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排序方式: 共有1367条查询结果,搜索用时 31 毫秒
71.
Lianqi Zhang Hideyuki Noguchi Decheng Li Takahisa Muta Xiaoqing Wang Masaki Yoshio Izumi Taniguchi 《Journal of power sources》2008
On the basis of extreme similarity between the triangle phase diagrams of LiNiO2–LiTiO2–Li[Li1/3Ti2/3]O2 and LiNiO2–LiMnO2–Li[Li1/3Mn2/3]O2, new Li–Ni–Ti–O series with a nominal composition of Li1+z/3Ni1/2−z/2Ti1/2+z/6O2 (0 ≤ z ≤ 0.5) was designed and attempted to prepare via a spray-drying method. XRD identified that new Li–Ni–Ti–O compounds had cubic rocksalt structure, in which Li, Ni and Ti were evenly distributed on the octahedral sites in cubic closely packed lattice of oxygen ions. They can be considered as the solid solution between cubic LiNi1/2Ti1/2O2 and Li[Li1/3Ti2/3]O2 (high temperature form). Charge–discharge tests showed that Li–Ni–Ti–O compounds with appropriate compositions could display a considerable capacity (more than 80 mAh g−1 for 0.2 ≤ z ≤ 0.27) at room temperature in the voltage range of 4.5–2.5 V and good electrochemical properties within respect to capacity (more than 150 mAh g−1 for 0 ≤ z ≤ 0.27), cycleability and rate capability at an elevated temperature of 50 °C. These suggest that the disordered cubic structure in some cases may function as a good host structure for intercalation/deintercalation of Li+. A preliminary electrochemical comparison between Li1+z/3Ni1/2−z/2Ti1/2+z/6O2 (0 ≤ z ≤ 0.5) and Li6/5Ni2/5Ti2/5O2 indicated that charge–discharge mechanism based on Ni redox at the voltage of >3.0 V behaved somewhat differently, that is, Ni could be reduced to +2 in Li1+z/3Ni1/2−z/2Ti1/2+z/6O2 while +3 in Li6/5Ni2/5Ti2/5O2. Reduction of Ti4+ at a plateau of around 2.3 V could be clearly detected in Li1+z/3Ni1/2−z/2Ti1/2+z/6O2 with 0.27 ≤ z ≤ 0.5 at 50 °C after a deep charge associated with charge compensation from oxygen ion during initial cycle. 相似文献
72.
Hydrogen and carbon dioxide adsorption with tetra‐n‐butyl ammonium semi‐clathrate hydrates for gas separations 下载免费PDF全文
Hiroyuki Komatsu Masaki Ota Yoshiyuki Sato Masaru Watanabe Richard L. Smith Jr. 《American Institute of Chemical Engineers》2015,61(3):992-1003
Gas adsorption rates of H2, CO2, and H2‐CO2 gas mixture (H2/CO2 = 3.4) with tetra‐n‐butyl ammonium salt (bromide, chloride, and fluoride) semi‐clathrate hydrate particles were measured at 269 K to assess their properties for gas separation. Equilibrium gas occupancies in the S‐cages of the particles were in order of (high to low) for hexagonal structure‐I, tetragonal structure‐I, and superlattice of cubic structure‐I structures with the maximum fractional occupancy by CO2 being about 40%. The CO2 diffusion rate depended on the anion size of the salt, which is attributed to distortion of the S‐cage that is close to the molecular size of CO2. Simulations of semi‐clathrate hydrate particles with theory showed that H2/CO2 selectivities could be as high as 36 (3.0 mol% TBAF) and that selectivities for an ideal membrane (3.3 mol% TBAF) could be >100 (269 K, 0.3–4.5 MPa). Semi‐clathrate hydrates have wide application as separation media for gas mixtures. © 2014 American Institute of Chemical Engineers AIChE J, 61: 992–1003, 2015 相似文献
73.
