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81.
Application of Highly Functional Ti-Oxide-Based Photocatalysts in Clean Technologies 总被引:1,自引:0,他引:1
Masato Takeuchi Shirou Sakai Afshin Ebrahimi Masaya Matsuoka Masakazu Anpo 《Topics in Catalysis》2009,52(12):1651-1659
Various Ti-oxide based photocatalysts such as the highly dispersed Ti-oxide species within zeolite frameworks, TiO2 nano-particles hybridized with hydrophobic zeolite adsorbents as well as visible light responsive TiO2 thin films have been successfully prepared. Characterization studies at the molecular level, such as X-ray absorption fine
structure (XAFS) and photoluminescence (PL), revealed that the highly dispersed Ti-oxide species within the nano-spaces of
zeolites possess a tetrahedral coordination and that they demonstrate unique and high performance for the photocatalytic decomposition
of NOx and the photocatalytic reduction of CO2 with H2O. A high photocatalytic reactivity for the TiO2 semiconducting photocatalysts could be achieved by blending them with hydrophobic siliceous zeolites which was equal to the
performance of TiO2 deposited with expensive Pt particles. The role of the siliceous zeolites can be described as a so-called “catch and release
effect of organic compounds”, i.e., (i) the condensation of the reactants within the hydrophobic cavities of zeolites and;
(ii) the efficient diffusion of the reactant onto the TiO2 photocatalytic sites. Furthermore, a novel photocatalytic system which can convert abundant solar energy into renewable H2 energy by the decomposition of H2O into H2 and O2 can also be achieved by using visible light responsive TiO2 thin film photocatalysts prepared by a RF-magnetron sputtering deposition method. The conversion efficiency of solar energy
into H2 energy may be estimated at ca. 0.1% from the initial rate of H2 evolution. 相似文献
82.
Takashi Kubo Masato Takeuchi Masaya Matsuoka Masakazu Anpo Atsushi Nakahira 《Catalysis Letters》2009,130(1-2):28-36
Morphologic control of Pt supported titanate nanotubes was attempted by the hydrothermal hot-pressing (HHP) technique in order to improve the handleability as a photocatalyst. The bulk of Pt-nanocrystal supported titanate nanotubes was successfully fabricated without the H2 reduction process by applying the HHP technique. The bulky Pt-nanocrystal supported titanate nanotubes possessed dense microstructures, significantly sharp distributions of mesopores, and high Brunauer–Emmett–Teller (BET) surface area. Furthermore, the bulky Pt-nanocrystal supported titanate nanotubes showed the photocatalytic degradation activities of 2-propanol aqueous solution under UV-light irradiation. 相似文献
83.
Masato Takeuchi Junichi Deguchi Manabu Hidaka Shiro Sakai Kyoungja Woo Pyuck-Pa Choi Jong-Ku Park Masakazu Anpo 《Applied catalysis. B, Environmental》2009,89(3-4):406-410
The photocatalytic oxidation of gaseous acetaldehyde with O2 on commercial TiO2 nano-particles could be successfully enhanced by a simple mechanical blending with a high-silica mordenite (MOR) zeolite, the surface of which showed high hydrophobic properties. When the TiO2 nano-particles of ca. 5–20 wt% were mixed with the MOR zeolite powders in an agate mortar for only 5 min, the blended TiO2/MOR samples showed higher photocatalytic reactivity as compared to the pure TiO2 nano-particles. Since the high-silica zeolite powders are highly transparent in UV light regions, the incident UV light is effectively irradiated onto the whole part of the TiO2 nano-particles without any loss of light intensity. Furthermore, the siliceous MOR zeolite powders effectively adsorb the gaseous acetaldehyde molecules and supply them onto the surfaces of the blended TiO2 nano-particles, resulting in an enhancement of the photocatalytic reactivity. 相似文献
84.
Takuya Oda Masakazu Ito Norihiro Kawasaki Takahiko Miyazaki Takao Kashiwagi 《Electrical Engineering in Japan》2013,182(3):30-38
If both EVs (Electric Vehicles, includes plug‐in hybrid electric vehicles) and renewable energies spread in large quantities, it is possible to control the supply fluctuation of renewable energies using the storage battery of EVs. This research sought to show the charge load potential of EVs based on the state of the Japanese passenger car using traffic census results, etc. Furthermore, it tried to show the trend of the storage battery capacity according to time. From the estimated results: (1) the charge electricity of low and middle distance gets a majority of the total charge demand, (2) charge load changes according to time several times, and the minimum load is the number of gigawatt‐hours at early morning, (3) if night charge is assumed, the standby charge demand of noon will reach tens of gigawatt‐hours, it may have sufficient scale for supply fluctuation control of PVs. Although the present EV is not suitable for long‐distance running, these are expected to be 30 or less percent of the total charge demand. The estimated storage capacity potential in this research will not change numbers of times. © 2012 Wiley Periodicals, Inc. Electr Eng Jpn, 182(3): 30–38, 2013; Published online in Wiley Online Library ( wileyonlinelibrary.com ). DOI 10.1002/eej.22352 相似文献
85.
Trans‐fatty acid promotes thrombus formation in mice by aggravating antithrombogenic endothelial functions via Toll‐like receptors
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Kensuke Kondo Tatsuro Ishida Tomoyuki Yasuda Hideto Nakajima Kenta Mori Nobuaki Tanaka Takeshige Mori Tomoko Monguchi Masakazu Shinohara Yasuhiro Irino Ryuji Toh Yoshiyuki Rikitake Kazunobu Kiyomizu Yoshiaki Tomiyama Junichiro Yamamoto Ken‐ichi Hirata 《Molecular nutrition & food research》2015,59(4):729-740
86.
