Highly efficient synthesis of(R)-1,3-butanediol via anti-Prelog reduction of 4-hydroxy-2-butanone with absolute stereoselectivity by a newly isolated Pichia kudriavzevii

(R)-1,3-butanediol is an important pharmaceutical intermediate, and the synthesis of(R)-1,3-butanediol using green biological methods has recently been of interest for industrial application. Here, a novel strain QC-1 that efficiently transforms 4-hydroxy-2-butanone to(R)-1,3-butanediol was isolated from soil samples. Based on morphological, physiological, and biochemical tests and 5.8 S-internal transcribed spacer sequencing, the strain was identified as Pichia kudriavzevii QC-1. The reaction conditions were optimized to 35 ℃, pH 8.0, rotation speed 200 rpm, and 6:5 mass ratio of glucose to 4-hydroxy-2-butanone. Evaluation of the effects of 4-hydroxy-2-butanone concentrations on yield and cell survival rate showed that 85.60 g·L~(-1) product accumulated, with an enantiomeric excess of more than 99%, when 30 g·L~(-1)4-hydroxy-2-butanone was added at 0, 10, and 30 h in a 3-L bioreactor. Thus, strain QC-1 showed excellent catalytic activity and stereoselectivity for the synthesis of(R)-1,3-butanediol from 4-hydroxy-2-butanone.     

Thermodynamic modeling and phase diagram prediction of salt lake brine systems. I. Aqueous Mg2+–Ca2+–Cl− binary and ternary systems

Salt lake brine is a complex salt-water system under natural environment. Although many models can express the thermodynamic properties and phase equilibrium of electrolyte aqueous solution, the multi-temperature characteristics and predictability are still the goals of model development. In this study, a comprehensive thermodynamic model system is re-established based on the eNRTL model and some improvements: (1) new expression of long-range electrostatic term with symmetrical reference state is proposed to handle the electrolyte solution covering entire concentration range; (2) the temperature dependence of the binary interaction parameters is formulated with a Gibbs Helmholtz expression containing three temperature coefficients, the liquid parameters, which associated with Gibbs energy, enthalpy, and heat capacity contribution; and (3) liquid parameters and solid species data are regressed from properties and solubility data at full temperature range. Together the activity coefficient model, property models and parameters of liquid and solid offer a comprehensive thermodynamic model system for the typical bittern of MgCl₂–CaCl₂–H₂O binary and ternary systems, and it shows excellent agreement with the literature data for the ternary and binary systems. The successful prediction of complete phase diagram of ternary system shows that the model has the ability to deal with high concentration and high non-ideality system, and the ability to extrapolate the temperature.     

溶胶-凝胶法制备PDMS/SiO2杂化材料

采用sol-gel工艺,以正硅酸乙酯(TEOS)为无机组分前驱物,以含端羟基的聚二甲基硅氧烷(PDMS)为有机组分,分别采用盐酸、草酸、氨水、三乙醇胺为催化剂,合成了PDMS/SiO2杂化材料,讨论了催化剂、共溶剂对杂化材料的影响,考察了杂化材料收缩率及透光率.结果表明:采用草酸作催化剂合成了块状、透明的杂化材料,PDMS/SiO2杂化材料的收缩率随共溶剂用量的增加和PDMS用量的减小而增加,采用羟基含量为4%的PDMS合成的杂化材料的透明性较好.     

氢氧化锌浆体抗菌材料-抗菌涂料一体化制备技术研究

采用氢氧化锌浆体抗菌材料-抗菌涂料一体化制备技术,能缩短工序,不排放废物,节约能耗,降低成本.氢氧化锌浆体加入量和粉磨时间对涂料的基本性能有影响,合适的加入量折算的锌含量为1%,粉磨时间为40min;氢氧化锌粉体和氧化锌粉体对涂料基本性能没有影响;锌型抗菌涂料有明显的抗菌效果,氢氧化锌浆体型涂料比氢氧化锌和氧化锌粉体型涂料抗菌性能更好.     

