Power system control method using customers' energy storage systems and the verification of proposed method

Advanced energy storage systems have been widely applied to industries and are being installed at large buildings and factories to realize efficient energy usage. This paper presents a control method involving load frequency control and distribution network control (loss reduction control) using a part of customers' owned battery capacity. When 10% of total battery capacity of 100 MW in a network of 30‐GW generator capacities is used for load frequency control, a total of 1500‐MW generation units for load frequency control, at maximum, can be stopped without deterioration of power quality. In addition, when batteries are used for loss reduction in a distribution network, 2% of the loss on a summer day can be reduced. To realize both effects to their fullest, a novel integrated control algorithm is proposed and its economic effect is evaluated by numerical simulations. © 2008 Wiley Periodicals, Inc. Electr Eng Jpn, 165(4): 11–20, 2008; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/eej.20704     

Preferential Oxidation of CO in H2-Rich Gas at Low Temperatures over Au Nanoparticles Supported on Metal Oxides

We investigated Au catalysts supported on TiO₂, Fe₂O₃, and ZnO for their preferential oxidation of CO in a H₂-rich atmosphere. Both full conversion and selectivity were achieved over Au/Fe₂O₃ and Au/ZnO around room temperature, but at higher temperatures the CO conversion was suppressed due to competition between CO and H₂.     

Chiral recognition ability of oligopeptide derivatives consisting of glutamyl residues

The effect of the constituting amino acid residue [Glu(OBzl)] number on the chiral recognition ability was investigated. Chiral recognition sites were prepared from oligopeptide derivatives (constituting amino acid residue number = three–five) by adopting alternative molecular imprinting. It was made clear that with a constituting amino acid residue number of four, the tetrapeptide derivative of Glu(OBzl) is the best candidate material to generate a chiral recognition site among eight types of oligopeptide derivatives in the study. The affinity constant between Ac‐L ‐Trp and a chiral recognition site ranged from 3.4 × 10³ to 1.08 × 10⁴ mol^?1 dm³, depending on the number of Glu(OBzl) residues in an oligopeptide derivative. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 95: 1302–1309, 2005     

Efficiency of repeated batch penicillin fermentation using two fermentors. Computer simulation and optimisation

Repeated batch operation using two fermentors (RBTF) to penicillin fermentation was demonstrated by computer simulation to improve productivity. Three operation modes were compared: chemostat, repeated batch operation using a single fermentor (RBSF) and RBTF; in each case account was made of the lag period before growth. The simulated fermentor performances were assessed on the basis of the penicillin productivity and concentration; the simulation was based on published batch fermentation data. It was shown that RBTF was superior to RBSF and chemostat. The advantage of RBTF increased as the lag period became greater.     

Electrostatic Field Variation in the Atmosphere Induced by Earth Potential Difference Variation During Seismic Wave Propagation

To clarify the relationship between earthquakes and electrical phenomena, signals of three parameters were observed continuously at Sennan in Akita Prefecture, Japan: ground acceleration (GAC), earth potential difference (EPD), and electrostatic field in the atmosphere (EFA). A large metal plate was used as an electrostatic antenna to observe EFA variation. For this paper, we used the digital natural observation (D-NOB) method as a signal processing technique and found clear EPD and EFA waveforms during seismic wave propagation. Our observation and examination results show that GAC causes EPD variation. Subsequently, the EPD variation induces EFA variation     

