Metal complex pigments have been widely used for various applications such as pigments in coatings. This work presents the use of microwave technique (Green chemistry) for the synthesis of new copper(II), nickel(II), iron(III), and chromium(III) Schiff base complexes derived from metal salts and Schiff base ligand. Also, the microwave technique was used in the synthesis of Schiff base ligand which is derived from selected amine, namely methoxy-tolidine, and selected aldehyde, namely 2-hydroxynaphthaldehyde. The prepared ligand and metal complex pigments were characterized by elemental analysis, NMR, spectral UV–Vis, infrared, and thermal gravimetric analysis. The physical and mechanical properties and corrosion resistance of dry paint films were also examined. The obtained results revealed that the prepared metal complex pigments showed excellent mechanical and corrosion resistance. 相似文献
Though less frequently studied for solar-hydrogen production, films are more convenient to use than powders and can be easily recycled. Anatase TiO2 films decorated with Ag nanoparticles are synthesized by a rapid, simple, and inexpensive method. They are used to cleave water to produce H2 under UV light in the presence of methanol as a hole scavenger. A simple and sensitive method is established here to monitor the time course of hydrogen production for ultralow amounts of TiO2. The average hydrogen production rate of Ag/TiO2 anatase films is 147.9 ± 35.5 μmol/h/g. Without silver, it decreases dramatically to 4.65 ± 0.39 μmol/h/g for anatase TiO2 films and to 0.46 ± 0.66 μmol/h/g for amorphous TiO2 films fabricated at room temperature. Our method can be used as a high through-put screening process in search of high efficiency heterogeneous photocatalysts for solar-hydrogen production from water-splitting. 相似文献
In the current research, the effects of TiO2 additive on mechanical and physical properties of SiC bodies, sintered by liquid phase methods were investigated. Al2O3 and Y2O3 were used as sintering-aids (10?wt% in total) with an Al2O3/Y2O3 ratio of 43/57 to provide liquid phase during Sintering. TiO2 was also used as the oxide additive with an amount ranging from 0 to 10?wt%. After scaling and mixing the starting materials by a planetary mill, the obtained slurry was dried at 100?℃ for four hours. The derived powders were finally pressed under a pressure of 90?MPa. The samples were then pyrolyzed and sintered at 600?℃ and 1900?℃, respectively under argon atmosphere for 1.5?h. Phase analysis showed no trace of TiO2 after the sintering process, demonstrating the complete TiO2 to TiC transformation. The results showed that an increase in TiO2 content up to 5?wt%, led an improvement in all the measured properties including the relative density, hardness, Young's modulus, bending strength, indentation fracture resistance and the brittleness factor, reaching to 96.2%, 24.4?GPa, 395.8?GPa, 521?MPa, 5.8?MPa?m1/2 and 286.5?×?10?6 m?1, respectively. However more than 5?wt% additive resulted in a decrease in all the above-mentioned properties. Microstructural studies demonstrated that crack deflection and crack bridging were the major mechanisms responsible for an increase in the indentation fracture resistance. 相似文献
This work studies the thermal stresses generated within a rapidly heated thin metal plate when a parabolic two-step heat conduction equation is used. The effect of different design parameters on the thermal and stress behavior of the plate is investigated. 相似文献
Variations of thermal and residual stresses are investigated inside a thin mild steel plate during welding processes. The temperature distribution is determined analytically using Green's functions. Transient thermal stresses developed within the plate are computed numerically. The resulting residual stresses, which remain after cooling of the plate, are found based on a method presented originally by Tall (L. Tall, Welding Journal, vol. 43, pp. 10–23, 1964). It is found that welding speed and heat source intensity are the main factors that affect the residual stress formation in the plate. 相似文献
Gas–solid flow in a pipe with different configurations (vertical, horizontal, and inclined positions) is studied experimentally. Air with temperature around 170°C and sand particles with mean diameter of 253 μm are used as gas and solid mediums, respectively. Effects of different parameters (pipe slope and solid particles feed rate) are studied on heat transfer rate between gas and solid particles. The Nusselt number decreases at lower solids feed rate in a dilute regime of the mixture; however, it increases at higher solids feed rates. Furthermore, results show that a higher Nusselt number takes place at the angles closer to 45 degrees. 相似文献
A modified version of Boosted Mixture of Experts (BME) is presented in this paper. While previous related works, namely BME, attempt to improve the performance by incorporating complementary features of a hybrid combining framework, they have some drawback. Analyzing the problems of previous approaches has suggested several modifications that have led us to propose a new method called Boost-wise Pre-loaded Mixture of Experts (BPME). We present a modification in pre-loading (initialization) procedure of ME, which addresses previous problems and overcomes them by employing a two-stage pre-loading procedure. In this approach, both the error and confidence measures are used as the difficulty criteria in boost-wise partitioning of problem space.
Long‐term hemodialysis patients are prone to an exceptionally high burden of cardiovascular disease and mortality. The novel temperature‐based technology of digital thermal monitoring (DTM) of vascular reactivity appears associated with the severity of coronary artery disease in asymptomatic population. We hypothesized that in hemodialysis patients, the DTM and coronary artery calcium (CAC) score have a gradient association that follows that of subjects without kidney disease. We examined the cross‐sectional DTM‐CAC associations in a group of long‐term hemodialysis patients, and their 1:1 matched normal counterpart. Area under the curve for temperature (TMP‐AUC), the surrogate of the DTM index of vascular function, was assessed after a 5‐minute arm‐cuff reactive hyperemia test. Coronary calcium score was measured via electron beam computed tomography or multidetector computed tomography scan. We studied 105 randomly recruited hemodialysis patients (age: 58 ± 13 years, 47% men) and 105 age‐ and gender‐matched controls. In hemodialysis patients vs. controls, TMP‐AUC was significantly worse (114 ± 72 vs. 143 ± 80, P = 0.001) and CAC score was higher (525 ± 425 vs. 240 ± 332, P < 0.001). Hemodialysis patients were 14 times more likely to have CAC score >1000 as compared with controls. After adjustment for known confounders, the relative risk for case vs. control for each standard deviation decrease in TMP‐AUC was 1.46 (95% confidence interval: 1.12–1.93, P = 0.007). Vascular reactivity measured via the novel DTM technology is incrementally worse across CAC scores in hemodialysis patients, in whom both measures are even worse than their age‐ and gender‐matched controls. The DTM technology may offer a convenient and radiation‐free approach to risk‐stratify hemodialysis patients. 相似文献