The Effects of Cyclic Terminal Groups in 4-Aminoazo-benzene and Related Azo Dyes: Part 21—pKa Values of Some Monoazo Dyes Derived from

Basicity values have been determined for series of monoazo dyes incorporating a pyrrolidino or a piperidino moiety. In general, the pK_a value is found to decrease as the donor capacity of the terminal nitrogen atom decreases.The basicities of the 4'-substituted piperidinoazobenzenes decrease as the electron withdrawing strength of the 4'-substituent increases. However, the pK_a values of the related pyrrolidino compounds appear to be insensitive to the substituent.     

Pressure effects on flow and fracture of Be-Al alloys

The flow and fracture behavior of Be-Al alloys were determined in tension with different levels of superimposed pressure. The Be-Al alloys were prepared by Brush Wellman, Inc. (Cleveland, OH) from prealloyed powders processed to either a hot isostatically pressed (“hipped”) or cold isostatically pressed and extruded condition. Significant effects of pressure on both the flow and ductility have been observed at room temperature, with implications on the formability of these materials. The effects of changes in processing conditions and stress state on the flow and fracture behavior are summarized in addition to both optical and scanning electron microscopy (SEM) examination of the fracture surfaces. Separate other studies on the alloy constituents (e.g., Al and Be) are also reported. The results are also compared to previous works on monolithic materials and composites tested with high pressure.     

Evaluating the solar resource: a review of problems resulting from temporal, spatial and angular variations

Accurate assessment of the availability of solar energy at the Earth's surface is hampered by difficulties associated with the variability of solar radiation in space and time and with the angular position in the sky hemisphere. This paper assesses each of these problem areas by highlighting the difficulties and the attempts to offset them. Major emphasis is placed on extrapolation and interpolation procedures, the sensitivity of inclined surfaces to variations in the solar input, numerical models for calculating the irradiance of inclined surfaces and the time scales for which these computations are valid.Finally, the reader is urged to consider the significance of these difficulties in light of both radiation measurement errors and the sensitivity of the application to imprecise determinations of the radiation environment.     

Solar pond ground heat loss to a moving water table

An analytical solution is presented that calculates the heat loss from the bottom of a solar pond (or any heated object) to a soil that contains a moving water table. The water table is treated as a fluid slab moving as a slug flow in one dimension. Edge effects and horizontal heat conduction are ignored. Both steady-state and time-dependent solutions are presented. Results are presented in terms of an effectiveness ratio—the actual heat flux divided by the steady-state heat flux resulting from a constant temperature heat sink at the depth of the water table. The only water-table parameter that strongly affects the effectiveness is the fluid capacity rate. Thus, for any potential solar pond site, a measurement of the mass flow rate of the water table combined with knowledge of the soil thermal properties will allow a good estimation of the ground heat loss expected over the lifetime of the pond.     

Evacuated-tube directional-radiating cooling system

A new type of radiative cooling system is described. The radiator makes use of nonimaging optics and evacuated-tube technology to radiate significant amounts of heat to the 3 K environment of outer space. The nonimaging optics are used to direct the radiation overhead, through the most transparent part of the 8–13 μm atmospheric window. The required optical concentration is small, and relatively simple mirror geometries are possible. The evacuated-tube technology is used to attain storage temperatures at or below the freezing point, even when dewpoint temperatures are well above the freezing point.