Di Guan Rui Zhao Yuan Li Yoshikiyo Sakakibara Masakazu Ike Ken Tokuyasu 《Journal of Applied Glycoscience》2019,66(1):21
Novel bioreactor beads for simultaneous saccharification and fermentation (SSF) of lime-pretreated rice straw (RS) into ethanol were prepared. Genetically modified Saccharomyces cerevisiae cells expressing genes encoding xylose reductase, xylitol dehydrogenase, and xylulokinase were immobilized in calcium alginate beads containing inorganic lightweight filler particles to reduce specific gravity. For SSF experiments, the beads were floated in slurry composed of lime-pretreated RS and enzymes and incubated under CO2 atmosphere to reduce the pH for saccharification and fermentation. Following this reaction, beads were readily picked up from the upper part of the slurry and were directly transferred to the next vessel with slurry. After 240 h of incubation, ethanol production by the beads was equivalent to that by free cells, a trend that was repeated in nine additional runs, with slightly improved ethanol yields. Slurry with pre-saccharified lime-pretreated RS was subjected to SSF with floating beads for 168 h. Although higher cell concentrations in beads resulted in more rapid initial ethanol production rates, with negligible diauxic behavior for glucose and xylose utilization, no improvement in the ethanol yield was observed. A fermentor-scale SSF experiment with floating beads was successfully performed twice, with repeated use of the beads, resulting in the production of 40.0 and 39.7 g/L ethanol. There was no decomposition of the beads during agitation at 60 rpm. Thus, this bioreactor enables reuse of yeast cells for efficient ethanol production by SSF of lignocellulosic feedstock, without the need for instruments for centrifugation or filtration of whole slurry. 相似文献
87.
Shohei Koizumi Masakazu Hori Yosuke Hayashida Kazuo Naito Seiji Kawabata Yudai Ishigaki Yoshiaki Kito 《Journal of the Society for Information Display》2019,27(11):679-690
Organic thin‐film transistors (OTFTs) can be fabricated via a wet process and have exceptionally high flexibility. Therefore, production using the roll‐to‐roll (RtoR) method is expected. We succeeded in developing a new OTFT wet fabrication process adaptable to the RtoR process. Utilizing the electroless plating method for wiring formation, all materials can be formed in a wet process and can be patterned using the photolithography process. In addition, we succeeded in fabricating OTFT on an A4‐type flexible substrate using RtoR direct imaging exposure system. 相似文献
88.
Kyeong Taek Jung Yong Gun Shul Masakazu Anpo Hiromi Yamashita 《Korean Journal of Chemical Engineering》1997,14(3):213-215
TS-1 zeolite film has been prepared by using nano sized TS-1 zeolite particles for the photocatalytic isomerization of cis-2-butene.
TS-1 zeolite film showed optical transparent property and the thickness of film was 0.7 μm. UV irradiation of TS-1 zeolite
film in the presence ofcis-2-butene leads to the photocatalytic isomerization ofcis-2-butene intotrans-2-butene at the temperature of 275 K. The yield oftrans- 2-butene was linearly increased with UV-irradiation time. 相似文献
89.
The photocatalytic oxidation of CO into CO2 with oxidants such as NO, N2O and O2 proceeded efficiently on a Mo/SiO2 with high Mo dispersion under UV light irradiation. It was found that the reaction rate greatly depended on the kind and concentration of the oxidant. Photoluminescence investigations reveal the close relationship between the reaction rate and the relative concentration of the photo-excited Mo6+-oxide species, i.e. charge transfer–excited–triplet state (Mo5+–O−)*, under steady-state reaction conditions. Moreover, the photocatalytic oxidation of CO with O2 in excess H2 was carried out to test suitability for applications to supplying pure H2. This reaction was seen to proceed efficiently on Mo/SiO2 with a high CO conversion of 100% and CO selectivity of 99% after 180 min under UV light irradiation, showing higher photocatalytic performance than TiO2 (P-25) photocatalyst. UV–vis, XAFS, photoluminescence and FT-IR investigations revealed that the high reactivity of the charge transfer–excited–triplet state (Mo5+–O−)*, with CO as well as the high reactivity of the photoreduced Mo-oxide species (Mo4+-species) with O2 to produce the original Mo-oxide species (Mo6+O2−), played a crucial role in the reactions. 相似文献
90.
Kenji Tsuchihara Toshio Masuda Toshinobu Higashimura Masakazu Nishida Hiroshige Maramatsu 《Polymer Bulletin》1990,23(5):505-511
Summary [2,5-Bis(trifluoromethyl)phenyl]acetylene [BTFPA; HCCC6H3-2, 5-(CF3)2]polymerized with W, Mo, and Nb catalysts to produce methanol-insoluble polymers in high yields. The poly(BTFPA) produced by the W(CO)6-based catalyst at 30 °C was soluble in p-(CF3)2C6H4, and had relatively high molecular weight ([]=0.352 dL/g in p-(CF3)2C6H4). The main chain of the polymer was composed of alternating double bonds, and the polymer was a dark brown solid. The temperature at which the weight loss of the polymer started was higher than 300 °C. The polymerization behavior and polymer properties for BTFPA are compared with those for phenylacetylene and [o-(trifluoromethyl)phenyl]acetylene. 相似文献