Physically Based Failure Criterion for Dimensioning of Thick-Walled Laminates

The extreme lightweight potential of modern composites for the application in highly strained and thick walled components can only be sucessfully utilized with the help of adapted design procedures. Therefore, the stress and strain analysis of fibre reinforced components has experienced a tremendous improvement in recent years. The derived mechanical methods and the existing computing facilities are now capable of calculating complex and three-dimensional states of stress for single layers within laminated structures. The adequate development of appropriate failure criteria for the evaluation of such stress states has unfortunately not been promoted in the desired manner. In 1980, Hashin proposed a new generation of physically based failure analysis which could only be realized by a considerably increased numerical effort. Recently, Puck made a new attempt based on Hashin's concept using fundamental elements of the failure criterion by Mohr and Coulomb. Applying this model, the three-dimensional state of stress is evaluated in a realistic manner. It is assumed that besides the occurence of fibre failure only tensile stresses and shear stresses in loading planes tangential to the fibre direction induce the inter-fibre failure of the unidirectionally reinforced composite, whereas compressive stresses in these planes obstruct failure.     

Si-containing copolymer of 2,3-epoxypropyl-1-methacrylate

Summary Poly-p-trimethylsilylphenylmethacrylate(75)-co-glycidylmethacrylate (25) containing aromatic bisazides exhibits uv sensitivity as a negative type photoresist. Sensitometric data have been evaluated. The pressure-dependant reactivity under the conditions of oxygen reactive ion etching was determined.     

Characterization of Palladium Nanoparticles Adsorpt on Polyacrylic Acid Particles as Hydrogenation Catalyst

Palladium particles can be prepared in sizes of a few nanometers from Pd(OAc)₂in the presence of a block copolymer in aromatic unpolar solvents with suitable reducing agents like NaBH₄ or LiAlH₄. After mixing the organic metal solution with a polyacrylic acid (PAA) dispersion of defined concentration and following a crosslinking process with an epoxide, reactive membranes with a well-defined pore diameter were obtained. The catalytic activity of the prepared palladium particles incorporated in the crosslinked PAA network has been proven by the gas phase hydrogenation of propyne in a special membrane reactor.     

Gemini Surfactants Foam Formation Ability and Foam Stability Depends on Spacer Length

A series of cationic gemini surfactants containing different spacer length were synthesized and analyzed structurally. It was shown that the surface tension (σ) and critical micelle concentration (CMC), which had a maximum for the n-C₄H₈ spacer depended on the spacer length. The foaming ability and foam stability are high for the gemini surfactants with short spacers (C₂H₄ to n-C₄H₈), while longer spacers lead to a distinct decrease of these foam parameters. Foaming properties are discussed in terms of configuration and conformation of a surfactant molecule and in relation to micellization state kinetic.     

Frequency-dependent damping model for the hydroacoustic finite element analysis of fluid-filled pipes with diameter changes

The integration of a model for longitudinal hydroacoustic fluid damping in thin hydraulic pipes in 3D finite element models is presented in this paper. In order to perform quantitative prediction of the vibroacoustic behavior and resulting noise levels of such fluid-structure coupled system due to hydraulic excitation, an accurate frequency-dependent fluid damping model including friction effects near the pipe wall is required. This step is achieved by matching complex wave numbers from analytical derivation into a parameterized damped wave equation and consecutive translation into finite element modeling.Since the friction effect close to the pipe wall changes locally with the inner pipe radius, the fluid damping model is applied segment-wise in order to model the influence of cross-sectional discontinuity, such as orifices, on the oscillating pressure pulsations. A component synthesis approach, which uses pipe segments as substructures, allows a simple model generation and fast computation times.The numerical harmonic results are compared to experimental frequency response functions, which are performed on a hydraulic test bench driven by a dynamic pressure source in the kHz-range.