High tensile strength fiber of poly[(R)‐3‐hydroxybutyrate‐co‐(R)‐3‐hydroxyhexanoate] processed by two‐step drawing with intermediate annealing 下载免费PDF全文
Taizo Kabe Chizuru Hongo Toshihisa Tanaka Takaaki Hikima Masaki Takata Tadahisa Iwata 《应用聚合物科学杂志》2015,132(2)
High tensile strength fibers of poly[(R)‐3‐hydroxybutyrate‐co‐(R)‐3‐hydroxyhexanoate] [P(3HB‐co‐3HH)], a type of microbial polyesters, were processed by one‐step and two‐step cold‐drawn method with intermediate annealing. Thermal degradation behaviors were characterized by differential scanning calorimeter and gel permeation chromatography measurements. Thermal analyses were revealed that molecular weights decreased drastically within melting time at a few minute. One‐step cold‐drawn fiber with drawing ratio of 10 showed tensile strength of 281 MPa, while tensile strength of as‐spun fiber was 78 MPa. When two‐step drawing was applied for P(3HB‐co‐3HH) fibers, the tensile strength was led to 420 MPa. Furthermore, the optimization of intermediate annealing condition leads to enhance the tensile strength at 552 MPa of P(3HB‐co‐3HH) fiber. Wide‐angel X‐ray diffraction measurements of these fibers suggest that the fibers with high tensile strength include much amount of the planer‐zigzag conformation (β‐form) as molecular conformation together with 21 helix conformation (α‐form). © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 41258. 相似文献
74.
Okuda T Kato J Mori J Tenmoku M Suda Y Tanaka S He K Ma Y Yang F Yu X Duan F Lei Y 《The Science of the total environment》2004,330(1-3):145-158
This paper describes the daily concentrations of trace metals and ionic constituents in the aerosol of Beijing, China from March 2001 to August 2003. Daily PM10 concentrations were also measured from September 2001 to August 2003. The daily average PM10 concentration at Beijing, China from September 2001 to August 2003 was 171+/-117 microg m(-3) (n = 673), which is 5-fold higher than at Yokohama, Japan. Trace metal concentrations were analyzed by using inductively coupled plasma mass spectrometry equipped with a laser ablation sample introduction (LA/ICP-MS), which is a rapid and simultaneous method for multi-element analysis. The daily average metal concentrations in TSP in Beijing from March 2001 to August 2003 were: Al: 3.5+/-2.4 (n = 727), Ti: 0.47+/-0.35 (n = 720), V: 0.013+/-0.010 (n = 716), Cr: 0.019+/-0.015 (n = 618), Mn: 0.24+/-0.16 (n = 730), Fe: 5.5+/-3.9 (n = 728), Co: 0.0046+/-0.0055 (n = 629), Ni: 0.022+/-0.024 (n = 680), Cu: 0.11+/-0.11 (n = 660), Zn: 0.77+/-0.60 (n = 726), As: 0.048+/-0.047 (n = 731), Se: 0.010+/-0.010 (n = 550), Cd: 0.0068+/-0.0082 (n = 709), Sb: 0.033+/-0.036 (n = 687), and Pb: 0.43+/-0.50 (n = 728) (unit, microg m(-3)). All the metal concentrations in TSP in Beijing, China were 1.7-21.8 times higher than those in TSP in the center of Tokyo, Japan. Notably, As concentrations in TSP in Beijing were 20-fold higher than those in Tokyo. Source identification of aerosols in Beijing was carried out by using the chemical mass balance (CMB) receptor model, with the daily concentration of metals in the aerosol. The major primary sources of the aerosol of Beijing were considered to be soil dust and coal combustion. Vehicle exhaust contribution tended to increase. 相似文献
75.
To evaluate the oxidation behavior of high-burnup advanced fuel cladding tubes in high-temperature steam, laboratory-scale isothermal oxidation tests were conducted using the following advanced fuel cladding tubes with burnups of up to 85 GWd/t: M-MDATM, low-tin ZIRLOTM, M5®, and Zircaloy-2 (LK3). These oxidation tests were performed in steam-flowing conditions at temperatures ranging from 1173 to 1473 K for durations between 120 and 4000 s, and the oxidation kinetics was evaluated. The oxidation kinetics of the high-burnup advanced fuel cladding tube specimens estimated by assuming the parabolic rate law was comparable to or slower than that of the unirradiated Zircaloy-4 cladding tube specimens reported in a previous study. It is considered that the protective e?ect of the corrosion layer hindered oxidation. Furthermore, no increase in the oxidation kinetics because of the pre-hydriding was observed. The onset times of the breakaway oxidations of these cladding tube specimens were comparable to those of the unirradiated Zircaloy-4 cladding tubes reported in previous studies. Therefore, it is considered that the burnup extension up to 85 GWd/t and the use of the advanced fuel cladding tubes do not significantly increase the oxidation kinetics and do not significantly reduce the onset time of the breakaway oxidation. 相似文献
76.
