Low Dielectric Polyimide/Fluorinated Ethylene Propylene (PI/FEP) Nanocomposite Film for High-Frequency Flexible Circuit Board Application

The low dielectric polymer films have drawn great attention to the application as the dielectric insulating materials in high-frequency circuit boards, while the weak adhesion to the copper foils and the poor processability resulted from the fluorinated or rigid structures limited their high-frequency application. In this work, the low dielectric and high adhesive polyimide/fluorinated ethylene propylene (PI/FEP) nanocomposite film for high-frequency flexible circuit board application is developed. It is indicated that the fluorocarbon surfactants can significantly improve the dispersion of FEP in PI substrate, and thus, the PI/FEP nanocomposite film exhibits excellent mechanical properties, including the tensile strength increases to 46.6 MPa and the elongation at the break increases to 13.7%. Importantly, at the high-frequency of 10 GHz, the 60 wt% FEP filled PI nanocomposite film displays an ultralow dielectric loss (0.006) and a reduced dielectric constant (2.69). In addition, the high-frequency flexible circuit board with the PI/FEP film as the dielectric insulating layer has a high peel strength of 0.75 N mm⁻¹, indicating this PI/FEP nanocomposite film can meet the requirements of the high-frequency flexible circuit board application.     

Chemical Labeling of Protein 4′-Phosphopantetheinylation

Nature uses a diverse array of protein post-translational modifications (PTMs) to regulate protein structure, activity, localization, and function. Among them, protein 4′-phosphopantetheinylation derived from coenzyme A (CoA) is an essential PTM for the biosynthesis of fatty acids, polyketides, and nonribosomal peptides in prokaryotes and eukaryotes. To explore its functions, various chemical probes mimicking the natural structure of 4′-phosphopantetheinylation have been developed. In this minireview, we summarize these chemical probes and describe their applications in direct and metabolic labeling of proteins in bacterial and mammalian cells.     

钨酸镁催化超声降解金橙Ⅱ研究

采用水热法合成了钨酸镁(MgWO4)半导体催化剂,并使用金橙II为有机污染物模型研究了其声催化降解性能.结果表明:MgWO4具有良好的声催化活性,可显著提升超声对有机污染物的降解效果,而且MgWO4具有优秀的可重复利用性能.同时,MgWO4催化超声降解金橙Ⅱ的机理研究表明,产生的活性物质如羟自由基(·OH)、超氧阴离子自由基(·O2-)和空穴(h+)是声催化降解金橙II的主要原因.以上研究结果表明MgWO4作为声催化剂用于处理有机染料废水具有良好的应用前景.     

高钠煤灰烧结特性研究进展

中国新疆准东煤具有储量巨大、开采成本低、挥发分高、硫含量低等特点,是优质的动力用煤。但准东煤钠含量高,燃烧利用时易在受热面上形成烧结性积灰,产生严重的结渣,极大限制了高钠煤的开发利用。因此,要实现高钠煤的清洁高效利用,需充分认识高钠煤灰的烧结特性。总结了高钠煤积灰结渣机理,概述了高钠煤灰烧结机制,探讨了二者之间的内在关联。高钠煤在燃烧过程中,煤中碱金属(主要为钠)释放并以Na_2SO_4、NaCl及Na的形式存在于烟气中,与受热面接触并于其上冷凝形成黏性内白层,内白层捕获飞灰颗粒后反应生成低熔点化合物,其烧结温度降低,使锅炉受热面上发生沾污增强型的"沾污烧结"过程。高钠煤灰的烧结过程包含固相烧结、液相烧结和气相烧结3种方式,对煤灰烧结过程的影响因素包括反应温度、化学组成、煤灰粒径、反应气氛、添加剂种类、锅炉设计和锅炉运行工况等。其中添加剂按氧化物种类可分为碱性氧化物和酸性氧化物,一般情况下碱性氧化物可以降低煤灰烧结温度,酸性氧化物可提高煤灰烧结温度。未来对于提高高钠煤灰烧结温度的研究方向可从新型添加剂出发,找到既能固定烟气中的钠,又能与灰渣中的低熔点含钠矿物质反应生成高熔点化合物的单一或混合成分的添加剂。同时,关于钠蒸气对积灰结渣在微观层面上的动态特性的影响机制也需进一步研究。概述了煤灰烧结温度的测量方法,热导率分析法、压力测量法、热机械分析法、筛分法和压降法,其中压降法是目前为止测量烧结温度较为准确的方法。介绍了上海理工大学碳基燃料洁净转化实验室在高钠煤灰烧结特性方面的研究方向,以期为解决燃用高钠煤锅炉积灰结渣问题提供参考。     

