Mathematical Modeling of Methane Air Conversion on a Structured Porous Metal Catalyst

A one-dimensional two-phase mathematical model of an ideal plug-flow reactor for methane air conversion on a Ni–MgO monolith catalyst on porous nickel was proposed. The model describes the methane air conversion as the result of three simultaneous reaction stages: methane deep oxidation, methane steam reforming, and reverse shift reaction. The effect of the external gas–solid mass transfer is taken into account in two variants: (i) independent diffusion and (ii) multicomponent diffusion for all mixture components. The results of modeling were used to analyze the experimental data (obtained in our previous work) on the dependence of the temperature of the front layer of the catalyst on the pressure and excess air coefficient. The best agreement between the calculation and experiment was obtained under conditions of complete external diffusion control of the exothermic stage for oxygen and the transition (between the kinetic and external diffusion) region of the endothermic stage, the kinetic effect of the endothermic stage being further limited by internal pore-diffusion resistance of the rate of this stage for methane.     

Composite materials of diamond–(Co–Cu–Sn) system with improved mechanical characteristics. Part 2. The influence of CrB<Subscript>2</Subscript> additive on the structure and properties of diamond–(Co–Cu–Sn) composite

The structural alterations in the diamond–metallic binder transition zone in the diamond(78.4Co–11.76Cu–7.84Sn–2CrB₂) composite upon its sintering in a mold in hydrogen atmosphere at 800°C for 1 h have studied versus the hot re-pressing parameters, and the influence of such alterations on physical-mechanical and tribological properties of the composites has been clarified. Adding 2 wt % CrB₂ to the starting diamond?(80Co–12Cu–8Sn) composite is shown to raise the ultimate compression strength from 816 to 1720 MPa, bending strength from 790 to 1250 MPa, and wear resistance by a factor of 2.4. The improvement of properties of the composite and the increase of its wear resistance are provided due to the formation of Cr₃C₂ nanocarbide in the transition zone and the uniform distribution of Co, CrB₂ phases and CoSn inclusions in the volume of the metallic binder.     

Correlation of Vibroacoustic Signal with Ceramic Component Wear During Frictional Interaction with a Steel Disc

Refractories and Industrial Ceramics - Complete correlation between dimensions of the wear area on specimens made of oxide-carbide ceramics and the root-mean-square value of vibration acceleration...