A novel foaming approach to prepare porous superabsorbent poly(sodium acrylic acid) resins

A system composed of surfactant and foam stabilizer is used in preparing porous superabsorbent resins (SARs) of poly(sodium acrylic acid) (PAA‐Na), which is obtained by free‐radical solution polymerization of partially neutralized acrylic acid with mechanical agitation of eggbeater. Different types of surfactant, including anionic surfactant sodium n‐dodecyl benzene sulfate (SDBS), cationic surfactant cetyltrimethyl ammonium bromide, and nonionic surfactant alkylphenols poly(oxyethylene) (OP‐10), are used as blowing agent to produce pores by mechanical agitation, and triethanolamine (TEA) is used to act as foam stabilizer agent. The results show that a synergistic effect of SDBS with TEA is obtained and the packing density is decreased, which could be proved by the clearly porous morphology, and the water absorbing capacity of SARs is enhanced. As a result, such method can get PAA‐Na SARs without any organic solvents, which provides an environmentally beneficial way to prepare SARs for hygiene and biomedical products. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 41298.     

油纸绝缘直流极性反转试验及局部放电测量

对油纸绝缘缺陷模型在极性反转过程中局部放电特征图谱以及空间电荷特性进行了研究,实现了对油纸绝缘极性反转过程中局部放电信号和空间电荷的测量。     

基于FMECA的电力电缆故障分析方法

针对电力电缆故障查找难度大、操作条件苛刻等问题,提出基于FMECA的电力电缆故障分析方法,从技术原理、应用等方面对该方法进行分析,认为该方法实现了对电力电缆故障的细化和评估,可有效预防重大事故的发生,并给出电力电缆故障的防范措施。     

Mapping QTLs Controlling Beneficial Fatty Acids Based on the Embryo and Maternal Plant Genomes in Brassica napus L.

This study was mainly carried out to detect the quantitative trait loci (QTLs) located simultaneously in embryo and maternal plant nuclear genomes for beneficial fatty acid contents of rapeseed under different environments by using a mapping model and mapping populations from a cross of ‘Tapidor’ × ‘Ningyou7.’ Eight, three, six, seven and three QTLs respectively for palmitic, oleic, linoleic, linolenic and eicosenoic acid contents were identified and subsequently mapped on chromosomes A1, A3, A4, A6, A8, A9, C1, C3, C5, C7, C8 and C9. Among them, 12 QTLs were major ones that could respectively explain more than 10 % of phenotypic variation. Two specific genomic regions on A8 and C3 were associated with several QTLs relating to multiple fatty acid contents. Some of the markers such as HBr015 and JICB0633 showed tight linkage with the QTLs, which could be used for improving the fatty acid component(s) of rapeseed.     

Discharged Energy Properties of SrO–PbO–Na2O–Nb2O5–SiO2 Glass‐Ceramics with Different Crystallization Time

Discharged energy properties of PbO–SrO–Na₂O–Nb₂O₅–SiO₂ glass‐ceramics with crystallization time from 1 to 1000 min were investigated by measuring their hysteresis loops (described as quasi‐static measuring method) and pulse‐discharge current‐time curves (described as dynamic measuring method). The results show the same trend for both measuring methods: With the increment of crystallization time, the discharged energy density increases gradually, while the energy efficiency decreases. The highest energy efficiencies were obtained in the sample with crystallization time of 1 min, which are 96.3% and 82.4%, corresponding quasi‐static and dynamic measurement, respectively. The reduction of energy efficiency with crystallization time is attributed to combined effect of ferroelectric polarization and interfacial polarization, and part of the corresponding energy could not release in the pulse‐discharge process.     

电磁继电器绝缘下降的失效分析与控制

文章通过对某电磁继电器不同引脚以及引脚与管壳之间绝缘下降进行失效分析,采用显微镜外部目检、扫描电镜检查和能谱分析等分析方法与手段,揭示了银离子迁移是导致该继电器绝缘下降的失效原因。阐述了银离子迁移的发生机理,从生产和使用两个方面提出了避免银离子迁移在继电器中发生的控制措施。     

10kV三相异步电动机相间放电机理及指纹模式的研究

通过实时监测运行中10k V三相异步电动机定子绕组局部放电水平,可为在线监测其绝缘状况提供判断依据。然而,对于一些高能量放电,往往会导致局部绝缘的迅速劣化,必须及时发现并安排维修。针对这一现象,本文选取10k V三相异步电动机定子绕组相间放电这一高能电容性放电,对其放电机理进行分析,利用真机定子绕组,在实验室提取出相间放电指纹分布。研究表明,相间放电属于一种典型的介质阻挡放电(DBD),其放电模式分布表现为正负电压半周窄相位段的高幅值分布。本文研究内容可为高压电机定子绕组绝缘在线监测提供依据。     

六氟磷酸锂浓度对锂离子电池性能的影响

配制不同浓度(0.8~2.2 mol/L)的Li PF6/EC+EMC+DMC(质量比1∶1∶1)电解液,用循环伏安、电化学阻抗谱(EIS)和恒流充放电测试并结合Li+迁移数、电导率和黏度等参数的测试,研究锂盐浓度和电解液物化参数对电池倍率性能、循环性能的影响。电解液浓度为1.6~1.8 mol/L时,制得的锂离子电池倍率性能和循环性能最佳。电解液浓度为1.6 mol/L和1.8 mol/L的电池在3.65~2.00 V循环,20.0 C放电相对于0.5 C时的容量保持率分别为89.10%、91.1%;以1.0 C充电、10.0 C放电循环300次,容量保持率分别为56.22%、62.6%。     

Electrochemical behaviour of Ti–25Nb–3Mo–3Zr–2Sn biomedical alloy in different simulated physiological environments

The electrochemical corrosion behaviour of biomedical Ti–25Nb–3Mo–3Zr-2Sn (TLM) alloy was investigated in various simulated body fluids at 37±0·5°C utilising potentiodynamic polarisation and current–time curves. The Ti–6Al–4V (TC4) alloy was also investigated to make a comparison. The different simulated body fluids comprised of 0·9%NaCl saline, Hank’s and Ringer’s solution were employed. The effect of heat treatment on the electrochemical behaviour of the TLM alloy was also considered. It was discovered that all the test specimens were passivated once immersed into the simulated body fluids. It was also found that the TLM alloy has poorer corrosion resistance in Hank’s solution, due to the chemical composition of the Hank’s. After different heat treated, the TLM alloy had different phases and microstructure, and the corrosion behaviour of the TLM alloy was different. In this study, after the heat treatment of 760°C/1 h/AC+550°C/6 h/AC, the TLM alloy had better corrosion resistance. Owing to the corrosion resistance of the TLM alloy was influenced by numerous factors, such as microstructure and the chemical composition of electrolyte, the corrosion behaviour of the TLM alloy is complex. By comparing with the corrosion behaviour of the TC4 alloy, the TLM alloy has poorer corrosion resistant than the TC4 alloy under the same conditions. But the current–time curves of the TLM alloy were more stable than these of the TC4 alloy with further experiments, because of the more passivation film on the surface of the TLM alloy.