阻RHP≤Rcri时,管外热阻起主导作用,热管换热器的散热效能εh几乎不随热管管内热阻的值而变化。     

应用数字PWM器件SA4828的大功率直流电源

本文介绍一种智能型、高精度PWR控制器SA4828，其控制实行全数字化产生三相脉宽调制波形．本文采用此器件设计大功率直流电源应用于22KW直流电机测试，对感性负载表现出具有纹波小，响应迅速、硬件电路简洁、控制简单易于编写的优点。     

全球宽带电话市场分析

近两年．IP电话又叫网络电话的发展受到全球的关注。随着宽带接入的发展，基于宽带接入提供的网络电话具有了更大的生命力。从宽带电话的经营模式出发，探究这类业务的出现时现有话音业务市场的影响，进而分析这类业务的发展前景。     

岩石物理横波速度曲线计算技术

横波速度是地震勘探中的重要参数。针对实际生产中缺乏横波速度测井曲线资料，利用经验公式计算精确度不高的问题，通过对横波速度计算理论模型的研究分析，选择Blot-Gassman模型法，利用岩石矿物成分、流体成分、孔隙度及密度等测井曲线进行横波速度测井曲线的计算，并对横波速度计算技术和流程进行研究。在实际工区进行了横波速度曲线计算，计算结果与实测横波吻合程度较高，误差小于10％，该技术在储层和流体识别预测的应用中取得了较好效果。     

移动运营商手机游戏业务的战略定位和发展策略探讨

分析了韩国、日本及国内运营商手机游戏业务的发展状况．探讨了手机游戏业务的模式．论述了该业务的战略定位和市场前景。从地区提供给移动通信市场对外部环境、产业链的准备是否充分以及运营商内部的资源和运营状况等三个方面阐明了手机游戏业务发展的关键因素。