基于数值模拟的等效拉延筋设计与优化

拉延筋在汽车覆盖件拉深成形中起着十分重要的作用。利用拉延筋可以在较大范围内调节和控制板料的变形程度和变形分布,抑制破裂、起皱、面畸变等多种冲压质量问题的产生。在很多情况下,拉延筋的设置合理与否将决定覆盖件拉深的成败。文章借助eta/DYNAFORM软件,模拟某轿车B柱加强板在无/有拉延筋的模具上进行拉深的全过程,通过模拟结果分析比较,确定拉延筋的合理布局及数量,最后结合正交实验法,优化拉延筋的结构参数。     

点焊机器人焊接系统

本文介绍用于点焊机器人的焊接系统的基本硬件结构,工作原理及系统的主要功能和特点。     

稀有金属杂多化合物的脱硫脱硝性能研究

对稀有金属钨、钼的典型杂多化合物HCP(Heteropoly Compound Comprising)进行了同时脱硫脱硝性能对比研究.发现磷钼酸钠对SO2,NOx具有较高的去除效率.在此基础上,以磷钼酸钠为对象,考察了温度、吸收剂浓度、pH值、气流中氧含量等多种因素对体系性能的影响.实验结果表明:磷钼酸钠溶液对SO2,NOx的脱除率分别可达92%与55%;体系的同时脱硫脱硝效率随温度升高而有所降低,适宜温度为室温;提高吸收剂浓度、增加溶液pH值,均能显著增强体系的脱硫脱硝性能;气流中氧含量的提高,对NOx的脱除有显著的促进作用,但却在一定程度上削弱了体系的脱硫效果.对比发现:磷钼酸钠体系对SO2和NOx的脱除率均高于Fe-EDTA体系.     

PZT／Terfenol-D／PVDF层状复合磁电材料谐振特性

采用热压法制备出二层锆钛酸铅(PZT)／聚偏氟乙烯(PVDF)与1层Tb0.28Dy0.72Fe2(Terfenol-D)／PVDF叠层结构的三元复合磁电材料，研究了不同PVDF含量，以及不同层厚比tp／L对样品的介电常数、介电损耗、电阻率、谐振频率以及磁电转换系数αE33，αE31的影响规律，结果显示PVDF的含量和层厚比都存在最佳值(最佳值出现在产0．5，tp／L=2／7)，并且在这个最佳值处，磁电转换系数达到最大。     

Corrosion resistance of the electro-galvanized steel treated in a titanium conversion solution

The conversion coating can be obtained by using a solution containing titanium tetrachloride, fluorosilicate acid and nitric acid. The results of X-ray photoelectron spectroscopy (XPS) showed that the titanium conversion coating consisted of ZnO, TiO₂ and Zn₄Si₂O₇(OH)₂. The formation process of the titanium conversion coating was studied. Effects of the immersion time, pH value and solution temperature on the corrosion resistance and the chemical composition of the titanium conversion coating were investigated by the salt spray test (SST) and XPS, respectively. The results of XPS and SST showed that the titanium conversion coating displayed better corrosion resistance with higher contents of Si and Ti. Results of corrosion tests (the salt spray and electrochemical test) indicate that the corrosion resistance of the conversion coating by titanium solution is better than that of the conversion coating using the traditional chromate solution.