全文获取类型
收费全文 | 96137篇 |
免费 | 2101篇 |
国内免费 | 624篇 |
专业分类
电工技术 | 1205篇 |
技术理论 | 1篇 |
综合类 | 2591篇 |
化学工业 | 14202篇 |
金属工艺 | 5294篇 |
机械仪表 | 3715篇 |
建筑科学 | 2586篇 |
矿业工程 | 657篇 |
能源动力 | 1560篇 |
轻工业 | 4876篇 |
水利工程 | 1351篇 |
石油天然气 | 578篇 |
武器工业 | 47篇 |
无线电 | 11241篇 |
一般工业技术 | 18622篇 |
冶金工业 | 3256篇 |
原子能技术 | 421篇 |
自动化技术 | 26659篇 |
出版年
2024年 | 29篇 |
2023年 | 197篇 |
2022年 | 346篇 |
2021年 | 535篇 |
2020年 | 415篇 |
2019年 | 389篇 |
2018年 | 14777篇 |
2017年 | 13775篇 |
2016年 | 10406篇 |
2015年 | 1098篇 |
2014年 | 939篇 |
2013年 | 1082篇 |
2012年 | 4030篇 |
2011年 | 10354篇 |
2010年 | 8962篇 |
2009年 | 6287篇 |
2008年 | 7428篇 |
2007年 | 8291篇 |
2006年 | 714篇 |
2005年 | 1658篇 |
2004年 | 1524篇 |
2003年 | 1490篇 |
2002年 | 888篇 |
2001年 | 360篇 |
2000年 | 408篇 |
1999年 | 295篇 |
1998年 | 357篇 |
1997年 | 243篇 |
1996年 | 185篇 |
1995年 | 145篇 |
1994年 | 115篇 |
1993年 | 96篇 |
1992年 | 74篇 |
1991年 | 71篇 |
1990年 | 51篇 |
1989年 | 40篇 |
1988年 | 31篇 |
1987年 | 31篇 |
1968年 | 44篇 |
1967年 | 33篇 |
1966年 | 42篇 |
1965年 | 45篇 |
1963年 | 28篇 |
1960年 | 30篇 |
1959年 | 36篇 |
1958年 | 37篇 |
1957年 | 36篇 |
1956年 | 34篇 |
1955年 | 63篇 |
1954年 | 68篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
51.
The aim of the present paper is to review the recent progress in the synthesis of in situ particle reinforced aluminum composites
using thermal, mechanical and combined mechanical-thermal activation of aluminothermic reduction reactions. The combination
of combustion synthesis (CS) and mechanosynthesis (MS) is the most recent development in the processing of advanced materials
like micro and nano aluminum based composites. The combined mechanical thermal synthesis (MTS) has widened the possibilities
for both CS and MS. MTS holds great potential for commercial viability and offers exciting processing route for the synthesis
of advanced materials. Enhanced reaction kinetics and extended concentration limits in MTS are demonstrated by illustrating
the synthesis of aluminum based nanocomposite involving Al–CeO2. 相似文献
52.
Hideo Sawada Hiroshi Kakehi Masashi Koizumi Yoshihiro Katoh Masashi Miura 《Journal of Materials Science》2007,42(17):7147-7153
Fluoroalkyl end-capped N-(1,1-dimethyl-3-oxobutyl)acrylamide oligomer [RF-(DOBAA)
n
-RF] reacted with tetraethoxysilane (TEOS) and silica nanoparticles in the presence of low-molecular weight biocides such as
hibitane, hinokitiol, and hinokioil under alkaline conditions to afford RF-(DOBAA)
n
-RF/silica nanocomposites-encapsulated these biocides in excellent to moderate isolated yields. Fluoroalkyl end-capped N,N-dimethylacrylamide oligomer [RF-(DMAA)
n
-RF] and acrylic acid oligomer [RF-(ACA)
n
-RF]/silica nanocomposites-encapsulated hibitane were obtained under similar conditions. Dynamic light scattering measurements
showed that the size of these fluorinated nanocomposites-encapsulated biocides thus obtained is nanometer size-controlled.
Additionally, these fluorinated nanocomposites were shown to have a good dispersibility and stability in methanol and water.
Of particular interest, these fluorinated nanocomposites-encapsulated biocides were found to have a good antibacterial activity
against Staphylococcus aureus, and these nanocomposites were applied to the surface modification of traditional organic polymers such as poly(methyl methacrylate). 相似文献
53.
