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21.
Hongkun He Mingjiang Zhong Dominik Konkolewicz Karin Yacatto Timothy Rappold Glenn Sugar Nathaniel E. David Jeff Gelb Naomi Kotwal Arno Merkle Krzysztof Matyjaszewski 《Advanced functional materials》2013,23(37):4720-4728
The design and preparation of porous materials with controlled structures and functionalities is crucial to a variety of absorption‐ or separation‐relevant applications, including CO2 capture. Here, novel functional polymeric materials with three‐dimensionally ordered macroporous (3DOM) structures are prepared by using colloidal crystals as templates using relatively simple, rapid, and inexpensive approaches. These ordered structures are used for the reversible CO2 capture from ambient air by humidity swing. Typically, the colloidal crystal template is synthesized from polymer latex particles of poly(methyl methacrylate) (PMMA) or polystyrene (PS). To maintain the functionality of the material, it is important to prevent the porous structure collapsing, which can occur by the hydrolysis of the ester bonds in conventional crosslinkers under basic conditions. This hydrolysis can be prevented by using a water‐soluble crosslinker containing two quaternary ammonium moieties, which can be used to prepare stable porous crosslinked polymers with the monomer (vinylbenzyl)trimethylammonium chloride (VBTMACl) and using a PMMA‐based colloidal crystal template. The hydroxide‐containing monomer and dicationic crosslinker are synthesized from their chloride precursors, avoiding the ion‐exchange step which causes shrinkage of the pores. An analysis of different methods for infiltrating the monomer solution into the colloidal crystal template shows that infiltration using capillary forces leads to fewer defects than infiltration under a partial vacuum. In addition, functional macroporous films with micrometer thickness are prepared from a template of PS‐based colloidal crystals in a thin film. In general, the colloidal crystal templated materials showed improved CO2 absorption/desorption rates and swing sizes compared to a commercially available material with similar functional groups. This work could easily be extended to create a new generation of ordered macroporous polymeric materials with tunable functionalities for other applications. 相似文献
22.
Ulrich Glaser Kai Esmark Martin Streibl Christian Russ Krzysztof Domaski Mauro Ciappa Wolfgang Fichtner 《Microelectronics Reliability》2007,47(7):1044-1053
Diodes and diode strings in 90 nm and beyond technologies are investigated by measurement and device simulation. After a thorough calibration, the device simulator is utilised to achieve a better understanding and an enhanced device performance of diode strings under static and transient ESD conditions. Thereto, parasitic transistors and a so far neglected parasitic thyristor (SCR) in the diode string are regarded, exploited and optimised. 相似文献
23.
Ye Wen Selim Gurun Navraj Chohan Rich Wolski Chandra Krintz 《Journal of Signal Processing Systems》2008,50(2):115-136
Simulation is an important tool to study and analyze sensor networks. Prior work in sensor network simulation focuses on homogeneous
devices. In this paper, we present a system that performs scalable and accurate simulation of a network of heterogeneous sensor
devices, including both Stargate intermediate level devices and mote devices. We study accuracy, performance, and scalability
of our system. The results show that we can achieve accurate functional behavior for both standalone Stargate simulation and
ensemble simulation of a Stargate and motes. For motes, we have less than 4.06% cycle count error for all benchmarks and for
Stargate, we have less than 10% error for most benchmarks, and less than 12.5% error for all benchmarks. We also achieve less
than 3.6% error for all benchmarks when simulating an ensemble of Stargate and motes. Our system is also more scalable than
prior work. We can simulate 160 sensor nodes in real time speed and 2,048 sensor nodes with ten times slowdown on a 16-node
cluster.
相似文献
Chandra KrintzEmail: |
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25.
Czekierda ? Masternak T Zieliński K 《IEEE transactions on information technology in biomedicine》2012,16(4):550-560
This paper presents an evolution of a modern collaborative teleconsultation system called TeleDICOM over the period of several years. We show how new features (required from a medical point of view) can be provided, which barriers have been identified, and how these factors influence the system's architecture. A turning point in the evolution of our system was the formulation of a new architecture, fully facilitating service-oriented architecture paradigm guidelines. We therefore show how the knowledge and experience gathered during utilization of previous versions of TeleDICOM positively stimulate procedures of service-based system decomposition and business processes definition. 相似文献
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The paper presents a new form of the electrothermal model of the ferromagnetic core for SPICE and the way, in which the parameters of the model are determined. The manner of determining magnetic, geometric and thermal parameters of this model is described. The correctness of the proposed model and the manner of determining the values of the parameters are verified by comparing the calculated and measured characteristics of the selected ferromagnetic cores. 相似文献
28.
Eric Chin David Chieng Victor Teh Marek Natkaniec Krzysztof Loziak Janusz Gozdecki 《Wireless Networks》2014,20(3):379-396
Through time domain observation, typical wireless signal strength values seems to exhibit some forms of mean-reverting and discontinuous “jumps” behaviour. Motivated by this fact, we propose a wireless link prediction and triggering (LPT) technique using a modified mean-reverting Ornstein–Uhlenbeck (OU) jump diffusion process. The proposed technique which we refer as OU-LPT is an integral component of wireless mesh network monitoring system developed by ICT FP7 CARrier grade wireless MEsh Network project. In particular, we demonstrate how this technique can be applied in the context of wireless mesh networks to support link switching or handover in the event of predicted link degradation or failure. The proposed technique has also been implemented and evaluated in a real-time experimental testbed. The results show that OU-LPT technique can significantly enhance the reliability of wireless links by reducing the rate of false triggers compared to a conventional linear prediction technique and therefore offers a new direction on how wireless link prediction, triggering and switching process can be conducted in the future. 相似文献
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Flat textiles exhibiting good electric conduction are materials that find presently increasingly broad application. Electroconductive textiles belong to the group of bodies whose properties usually show flat and normal anisotropy. The paper sets out a new method for the assessment of the flat anisotropy of properties of electroconductive textile samples in multi-directions lying in the sample plane. A new textile anisotropy index is also proposed, which constitutes a criterion enabling electroconductive textiles to be classified to either the isotropic or the anisotropic product group. An electroconductive textile property anisotropy function is introduced, which is the dependence of the resistance on the sample testing direction. The resistance of the sample was determined based on a four-electrode method. The analysis of the anisotropy of electroconductive properties of selected textile samples was also made. 相似文献