In situ polymerization and characterization of polyester‐based polyurethane/nano‐silica composites

Polyester‐based polyurethane/nano‐silica composites were obtained via in situ polymerization and investigated by Fourier‐transform infrared spectroscopy (FTIR), or FTIR coupled with attenuated total reflectance (FTIR‐ATR), Transmission electron microscopy (TEM), atomic force microscopy (AFM), an Instron testing machine, dynamic mechanical analysis (DMA) and ultraviolet‐visible spectrophotometry (UV‐vis). FTIR analysis showed that in situ polymerization provoked some chemical reactions between polyester molecules and nano‐silica particles. FTIR‐ATR, TEM and AFM analyses showed that both surface and interface contained nano‐silica particles. Instron testing and DMA data showed that introducing nano‐silica particles into polyurethane enhanced the hardness, glass temperature and adhesion strength of polyurethane to the substrate, but also increased the resin viscosity. UV‐vis spectrophotometry showed that nano‐silica obtained by the fumed method did not shield UV radiation in polyurethane films. Copyright © 2003 Society of Chemical Industry     

Web-based systems design: a study of contemporary practices and an explanatory framework based on “method-in-action”

This paper reports the findings of a detailed study of Web-based systems design (WBSD) practices in Ireland based on data collected over a 3-year period (2002–2005), the objectives of which were to (1) contribute towards a richer understanding of the current “real-world” context of WBSD by characterising the profile of a typical project (team size, timeframe, nature of requirements, etc.) and identifying the key challenges, constraints, and imperatives (i.e. “mediating factors”) faced by Web-based system designers, and (2) understand how those contextual parameters and mediating factors influence the activity of WBSD as regards the selection and enactment of whatever design practices are therefore engaged (i.e. the use of methods, procedures, etc.). Data was gathered through a survey which yielded 165 usable responses, and later through a series of semi-structured qualitative interviews. Using grounded theory, an explanatory conceptual framework is derived, based on an extension of the “method-in-action” model, the application of which to WBSD has not been previously investigated in depth. It is proposed that this framework of WBSD issues is valuable in a number of ways to educators, researchers, practitioners, and method engineers.     

基于拓扑法的多关节机械手无碰路径规划

本文提出了一种基于拓扑法的多关节机械手无碰路径规划方法,文中重点讨论了三关节机械手路径规划时如何划分状态空间、判别各连通块之间的连通性以及路径搜索等问题,最后我们给出了一个实验结果以示该方法的有效性。     

0.5级电子式电能表的设计与实现

本文论述了一种普及型电子式电能表的设计原理和实现方法，具体讨论了时分割乘法器和电流互感器的组成和误差分析，最后给出测试结果。     

Sensitivity analysis of free torsional vibration frequencies of thin-walled i-beam resting on elastic foundation

The sensitivity analysis of natural frequencies of torsional vibration of thin-walled I-beams resting on a Winkler-type elastic foundation and subjected to axial static loads is discussed. The first-order variation of the frequencies due to the design variable variations is derived. The cross- ection dimensions, the beam material constants and the foundation stiffness are assumed to be the design variables. The considerations are based on the theory of thin-walled beams with nondeformable cross-section. The underintegral sensitivity coefficients of the flange width and the foundation stiffness variations for a simply supported I-beam are determined. An accuracy of approximation of the natural frequencies changes due to the design variable change, by means of their first-order variations, is also investigated.     

塔河油田特殊钻井条件下的录井技术

该文阐述了定向井、水平井和欠平衡钻井技术对传统录井方法的影响:钻时偏大、失真,岩屑细、代表性差,荧光常达12级、无意义,全烃值一般在5%以上,难以有效划分油气层;指出在特殊钻井条件下掌握设计指导思想,卡准重要层位是录井工作的关键,重点要参考组分分析数据、定量荧光分析数据和综合录井其它信息才能准确识别油气层。     

光隔离器及其相关的磁光材料

本文简要介绍了磁光隔离器的理论、结构和分类 ,并提出了该器件今后发展的几个问题 ,最后介绍了几种磁光材料     

偏振模色散统计特性的研究

利用动态方程研究了偏振模色散矢量的统计特性 ,分别用统计系综和频率系综两种方法进行数值模拟。数值结果表明 ,统计系综和频率系综两种方法的结果一致。在大归一化距离条件下 ,均方根时延的平方随归一化距离线性变化 ;偏振模色散矢量的各个分量服从高斯分布 ,差分群时延服从麦克斯韦分布 ;偏振模色散矢量弥散于整个邦加球