Damage repair in CMSX-4 alloy without fatigue life reduction penalty

The microstructural changes in a single-crystal Ni-base superalloy, CMSX-4, that might occur during the processes of repair and recoating of hot section components for advanced gas turbines were studied. It is shown that the cellular γ/γ′ microstructure is formed when the material is subjected to local plastic straining, followed by the reheat treatments during the course of damage recovery. The formation of cellular microstructure in the material led to the remarkably reduced fatigue strength. In order to reduce or prevent the preceding undesirable effect resulting from cellular microstructure, a new method based on applying overlay coating technique was developed. The method is based on an idea that the alloying elements that are depleted in base alloys could be supplemented via the overlay coating. An X alloy, which contains grain boundary strengthening elements, was selected and coated on the CMSX-4 with the cellular microstructure by low-pressure plasma spraying. The fatigue tests on the coated CMSX-4 specimens demonstrated the effectiveness of the method. The observations of the crack initiation site, the fatigue fracture mode, the crack density in the cellular transformed area, and the crack propagation morphologies near the prior interface strongly supported the validity of this approach. The method is expected to build a road to a so-called damage cure (or recovery) coating.     

Removal of Cr(VI) from aqueous solution by London plane leaves

The effect of initial metal concentration, contact time and solution temperature on the removal of Cr(VI) from solution by waste London plane leaves, generated by the pruning of street trees, was investigated in batch mode conditions. The removal of Cr(VI) was highly concentration‐dependent and mainly governed by physico‐chemical adsorption under the weak acidic conditions studied. The equilibrium data fit well in the Langmuir isotherm model. The Langmuir constants were calculated at different temperatures and both the adsorption capacity and adsorption intensity increased with rising temperature. The endothermic nature of the Cr(VI) adsorption was confirmed by the thermodynamic parameters. The study has shown that the waste leaves can be used as an effective adsorbent for removal of Cr(VI) from wastewater. Copyright © 2003 Society of Chemical Industry     

Optical Resolution Membranes from Polysulfones Bearing Alanine Derivatives as Chiral Selectors

Polysulfones bearing a derivative of alanyl residue employed as chiral selectors were prepared by polymer modification. The specific rotation ([α]_D) of the polysulfone with a derivative of D ‐alanyl residue (PSf‐Ac‐D ‐Ala) was determined to be 2.87 deg · cm² · g^?1 (c = 1.00 g · dL^?1 in DMF) and that with L ‐alanyl residue (PSf‐Ac‐L ‐Ala) to be ‐2.36 deg · cm² · g^?1 (c = 1.00 g · dL^?1 in DMF). The membrane from PSf‐Ac‐D ‐Ala preferentially adsorbed the D ‐isomer of Glu from racemic mixture of Glu and vice versa. Chiral separation ability was studied by applying a potential difference as a driving force for membrane transport. The permselectivity of PSf‐Ac‐D ‐Ala toward D ‐Glu (α_D/L) was determined to be 1.40, and that of PSf‐Ac‐L ‐Ala toward the L ‐isomer (α_L/D) to be 1.48 at 18.0 V, reflecting their adsorption selectivity.

     

Improvement of thermal stability of nitrogen doped titania photocatalyst by addition of surfactants during solvothermal treatment

The TiO_2−x N _y nanocrystals with beige color were prepared by homogeneous precipitation-solvothermal process in TiCl₃-hexamethyleneamine-alcohol solutions with the addition of various surfactants, such as sodium dodecylbenzenesulfonate (SDBS), n-hexadecylamine (HAD), and n-hexadecyltrimethylammonium chloride (HTAC) at 190 °C for 10 h. The phase composition, crystallinity, microstructure, specific surface area, nitrogen doped amount, and photocatalytic activity of titania powders greatly changed depending on pH value and other reaction conditions. The TiO_2−x N _y powders prepared by solvothermal treatment with surfactant additives followed by calcination in air at 400 °C showed smaller particle size, larger BET specific surface area and higher photocatalytic activity than those without surfactant. The TiO_2−x N _y powders showed excellent visible-light absorption, thermal stability and photocatalytic activity for nitrogen monoxide destruction under irradiation of both visible-light and UV-light irradiation. About 40% and 60% nitrogen monoxide could be continuously removed with the residence time of 1.9 min by the TiO_2−x N _y photocatalyst under irradiation of visible-light (λ > 510 nm) and UV-light (λ > 290 nm), respectively.