Shoji Eita Takahashi Ryuji Isogai Shosei Ito Naoto Kubo Masaki Tsukada Takao Fukuyama Hiroyuki 《Metallurgical and Materials Transactions B》2019,50(5):2454-2458
Metallurgical and Materials Transactions B - Normal spectral emissivity of molten Cu-Fe alloy with different compositions was measured at the wavelength of 807 nm using an electromagnetic... 相似文献
77.
Takeyuki Gotoh Fuyuki Abe Takenori Ishizu Masaki Yoshio 《Journal of power sources》1996,60(2):193-196
A study of the pyrolysis of an aqueous solution of manganese nitrate in the presence of silver compounds has been carried out. Thermal analysis showed that the MnO2 formation temperature and the transformation temperature from MnO2 to Mn2O3 shifted towards a lower temperature in the presence of silver acetate. A large particle-size and high crystallinity MnO2 was formed; this may be a useful method of making an excellent tantalum capacitor with high capacitance. 相似文献
78.
Hashimoto A Mitsuishi K Shimojo M Zhu Y Takeguchi M 《Journal of electron microscopy》2011,60(3):227-234
We experimentally examined the characteristics of bright-field (BF) scanning confocal electron microscopy (SCEM) images by changing the observation conditions and comparing the images with those obtained by BF transmission electron microscopy (TEM) and BF scanning TEM (STEM) modes. The observation of 5-nm-diameter Au nanoparticles demonstrated that BF-SCEM produces object elongation of more than 2000?nm along the optical axis, as do BF-TEM and BF-STEM. We demonstrated the relationship between elongation length and geometric effects such as convergence and collection angles of a probe and the lateral size of an object; the relationship is consistent with previous theoretical prediction. Further, we observed interesting features that are seen only in the BF-SCEM images; the film contrast was strongly enhanced, compared with that of BF-STEM. In addition, a bright contrast appeared around the object position in the elongated images. Using this characteristic, we could determine the object position and structure. 相似文献
79.
Shoya Ueno Yuki Nakamura Ken-Ichi Sugioka Masaki Kubo Takao Tsukada Masahito Uchikoshi Hiroyuki Fukuyama 《International Journal of Thermophysics》2017,38(2):16
The normal spectral emissivity of molten Cu–Co alloy with different compositions was measured in the wavelength range of 780 nm to 920 nm and in the temperature range of 1430 K to 1770 K including the undercooled condition by an electromagnetic levitator superimposed with a static magnetic field. The emissivity was determined as the ratio of the radiance from a levitated molten Cu–Co droplet measured by a spectrometer to the radiance from a blackbody calculated by Planck’s law at a given temperature, where a static magnetic field of 2.5 T to 4.5 T was applied to the levitated droplet to suppress the surface oscillation and translational motion of the sample. We found little temperature dependence of the normal spectral emissivity of molten Cu–Co alloy. Concerning the composition dependence, the emissivity decreased markedly above 80 at%Cu and reached that of pure Cu, although its dependence was low between 20 at%Cu and 80 at%Cu. In addition, this composition dependence of the emissivity of molten Cu–Co alloy can be explained well by the Drude free-electron model. 相似文献
80.
Toshiki Tsubota Masaki Morita Sunao Kamimura Teruhisa Ohno 《Journal of Porous Materials》2016,23(2):349-355
Unconventional pretreatment, that is, delignification and the addition of guanidine phosphate, was performed for the synthesis of activated carbon having a high specific surface area from bamboo by physical activation. The values of the specific surface area, total pore volume, and average pore size depended on the amount of added guanidine phosphate and the CO2 activation time. The amount of the added guanidine phosphate under the optimum conditions for the highest specific surface area was much lower than that of the phosphorous acid chemical activator under conventional conditions. The N2 adsorption isotherms of all the samples were type I, which means that micropores were dominant. The pore sizes of the samples in this study were similar to that of the physically-activated carbon. Therefore, the activation process was presumed to be essentially not chemical, but physical. The relation between the yield and the specific surface area improved with the addition of guanidine phosphate. The reason for the improvement may be the change in the reactivity of the carbon material generated during the heating process. The maximum specific surface area was ca. 2000 m2 g?1, which is a high value for a physically-activated carbon. 相似文献