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61.
α-Tocopherol was reacted with methyl linoleateperoxyl radicals at 37°C. The peroxyl radicals were generated by the reaction
of methyl linoleate with a free radical initiator, 2,2′-azobis(2,4-dimethylvaleronitrile). The primary products of α-tocopherol with methyl linoleate-peroxyl radicals were isolated by
reversephase and normal-phase high performance liquid chromatography (HPLC), and their structures were characterized by ultraviolet
(UV), infrared (IR),1H and13C nuclear magnetic resonance (NMR) and mass spectrometry (MS). There were four stereoisomers of methyl 13-(8a-peroxy-α-tocopherone)-9(Z),11(E)-octadecadienoate and four stereoisomers of methyl9-(8a-peroxy-α-tocopherone)-10(E),12(Z)-octadecadienoate. 相似文献
62.
Tatsuhiko Matsumoto
Akio Kato
《Ceramics International》1990,16(6):325-331The effects of a large number of sintering aids for the densification of magnesia were examined. Al2O3, BaO, Fe2O3, P2O5, SiO2, TiO2, Y2O3 and ZrO2 are effective for the sintering of CVD-MgO powders at low doping levels. The effects of TiO2 and ZrO2 are significant. Heavy doping is harmful for densification. The eight oxides above are also effective for the sintering of seawater MgO, but the degree of effectiveness is smaller than for CVD-MgO. In the doping of BaO, P2O5, SiO2 and TiO2, which form eutectic liquids with MgO below 1600°C, there is an optimum firing temperature for densification.
Vickers hardness of doped MgO is proportional to the relative density and is unaffected by doping. Corrosion resistance of MgO ceramics for liquid PbO is also unaffected by dopants, except for P2O5. 相似文献
63.
Masamichi Akimoto Tetsuya Ishii Koji Yamagaki Kazuhisa Ohtaguchi Kozo Koide Kazunaga Yazawa 《Journal of the American Oil Chemists' Society》1990,67(12):911-915
Optimization of culture conditions for the growth rate, 5,8,11,14,17-cis-Eicosapentaenoic acid (EPA) content and EPA productivity of a bacterium isolated from Pacific mackerel intestines was investigated
by use of a culture medium containing 1.00 wt% peptone and 0.50 wt% yeast extract in an artificial sea water (ASW). Cultivation
temperature affected the growth rate and cellular EPA content of the bacterium. The cellular EPA content at 8°C was as great
as 16.8 mg/g of dry cells, which was more than two times greater than that at 25°C (7.3 mg/g of dry cells), although the growth
rate showed a maximum at 25°C. Both the yield of bacterial cells and the cellular EPA content at 25°C reached maximum values
when the pH of the culture medium was nearly 7.0 and when the concentration of ASW was 100% (v/v). Under optimum culture conditions
[25°C pH 7.0 and 100% (v/v) ASW], the amount of EPA accumulated in the cellular lipids reached 45.6 mg/L of culture broth
after 8 hr. 相似文献
64.
A new milling technique based on a focused ion beam (FIB) microsampling system is proposed to avoid the curtaining effect, commonly occurring in other FIB milling methods, in order to obtain a crosssectional device specimen with uniform thickness can be obtained for electron holographic observation. 相似文献
65.
Yoshiaki Kinemuchi Ken-ichi Mimura Atsuya Towata Kazumi Kato 《Journal of Electronic Materials》2014,43(6):2011-2016
A giant Seebeck coefficient of ?890 μV/K at 500 °C has been observed in Y0.2Sr0.8TiO3 prepared using nanocubes. Doping rare earth elements, RE, has revealed that small RE is effective to enhance the Seebeck coefficient. Through soft mode observations by Raman spectroscopy and structural calculations based on density functional theory, it has been found that the breakdown of inversion symmetry of the perovskite structure near the surface of nanocubes can be recovered by doping with small RE. Because the dielectric constant is strongly related to the surface structure in this compound, we suggest that RE doping modulates the potential barrier at the grain boundary, resulting in a pronounced energy filtering effect in Y doped SrTiO3. 相似文献
66.
Yasuhisa Oda Ken Kajiwara Koji Takahashi Atsushi Kasugai Michael A. Shapiro Richard J. Temkin Keishi Sakamoto 《Journal of Infrared, Millimeter and Terahertz Waves》2010,31(8):949-957
The preliminary results of mode measurement in the ITER relevant 40 m long transmission test line composed from 63.5 mm diameter
corrugated waveguides and miter bends are presented. The field patterns were measured by taking temperature profiles on a
paper screen placed in front of the waveguide end using an infrared imaging camera. The complex electric field at the waveguide
end was retrieved from the measured temperature profiles. As a result, the transmission power includes 87% of HE11 mode and 6% of LP11 odd (HE21+TE01) mode and small ratios of other modes. The mode content had small dependence on length of the transmission line. This result
indicated that the higher order mode content generated at the input of the transmission line is conserved and propagated through
the transmission line. This suggests that the initial RF coupling to the waveguide is critical since it affects the launcher
efficiency. 相似文献
67.
