An atomic force microscopy statistical analysis of laser‐induced azo‐polyimide periodic tridimensional nanogrooves

The surface morphology of azo‐polyimide films was investigated after 355nm Nd: YAG laser irradiation with two different incident fluencies. Atomic force microscopy (AFM) was employed to correlate the laser‐induced tridimensional nanogrooved surface relief with the incident fluence and the number of irradiation pulses. The height images revealed that the grooves depth increased even tens of times by increasing the incident fluence, using the same numbers of irradiation pulses. For low incident fluence, the films were uniformly patterned till 100 pulses of irradiation. Instead, when using higher fluence, after 15 pulses of irradiation the accuracy of the surface relief definition was reduced. This behavior could be explained by means of two different mechanisms, one that suppose the film photo‐fluidization due to the cis‐trans isomerization processes of the azo‐groups and the second one responsible for the directional mass displacement. The dominant surface direction and parameters like isotropy, periodicity, and period were evaluated from the polar representation for texture analysis, revealing the appearance of ordered and directionated nanostructures for most of the experimental conditions. Also, the graphical studies of the functional volume parameters have evidenced the improvement of the relief structuration during surface nanostructuration. The correlation of these statistical texture parameters with the irradiation characteristics is important in controlling the alignment of either the liquid crystals or the cells/tissues on patterned azo‐polyimide surfaces for optoelectronic devices and implantable biomaterials, respectively. Microsc. Res. Tech. 76:914–923, 2013. © 2013 Wiley Periodicals, Inc.     

Azo-polymers modified with nucleobases and their interactions with DNA molecules

The photo-fluidization process which is specific for azo-materials opens a new perspective for their use in the field of molecules nano manipulation at the surface of the azo polymer films. This is possible considering that in the case of the UV irradiation from a polarized laser source the azo material has an unidirectional flow. Here, we investigated the structuring phenomena occurring on the surface of the azo-polysiloxanes films modified with nucleobases, upon UV irradiation. Measurements of topography and adhesive forces between polymeric substrates and a hydrophilic probe have been done by atomic force microscopy (AFM). The response of the material upon irradiation has been investigated also by using UV−VIS spectroscopy. This method allowed us to draw the photo-isomerization and relaxation curves. Also, preliminary tests were conducted to determine the capacity of the film surface to immobilize DNA molecules.     

Analytical formula for three points sinusoidal signals amplitude estimation errors

In this note, we show that the amplitude estimation of sinusoidal signals proposed in Wu and Hong [Wu, S.T., and Hong, J.L. (2010), ‘Five-point Amplitude Estimation of Sinusoidal Signals: With Application to LVDT Signal Conditioning’, IEEE Transactions on Instrumentation and Measurement, 59, 623–630] is a particular case of Vizireanu and Halunga [Vizireanu, D.N, and Halunga, S.V. (2011), ‘Single Sine Wave Parameters Estimation Method Based on Four Equally Spaced Samples’, International Journal of Electronics, 98(7), pp. 941–948]. An analytical formula for amplitude estimation errors as effects of sampling period deviation is obtained.     

Antibacterial activity of silver-modified natural clinoptilolite

The aim of the present work was to estimate the bactericidal activity and efficacy of silver pre-treated clinoptilolite-rich tuff from Marsid (Romania) in solid media (agar plates) against Gram-negative Escherichia coli ATCC 25922 and Gram-positive Staphylococcus aureus ATCC 25923. Two samples of natural clinoptilolite-rich tuff was first pre-treated with oxalic acid and sodium hydroxide solutions, respectively. The sample treated with oxalic acid was then exchanged with sodium chloride solution to obtain sodium form. Finally, both samples were exchanged with silver nitrate solution at room temperature for 24 h to obtain silver forms (P1-Ag⁺ and P2-Ag⁺) of clinoptilolite. The structure, morphology, and elemental composition of the pre-treated clinoptilolite samples were characterized by XRD, infrared (ATR-IR), SEM, and EDX analysis. The antibacterial activity was investigated by exposing E. coli and S. aureus in nutritive agar to the silver-clinoptilolite samples. Microorganisms were completely inhibited at 2 mg Ag⁺-clinoptilolite/mL nutritiv medium after 24 h of incubation at 37 °C. The silver-clinoptilolite sample derived from natural clinoptilolite pre-treated with oxalic acid (P1-Ag⁺) exhibit a stronger antibacterial effect in the presence of E. coli and the sample derived from natural clinoptilolite pre-treated with sodium hydroxide (P2-Ag⁺) in the presence of S. aureus.     