铁系氧化物纳米晶粉/环氧树脂杂化材料的制备

采用硬脂酸凝胶法制备铁系氧化物Ba2Co2Fe2sO46纳米晶粉,并通过表征和制备机理的探讨,确定600℃、2h后处理为制备Ba2Co2Fe28O46纳米晶粉合适的条件.以此为基础制备铁系氧化物纳米晶粉/环氧树脂杂化材料,并研究了团聚现象对吸波性能的影响.     

改性纳米金刚石增强增韧医用口腔复合树脂的研究

以爆轰法合成的纳米金刚石作为填料,加入到双酚A型口腔用光固化复合树脂中,研究了纳米金刚石对树脂性能的影响.金刚石用硅烷偶联剂进行表面改性.结果发现:偶联剂化学接枝到金刚石表面,改性后的金刚石在乙醇中的分散稳定性得到提高;加入0.2%(质量分数)的改性纳米金刚石后,复合树脂的挠曲强度和硬度分别提高35.4%和29.8%,改性金刚石的增强作用明显优于未经改性的金刚石;同时金刚石的加入也改善了树脂的韧性.     

面向多无人车的目标点分配和协同路径规划算法

针对多智能体路径搜索算法在非指定式多车协同路径规划问题中路径冗长,计算效率低等缺陷,提出协同目标点分配 路径规划算法 Nutcracker-CBS。 首先构建紧耦合目标点分配 MAPF 框架,实现目标点分配和路径构建的联合寻优;针对目标点 分配模块,提出改进的星鸦优化算法,增量式求解分配问题,缩短模块用时;针对路径构建模块,提出改进的 MAPF 算法,通过回 退式约束构建机制,引入避碰路径估计的绕道机制和数据共享底层路径规划机制,提升效率和路径质量。 数据集实验中, Nutcracker-CBS 时耗相比 SOTA 算法减少 90. 37% ;目标点分配模块求解耗时减少 86. 76% ;MAPF 模块 6 s 内构建 100 辆无人车 路径,平均路径长度缩短 6. 058% 。 实际实验中路径总和与系统运行时长分别减少 55. 26% 和 61. 29% ,提升了多机器人系统的 效率,降低了路径长度。     

确保FF现场总线仪表系统开车一次成功的重要措施

信息化、数字化、网络化,已与人们的日常生活息息相关,倍受青睐。在化工厂实现网络化管理、信息化管理是工业企业发展的趋势,基于基金会现场总线技术的自控仪表在石油化工装置以其独特的技术上的特点和其它诸多的优越性,在化工自动化控制领域占据了很重要的位置。为此,在新技术、新材料、新工艺的使用上,更要认真对待,在施工的各个环节中如何确保现场总线仪表系统的正常运行尤为关键。     

Analysis and optimization of high-power pulse transformer for SXFEL

Longitudinal injection is a promising on-axis injection scheme for diffraction-limited storage rings. In the latest version of the Hefei advanced light source(HALS), both the dynamic aperture and momentum aperture have been optimized. A longitudinal injection scheme was investigated on the HALS using a doublefrequency radio frequency system. To evaluate the injection performance, various errors were considered. A series of tracking simulations were conducted, and the injection efficiency was obtained under different error levels.     

铁矿烧结过程微细颗粒物排放行为

 采用ELPI+设备(荷电低压撞击器)对铁矿烧结过程微细颗粒物进行在线检测与采样,利用场发射扫描电子显微镜(FESEM EDS)对采集的颗粒物形貌特征进行分析,研究铁矿烧结过程中微细颗粒物的排放行为。研究结果表明,PM10大量释放集中在烧结升温段,且颗粒物质量浓度与数目浓度在粒径分布上有较大差异,其中质量浓度峰值区间为5.37～10.00 μm,数目浓度峰值区间为0.10～0.16 μm;形貌特征上,微细颗粒物呈规则的球形、方块形和片状;不同粒径物质组成差异明显,其中颗粒物中的K、Na主要以KCl和NaCl的形式存在,含量随颗粒物粒级的增大而略有降低。