Charge–discharge and high temperature reaction of LiCoO2 in ionic liquid electrolytes based on cyano-substituted quaternary ammonium cation

The charge–discharge performance of LiCoO₂ positive electrode was observed in a mixed electrolyte system consisting of two ionic liquids: cyano-substituted quaternary ammonium bis(trifluoromethane)sulfoneimide (TFSI) and a same-anion salt of 1-ethyl-3-methyl imidazolium (EMI). The positive electrode exhibited a discharge capacity rather close to the theoretical one when N,N,N,N-cyanoethyl trimethyl ammonium salt was applied. Differential scanning calorimetry (DSC) studies revealed that these electrolytes exhibited exotherm only around 260 °C, 50 °C higher than conventional carbonate-based electrolytes. This is the first attempt to reveal the thermal stability of ionic liquid electrolyte under a practical situation.     

On the analysis of the umbrella antennas using the Hallen-type integral equation

Umbrella antennas of heights0.125lambdaand0.5141lambdaare numerically and experimentally analyzed, and the effect of the junction on the current distribution is discussed. A simplified Hallen-type integral equation and an integral equation for the scalar potential of the antenna composed of straight wires are formulated and applied to umbrella antennas. The integral terms in these equations are analytically reduced to single integrals, and the extended boundary condition that the electric field vanishes on the axis of the antenna is used.     

Preclinical and Clinical Evidence of Therapeutic Agents for Paclitaxel-Induced Peripheral Neuropathy

Paclitaxel is an essential drug in the chemotherapy of ovarian, non-small cell lung, breast, gastric, endometrial, and pancreatic cancers. However, it frequently causes peripheral neuropathy as a dose-limiting factor. Animal models of paclitaxel-induced peripheral neuropathy (PIPN) have been established. The mechanisms of PIPN development have been elucidated, and many drugs and agents have been proven to have neuroprotective effects in basic studies. In addition, some of these drugs have been validated in clinical studies for their inhibitory PIPN effects. This review summarizes the basic and clinical evidence for therapeutic or prophylactic effects for PIPN. In pre-clinical research, many reports exist of neuropathy inhibitors that target oxidative stress, inflammatory response, ion channels, transient receptor potential (TRP) channels, cannabinoid receptors, and the monoamine nervous system. Alternatively, very few drugs have demonstrated PIPN efficacy in clinical trials. Thus, enhancing translational research to translate pre-clinical research into clinical research is important.     

A direct determination method for ethanol concentrations in alcoholic beverages employing a eukaryote double-mediator system

A fast, direct, small-sample measurement method of ethanol determination in alcoholic drinks was established by the application of attractive characteristics of a eukaryote double-mediator (EDM) system, as previously reported. The EDM system, which consists of yeast as well as both hydrophilic and hydrophobic mediators, demonstrates superior sensitivity to organic substances. For high performance, the EDM system was reoptimised for ethanol determination with a small sample volume of only 3 μL and a short incubation time of 5 min. Under optimal conditions, a practical calibration curve for ethanol determination in alcoholic beverages was obtained between 0.5 and 50 v/v% (r = 0.997, 9 points, n = 3, average of relative standard deviation, RSD_av = 2.75%), with a detection limit of 0.5 v/v%. To characterise our ethanol determination method, the effects of pH, organic substances, carbon dioxide gas, or sodium sulphite on EDM responses were studied in detail. No notable effects of pH on EDM responses were observed; however, glucose and ascorbic acid strongly increased the EDM response to ethanol. Real sample applications were mainly performed using distilled alcoholic drinks (shochu, brandy, vodka, gin, and whisky) and several kinds of beer and similar beverages (lager, draft, low-malt, non-malt, and sugar-free). When the results with sugar-free beverages were compared with those obtained by the available enzymatic-spectrophotometric (ES) method, an excellent correlation was obtained (r = 0.990, 7 points, n = 3, RSD_av of the EDM method = 7.90%), with an excellent slope of 1.05. Finally, a yeast suspension stored at 4 °C was stable for at least 7 days, with a response reduction of 88% (RSD_av for five testing days = 4.8%).     

Microwave Synthesis of Yttrium Iron Garnet Powder

A 28 GHz microwave heating method was used to react an Fe₂O₃+ Y₂O₃ powder mixture to form yttrium iron garnet (YIG, Y₃Fe₅O₁₂) powder. The minimum temperature to form YIG was lower than the conventional (external) heating method. YIG began to form after only 70 s of irradiation, which means that the solid-state reaction proceeded very rapidly. The amounts of byproducts were controlled by the starting composition and by the Y₂O₃ particle size. The resultant YIG particle size also was controlled by the Y₂O₃ particle size.     

Microstructural Control of BaTiO3 Thick Film Fabricated by Utilizing Slide-Off Transfer Printing

Effects of fabrication conditions on the microstructure of thick BaTiO₃ films have been investigated by employing slide-off transfer printing technique. Formation of dense films with good adhesive properties was difficult when screen-printing was employed in preparing the slide-off transfer sheets (BaTiO₃ green films), irrespective of the kind of solvents used for the slurries. On the other hand, relatively dense films could be fabricated from the slide-off transfer sheet prepared by spin-coating of the slurries consisting of fine BaTiO₃ powder (particle size: ca. 0.1 m), printing oil, and 2-propanol, though cracks formed obviously. Co-addition of large BaTiO₃ particles (particle size: ca. 0.5 m) was very effective for reducing the formation of cracks, and homogenous and dense films could be fabricated by controlling the additive amount of the large particles.