54.
55.
Mamiko Hori Cécile Pagnoux Jean-François Baumard Masayuki Nogami 《Journal of Materials Science》2007,42(1):80-86
A new method is proposed to produce gold nanoparticles (GNP) by in situ reduction of a gold salt dissolved in water. The reducing
agent used is Tiron instead of the citrate anion most often mentioned in literature. The influence of various parameters has
been investigated, such as the content of Tiron with respect to that of the precursor of gold HAuCl4, or the initial pH of the solution after mixing of reactants. It is shown that Tiron also exerts a positive influence as
a dispersant, which impedes agglomeration of gold nanoparticles. The typical average size of GNP synthesized in the present
work is close to 7 nm. 相似文献
56.
57.
The effects of gallia additions on the sintering behavior of gadolinia-doped ceria were systematically investigated from the following aspects: the variation in sintered density, the variation in grain size, and the existing forms of Ga2O3 in CeO2.Sintered density increased with increasing Ga2O3 content up to 5 mol.% and then it decreased with further addition of Ga2O3. Grain size also increased with increasing Ga2O3 content up to 5 mol.% and then decreased with further addition of Ga2O3. Decrease in grain size was caused by a pinning effect of Ga2O3 precipitation at grain boundaries. Lattice constant decreased with increasing Ga2O3 content up to 5 mol.%. This decrease will be due to the substitution of smaller Ga3+ ions for Ce4+ ions in the CeO2 structure. According to the results obtained from scanning electron microscope (SEM) and X-ray diffraction (XRD) analyses, the solubility limit of Ga2O3 in Ce0.8Gd0.2O1.9 ceramics can be estimated to be nearly 5 mol.%. The addition of Ga2O3 up to the solubility limit was found to promote the sintering properties of Gd2O3-doped CeO2. 相似文献
58.
Du Young Choi Long Mei Jin Dexian Wang Kyung Ho Row 《Korean Journal of Chemical Engineering》2005,22(3):465-469
High-performance frontal analysis (HPFA) was used for a protein binding study of isoflavones (daidzein, genistin, and genistein),
enantiomers of perillyl alcohol and S-ibuprofen to human serum albumin (HSA). The analyses were performed on a Develosil and
Inertsil 100-Diol-5 column (10 cm×4.6mm). Sodium phosphate solution (pH 7.4, ionic strength 0.17) was used as the mobile phase
at a flow rate of 1 ml/min. To ensure the drug to be eluted as a trapezoidal peak with a plateau, injection volumes were each
fixed up the zonal profile with an evident plateau appears. The unbound drug concentration was determined from a plateau height
of the plateau region after that experimental data were fitted by Scatchard equation. The binding constants (K) and total
binding affinities (nK) of drugs to HSA were calculated, respectively. 相似文献
59.
A simple mathematical analysis on the effect of sand in Cr(VI) reduction using zero valent iron 总被引:1,自引:0,他引:1
A simple mathematical model was proposed to analyze the enhancement of Cr(VI) reduction when sand materials are added to the
zero valent iron (ZVI). Natural decay of Cr(VI) in a control experiment was analyzed by using a zero-order decay reaction.
Adsorption kinetics of Cr(VI) to sand was modeled as a first-order reversible process, and the reduction rate by ZVI was treated
as a first-order reaction. Natural decay of Cr(VI) was also included in other experiments, i.e., the adsorption to sand, the
reduction by ZVI, and both adsorption and reduction when sand and ZVI are present together. The model parameters were estimated
by fitting the solution of each model to the corresponding experimental data. To observe the effect of sand addition to ZVI,
both adsorption and reduction rate models were considered simultaneously including the natural decay. The solution of the
combined model was fitted to the experimental data to determine the first-order adsorption and reduction rate constants when
sand as well as ZVI is present. The first-order reduction rate constant in the presence of sand was about 35 times higher
than that with ZVI only. 相似文献
60.
M. K. Bakhadyrkhanov O. É. Sattarov Kh. M. Iliev K. S. Ayupov Tuérdi Umaier 《Semiconductors》2005,39(7):789-791
It is experimentally ascertained that light stimulates the negative magnetoresistance observed in a high electric field in silicon doped with boron and manganese. The optimum conditions (the electric field, temperature, illumination, and resistivity of the material) for observation of the largest magnitude of negative magnetoresistance in (Si:B):Mn are determined. The dependence of the negative magnetoresistance on the concentration of compensating impurity is established. 相似文献