A fast,simple and accurate time-varying frequency estimation method for single-phase electric power systems

This paper presents a simple and accurate method to estimate time-varying frequency for single-phase electric power systems, based on three equally spaced samples. A sinusoidal voltage signal model, without dc offset, with time-varying frequency was assumed. Analytical formulas are derived. The method shows good estimation accuracy over a real world wide range of frequency changes. Simulations have been performed.     

烧结造块粉状物料的造球机理

提高粉状物料造球效果的技术措施是基于对微造球机理的认识。假定了基于第一中心和第二中心的两种微造球机理。为了描述和解释原料粒度结构组成对微造球机理的影响,定义了两个新参数,即N1和N2两个比率,并介绍了关于N1、N2重要性的的试验结果和相关技术措施。     

Recent developments of biofuels/bioenergy sustainability certification: A global overview

The objective of this paper is to provide a review on the latest developments on the main initiatives and approaches for the sustainability certification for biofuels and/or bioenergy. A large number of national and international initiatives lately experienced rapid development in the view of the biofuels and bioenergy targets announced in the European Union, United States and other countries worldwide. The main certification initiatives are analysed in detail, including certification schemes for crops used as feedstock for biofuels, the various initiatives in the European Union, United States and globally, to cover biofuels and/or biofuels production and use. Finally, the possible way forward for biofuel certification is discussed. Certification has the potential to influence positively direct environmental and social impact of bioenergy production. Key recommendations to ensure sustainability of biofuels/bioenergy through certification include the need of an international approach and further harmonisation, combined with additional measures for global monitoring and control. The effects of biofuels/bioenergy production on indirect land use change (ILUC) is still very uncertain; addressing the unwanted ILUC requires sustainable land use planning and adequate monitoring tools such as remote sensing, regardless of the end-use of the product.     

Combined FPPE–PTR Calorimetry Involving TWRC Technique. Theory and Mathematical Simulations

Photopyroelectric calorimetry in the front detection configuration (FPPE) was combined with photothermal radiometry (PTR), in order to investigate dynamic thermal parameters of different layers of a detection cell. The layout of the detection cell consists of three layers: directly irradiated pyroelectric sensor, liquid layer, and solid backing material; and the scanning parameter is the thickness of the liquid layer (thermal-wave resonator cavity method). The theory developed for the two techniques indicates that both FPPE and PTR signals can lead, in the thermally thin regime for the sensor and liquid layer, to the direct measurement of the thermal diffusivity or effusivity of the sensor and/or liquid layer, or the thermal effusivity of the backing material. The two methods offer complementary results and/or reciprocally support each other.     

A methodology of computation,design and optimization of solar Stirling power plant using hydrogen/oxygen fuel cells

The objective of this paper is to develop a methodology to determine how many houses could be fueled from the solar energy captured by a number of solar Stirling modules (with a fixed dish area per module) and also to determine the minimum necessary area of the fuel cell to ensure the amount of power needed to meet daily energy use requirements. The detailed method includes the effect of the fuel cell efficiency function on the power consumption of the user. Experimental data from our laboratory are used to determine the fuel cell efficiency as a function of the electric current density for a specific power demand. As an illustrative example, the analysis is applied to a residential area having a specific electrical demand. Using the developed method, the number of houses that could be fueled directly by the stored hydrogen is determined, and also the minim fuel cell area required.     

UV Raman imaging--a promising tool for astrobiology: comparative Raman studies with different excitation wavelengths on SNC Martian meteorites

The great capabilities of UV Raman imaging have been demonstrated on the three Martian meteorites: Sayh al Uhaymir, Dar al Gani, and Zagami. Raman spectra without disturbing fluorescence and with high signal-to-noise-ratios and full of spectral features were derived. This result is of utmost importance for the development of powerful instruments for space missions. By point scanning the surfaces of the meteorite samples, it was possible for the first time to construct UV-Raman images out of the array of Raman spectra. Deep-UV Raman images are to the best of our knowledge presented for the first time. The images were used for a discussion of the chemical-mineralogical composition and texture of the meteorite surfaces. Comparative Raman studies applying visible and NIR Raman excitation wavelengths demonstrate a much better performance for UV Raman excitation. This comparative study of different Raman excitation wavelengths at the same sample spots was done by constructing a versatile, robust sample holder with a fixed micro-raster. The overall advantages of UV resonance Raman spectroscopy in terms of sensitivity and selectivity are demonstrated and discussed. Finally the application of this new technique for a UV Raman instrument for envisaged astrobiological focused space missions is suggested.