Detonation properties of 1,1-diamino-2,2-dinitroethene (DADNE)

1,1-Diamino-2,2-dinitroethene (DADNE, FOX-7) is an explosive of current interest. In our work, an advanced study of detonation characteristics of this explosive was performed. DADNE was prepared and recrystallized on a laboratory scale. Some sensitivity and detonation properties of DADNE were determined. The detonation performance was established by measurements of the detonation wave velocity, detonation pressure and calorimetric heat of explosion as well as the accelerating ability. The JWL (Jones-Wilkins-Lee) isentrope and the constant-gamma isentrope for the detonation products of DADNE were also found.     

Hybrid deposition of piezoelectric (11\bar 20) MgxZn1−xO (0≤x≤0.3) on (01\bar 12) R-sapphire substrates using RF sputtering and MOCVDR-sapphire substrates using RF sputtering and MOCVD

Mg_xZn_1?xO (0≤x≤0.3) films are deposited on R-plane $(01\bar 12)$ sapphire substrates using a hybrid deposition technique: metalorganic chemical vapor deposition and radiofrequency (RF) sputtering. Thick piezoelectric Mg_xZn_1?xO films are deposited by RF sputtering on MOCVD grown thin ZnO buffers on R-sapphire substrate. Molar ratio of ZnO and MgO powders are mixed to form Mg_xZn_1?xO (0≤x≤0.3) sputtering targets with NiO (2–3 wt.%) added for compensation doping to achieve piezoelectricity. Field emission scanning electron microscopy shows that the deposited films are dense and uniform. X-ray diffraction indicates that the sputter-deposited Mg_xZn_1?xO (0≤x≤0.3) films retain the wurtzite crystal structure. The crystallinity of the deposited films is further improved by postannealing at 700°C in oxygen. Compositional analysis of the films is carried out using Rutherford back-scattering. High-frequency and low-loss surface acoustic wave (SAW) testing devices fabricated on these films are demonstrated. The SAW properties are tailored to changing Mg compositions. In the ZnO/R-Al₂O₃ system, two types of wave modes, the Rayleigh-type and the Love-type wave modes, are investigated.     

Complexes of carbon nanotubes with selected carotenoids

As proven by the UV-VIS, micro-Raman spectroscopies, differential scanning calorimetry, beta-carotene, lycopene, retinoic acid, and retinol adsorbed on the surface of single-walled carbon nanotubes (SWCNT) form electron donor-acceptor (EDA) complexes. The rate of the adsorption of carotenoids is estimated as the rate of decrease in their concentration in solution followed the exponential curve equation. The rate of the adsorption decreased with the chain length of the guest capable sorption on the surface and steric effect of the terminals in the beta-carotene was also essential. Also, increase in the polarity of the functional groups expressed, for instance, in Taft sigma* substituent constants had its impact. The HyperChem 7 followed by Gaussian 03 computations revealed that the inclusion SWCNT-carotenoid complexes were more stable than corresponding surface complexes. In the surface complexes carotenoids acted as donors in respect to SWCNT whereas in the inclusion complexes they were acceptors.     

The Dominant Influence of Plastic Deformation Induced Residual Stress on the Barkhausen Effect Signal in Martensitic Steels

The paper presents the results of investigation of the influence of plastic deformation on the magnetic properties of martensitic steel (P91 grade). The properties of the hysteresis loops as well as of the Barkhausen effect (BE) signal are analysed for both tensile and compressive loading up to \(\varepsilon = 10\)% of plastic deformation. The choice of the steel and of the deformation range is unique, since for such combination one can expect high residual stresses (both compressive and tensile) in the material that does not exhibit saturation of the BE intensity as a function of elastic stress. The obtained relationships show that for the low level of deformation the dislocation density changes may play a dominant role, yet for higher deformation level the residual stress becomes a dominant factor. It leads to the strong decrease of the BE signal for tensile deformation and an increase for the case of compression. It agrees well with the assumption that the tensile plastic deformation results in the compressive stresses appearance in the soft (magnetically active) sub-regions of the material whereas for the compression one can expect a residual stress of a tensile nature in those areas. Both deformation modes result in the increase of coercivity of the samples, yet the increase observed for the tensile deformation is significantly higher since both the residual compressive stress and increase of dislocation density have a strong effect on the material coercivity. The change of the hysteresis loops steepness agrees well with the notion of the dominant role of residual stresses too.     