Sakai Y Yoshida H Yurimoto H Takabe K Kato N 《Journal of Bioscience and Bioengineering》1999,87(1):108-111
Fructosyl amino acid oxidase (FAOD) is the enzyme catalyzing the oxidative deglycation of Amadori compounds, such as fructosyl amino acids, yielding the corresponding amino acids, glucosone, and H(2)O(2). In a previous report, we determined the primary structures of cDNAs coding for FAODs from two fungal strains Aspergillus terreus AP1 and Penicillium janthinellum and we found that both fungal FAODs included the putative peroxisome targeting signal 1 (PTS1) at the carboxyl terminal (Yoshida, N. et al., Eur. J. Biochem., 242, 499-505, 1996). In this study, we determined the intracellular localization of FAODs in these two fungi. Subcellular fractionation experiments and immuno-electronmicroscopic observations, together with the previous findings indicated that the FAODs were localized in peroxisomes of A. terreus AP1 and P. janthinellum. These FAODs were also found to belong to a new member of "peroxisomal sarcosine oxidase family protein" in eucaryotic cells. 相似文献
68.
Kusano M Sakai Y Kato N Yoshimoto H Tamai Y 《Journal of Bioscience and Bioengineering》1999,87(5):690-692
Acetate ester synthesis was studied in vitro with the ethyl acetate-producing yeast Candida utilis. The level of enzyme activity observed for the NAD+-dependent hemiacetal dehydrogenase acting on hemiacetal, which was produced non-enzymatically from an alcohol and an aldehyde, was much greater than that for the other enzyme involved in ester synthesis, alcohol acetyltransferase. The level of ethyl acetate synthesis in vivo approximately paralleled the hemiacetal dehydrogenase (HADH) activity. The results suggest that the main pathway for ethyl acetate synthesis in C. utilis involves a novel hemiacetal dehydrogenase activity. 相似文献
69.
Kawahara T. Kawajiri Y. Kitsukawa G. Sagara K. Kawamoto Y. Akiba T. Kato S. Kawase Y. Itoh K. 《Solid-State Circuits, IEEE Journal of》1992,27(4):589-596
A 0.3-μm sub-10-ns ECL 4-Mb BiCMOS DRAM design is described. The results obtained are: (1) a V cc connection limiter with a BiCMOS output circuit is chosen due to ease of design, excellent device reliability and layout area; (2) a mostly CMOS periphery with a specific bipolar use provides better performances at high speed and low power; (3) the direct sensing scheme of a single-stage MOS preamplifier combined with a bipolar main amplifier offers high speed; and (4) the strict control of MOS transistor parameters has been proven to be more important in obtaining high speed DRAMs, based on the 4-Mb design 相似文献
70.
Yuki Akinaga Tokuhisa Kawawaki Hinano Kameko Yuki Yamazaki Kenji Yamazaki Yuhi Nakayasu Kosaku Kato Yuto Tanaka Adie Tri Hanindriyo Makito Takagi Tomomi Shimazaki Masanori Tachikawa Akira Yamakata Yuichi Negishi 《Advanced functional materials》2023,33(33):2303321
Single-atom (SA) catalysts exhibit high activity in various reactions because there are no inactive internal atoms. Accordingly, SA cocatalysts are also an active research fields regarding photocatalytic hydrogen (H2) evolution which can be generated by abundant water and sunlight. Herein, it is investigated whether 10 transition metal elements can work as an SA on graphitic carbon nitride (g-C3N4; i.e., gCN), a promising visible-light-driven photocatalyst. A method is established to prepare SA-loaded gCN at high loadings (weight of ≈3 wt.% for Cu, Ni, Pd, Pt, Rh, and Ru) by modulating the photoreduction power. Regarding Au and Ag, SAs are formed with difficulty without aggregation because of the low binding energy between gCN and the SA. An evaluation of the photocatalytic H2-evolution activity of the prepared metal SA-loaded gCN reveals that Pd, Pt, and Rh SA-loaded gCN exhibits relatively high H2-evolution efficiency per SA. Transient absorption spectroscopy and electrochemical measurements reveal the following: i) Pd SA-loaded gCN exhibits a particularly suitable electronic structure for proton adsorption and ii) therefore they exhibit the highest H2-evolution efficiency per SA than other metal SA-loaded gCN. Finally, the 8.6 times higher H2-evolution rate per active site of Pd SA is achieved than that of Pd-nanoparticles cocatalyst. 相似文献