Study on chemical structures of poly (tetrafluoroethylene-co-perfluoroalkylvinylether) by soft-EB irradiation in solid and molten state

Poly (tetrafluoroethylene-co-perfluoroalkylvinylether) (PFA) was irradiated by soft electron beam (soft-EB) under nitrogen gas atmosphere in solid-state and its molten state, respectively. The changes of thermal property and chemical structures of irradiated PFA in solid-state and molten state were studied by differential scanning calorimetric analysis (DSC) and solid-state ¹⁹F magic angle spinning (MAS) nuclear magnetic resonance (NMR) spectroscopy. By DSC analysis, the melting temperature shifted to lower temperatures, and crystallinity decreased with increasing soft-EB dose. By solid-state ¹⁹F MAS NMR spectroscopy, the new signals was observed and the detected new signals in irradiated PFA at 315 °C and at 30 °C were due to the tertiary carbon group with branching site (Y-type crosslinking site), perfluoro-propylene site and chain end methylene groups, respectively.Moreover, the molar ratio of perfluoroalkylvinylether (FAVE) structure to -CF₂- units decreased with increasing dose.     

Low cycle fatigue behaviors of elbow pipe with local wall thinning

Low cycle fatigue tests were conducted using 100A elbow specimens made of STPT410 carbon steel with local wall thinning. Local wall thinning by erosion/corrosion was simulated by machined pipe wall thinning. The local wall thinning areas were located at three different areas, called extrados, crown and intrados. The elbow specimens were subjected to cyclic in-plane bending under displacement control without internal pressure. The effects of eroded conditions, such as eroded ratio, eroded angle and position, on the low cycle fatigue behavior and fatigue life were discussed by using experimental results and finite element analyses. Also the location of crack initiation and the crack growth direction could be predicted by three dimensional elasto-plastic finite element analyses. In addition, the safety margin of eroded elbows against seismic loading was discussed by comparing the fictitious stress of elbows with the allowable stress limit demanded by the design code.     

Impedance characteristics of double-hetero structure laser diodes

The effects of the onset of lasing on the I-V characteristics, the impedance characteristics and the light modulation characteristics of laser diodes have been discussed by introducing the rate equations which involve carrier diffusion process in the active layer interacting with the radiation field intensity. The static I-V characteristics exhibit a kink at lasing threshold current, reflecting the decrease of effective lifetime of carriers. Effective carrier lifetimes decrease with increasing light intensity, which results in a steep attenuation of injected carrier density in the active region. The impedance and light modulation characteristics are obtained in the small signal approximation. The small signal light modulation characteristics depend strongly on whether the laser diode is excited by the constant current modulation or the constant voltage modulation. The impedance is changed drastically by the onset of lasing and exhibits a resonance which coincides exactly with the optical modulation resonance frequency.     

Epitaxial growth of WOx nanorod array on W(001)

Nanorods of substoichiometric tungsten oxide (WO_x) were grown on W(001) substrates. Two methods for the growth of nanorods were used: oxidation of the substrate under appropriate conditions and the deposition of tungsten oxide from a tungsten foil heated in the presence of oxygen. The grown nanorods were observed using a scanning electron microscope and an atomic force microscope. The diameters of the nanorods were 5–20 nm. The nanorods were slightly inclined from the directions parallel or normal to the surface. The inclination of nanorods was explained in terms of the epitaxial relationship between WO₃ crystals and the W(001) substrate. The WO₃ crystals formed at the initial stage of growth act as the nuclei of WO_x nanorods. We observed selective enhancement of the growth in a certain epitaxial direction depending on the method of growth, and an array of WO_x nanorods was produced on the W(001) substrate.     

Analysis of accelerated creep under constant sustaining load for austenitic stainless steels

The effect of stress on creep rate of austenitic stainless steels of type 347 and 316 was studied by applying the differential test technique. It was found that the creep rate could be expressed as follows, whereB ₁ is a material constant depending on temperature,a ₁ anda _o are constants, and σ is the real stress. Considering the increase in real stress during creep process due to void formation and to the decrease in cross sectional area of the specimen, integrating the above equation yields the following creep curve, 1 $$ \in = \in _m + \frac{1}{{n_o \left( {c_o + 1} \right)}}ln\frac{1}{{1 - n_o \left( {c_o + 1} \right) \in _m (t - t_{_m } )}}$$ where ∈ is the creep strain at a given time (t), ∈_m is the minimum creep rate, ∈_m andt _m are the strain and time, respectively, at the minimum creep rate,n _o is a constant, andc _o is the material constant relating to the void formation. This equation agrees very well with the experimental creep curve.     

The use of epoxy patch grafts for the repair of experimentally-created diaphragmatic defects in dogs

Canine pericardium which had been treated with polyepoxy compounds (Denacol EX-313) was used as a patch graft for the correction of experimentally-created diaphragmatic defects in five dogs belonging to the same litter. Clinical, macroscopic and histological examinations were conducted every month up to five months after suturing of the patch graft. Clinical examination of the patch graft showed no apparent abnormalities. Macroscopic examination conducted during autopsy showed that the patch graft maintained adequate elasticity for five months after suturing, the surface of the patch graft was covered with a thin membrane and neovascularization was observed. Histological examination showed that the surface of the patch graft was covered with a thin membrane. Inflammatory tissue reactions were observed at one month, but gradually decreased from the second month onwards. In addition, the patch graft had excellent tissue affinity.     

Damage repair in CMSX-4 alloy without fatigue life reduction penalty

The microstructural changes in a single-crystal Ni-base superalloy, CMSX-4, that might occur during the processes of repair and recoating of hot section components for advanced gas turbines were studied. It is shown that the cellular γ/γ′ microstructure is formed when the material is subjected to local plastic straining, followed by the reheat treatments during the course of damage recovery. The formation of cellular microstructure in the material led to the remarkably reduced fatigue strength. In order to reduce or prevent the preceding undesirable effect resulting from cellular microstructure, a new method based on applying overlay coating technique was developed. The method is based on an idea that the alloying elements that are depleted in base alloys could be supplemented via the overlay coating. An X alloy, which contains grain boundary strengthening elements, was selected and coated on the CMSX-4 with the cellular microstructure by low-pressure plasma spraying. The fatigue tests on the coated CMSX-4 specimens demonstrated the effectiveness of the method. The observations of the crack initiation site, the fatigue fracture mode, the crack density in the cellular transformed area, and the crack propagation morphologies near the prior interface strongly supported the validity of this approach. The method is expected to build a road to a so-called damage cure (or recovery) coating.     

Transfer to a nitrocellulose membrane allows of the bone forming activity of bone morphogenetic protein

When we purify bone morphogenetic protein (BMP), its activity diminishes, and the quantity we are able to extract decreases. It is difficult to evaluate the effects of each of the processes involved in BMP purification because it is unstable. In order to resolve the problem, a modified bioassay method using only slight quantities of BMP which do not decrease its bone-forming activity, is needed. We transferred BMP separated by sodium dodecylsulfate-polyacrylamide gel electrophoresis (SDS-PAGE) onto nitrocellulose membranes (NC) and cut out the bands. Then we used each band as implanted material. The NC membrane firmly bound the BMP activity fraction and held it in the implantation area of the mouse thigh. No formation of bone-like tissue was detected histologically at 14 days after the implantation, but, by 21 days after implantation, cartilage like tissue had clearly formed and newly formed bone was seen by 28 days. By implanting BMP transferred to individual NC membranes, we could perform a bioassay easily with small amounts of BMP without any reduction in activity.