Faster communication in known topology radio networks

This paper concerns the communication primitives of broadcasting (one-to-all communication) and gossiping (all-to-all communication) in known topology radio networks, i.e., where for each primitive the schedule of transmissions is precomputed in advance based on full knowledge about the size and the topology of the network. The first part of the paper examines the two communication primitives in arbitrary graphs. In particular, for the broadcast task we deliver two new results: a deterministic efficient algorithm for computing a radio schedule of length D + O(log³ n), and a randomized algorithm for computing a radio schedule of length D + O(log² n). These results improve on the best currently known D + O(log⁴ n) time schedule due to Elkin and Kortsarz (Proceedings of the 16th ACM-SIAM Symposium on Discrete Algorithms, pp. 222–231, 2005). Later we propose a new (efficiently computable) deterministic schedule that uses 2D + Δlog n + O(log³ n) time units to complete the gossiping task in any radio network with size n, diameter D and max-degree Δ. Our new schedule improves and simplifies the currently best known gossiping schedule, requiring time , for any network with the diameter D = Ω(log ⁱ⁺⁴ n), where i is an arbitrary integer constant i ≥ 0, see Gąsieniec et al. (Proceedings of the 11th International Colloquium on Structural Information and Communication Complexity, vol. 3104, pp. 173–184, 2004). The second part of the paper focuses on radio communication in planar graphs, devising a new broadcasting schedule using fewer than 3D time slots. This result improves, for small values of D, on the currently best known D + O(log³ n) time schedule proposed by Elkin and Kortsarz (Proceedings of the 16th ACM-SIAM Symposium on Discrete Algorithms, pp. 222–231, 2005). Our new algorithm should be also seen as a separation result between planar and general graphs with small diameter due to the polylogarithmic inapproximability result for general graphs by Elkin and Kortsarz (Proceedings of the 7th International Workshop on Approximation Algorithms for Combinatorial Optimization Problems, vol. 3122, pp. 105–116, 2004; J. Algorithms 52(1), 8–25, 2004). The second author is supported in part by a grant from the Israel Science Foundation and by the Royal Academy of Engineering. Part of this research was performed while this author (Q. Xin) was a PhD student at The University of Liverpool.     

An Attempt to Decompose the Impact of Land Use and Climate Change on Annual Runoff in a Small Agricultural Catchment

Water Resources Management - The aims of this study are: i) to better understand the coupled interactions between land use changes, climate change and the aquatic ecosystem in a small agricultural...     

Cold chemical lamination of ceramic green tapes

The cold chemical lamination (CCL) is a new technique of bonding ceramic green tapes into one 3D structure. Instead of a standard thermo-compression method, new solvent-based lamination is presented. A film of a special chemical agent is put on the green tape surface. The solvent melts the surface. Then the tapes are stacked. The bonding of the green tapes is made at a room temperature. The new method is used for joining green tapes of the low temperature co-fired ceramics (LTCC). A quality of the bonding depends on the solvent type. The cold chemical lamination is examined on two types of the LTCC tapes: DuPont 943 and DuPont 951. Six types of the solvents are analyzed in the paper. The bonding quality and geometry of the test structures are examined. The lamination quality is investigated by the scanning electron microscope.     

Renovation of brick interceptor sewers

Brick interceptor sewers began to be built in Europe (London, Paris, Hamburg) in the 18th century. The sewers were built from solid ceramic brick (so called sewer brick) or clinker brick. This paper presents a study of damage to brick interceptor sewers built in the 19th century and at beginning of the 20th century in Poland. Damage to the sewer structure and to the surrounding ground and its causes are identified. On the basis of results of in situ investigations, laboratory tests and structural and strength analyses, the condition of sewer structures in Poland was assessed as a pre-failure one. Underground infrastructure pipes of urban areas can be repaired in trenches or using trenchless techniques. Although trenchless technologies have been known in Poland for more than 25 years, there is still the lack of knowledge and imagination on the part of designers – so different problems in renovating process of brick interceptor sewers are described.     

L* Algorithm—A Linear Computational Complexity Graph Searching Algorithm for Path Planning

The state-of-the-art graph searching algorithm applied to the optimal global path planning problem for mobile robots is the A* algorithm with the heap structured open list. In this paper, we present a novel algorithm, called the L* algorithm, which can be applied to global path planning and is faster than the A* algorithm. The structure of the open list with the use of bidirectional sublists (buckets) ensures the linear computational complexity of the L* algorithm because the nodes in the current bucket can be processed in any sequence and it is not necessary to sort the bucket. Our approach can maintain the optimality and linear computational complexity with the use of the cost expressed by floating-point numbers. The paper presents the requirements of the L* algorithm use and the proof of the admissibility of this algorithm. The experiments confirmed that the L* algorithm is faster than the A* algorithm in various path planning scenarios. We also introduced a method of estimating the execution time of the A* and the L* algorithm. The method was compared with the experimental results.