Characterisation of the neutral oil from a low-temperature coal tar

Tar resulting from fluidised-bed, low-temperature carbonisation of coal was treated to yield a neutral oil from which a series of six other samples was extracted. These were examined by proton magnetic resonance (p.m.r.) spectroscopy, low-ionising-voltage (11 eV) mass spectroscopy (m.s.), gel chromatography followed by fluorescent indicator analysis, and cryoscopy. Aliphatic fractions separated chromatographically were also examined by infra-red spectroscopy. Distributions of hydrogen between chemical types were found for the several fractions from 60 MHz p.m.r. spectra and presented in terms of average structural parameters. M.s. analysis indicated negligible cracking of paraffin components, and the average molecular weight of 197 agreed well with cryoscopic determinations. For the carbon ratio, f_a, between aromatic and total, agreement between m.s. and p.m.r. depends on the p.m.r. structural analysis scheme adopted. P.m.r. and m.s. structural analyses of the aromatics emphasise the predominance of di- and tri-nuclears, with about 40% of available sites substituted, and the importance of acenes in lowtemperature carbonisation material. Gas and gel chromatography showed urea-adductable paraffins to be largely straight-chain C₁₀-C₂₆, much as for tars from carbonisation at higher temperature.     

Preparation of optically active poly β-propiolactones

Racemic -methyl--n-propyl--propiolactone is readily polymerized with zinc and cadmium chiral glycolates leading to optically active polyesters. The stereoelectivities observed are lower than for oxiranes and thiiranes with the same initiator system. A value of rotatory power for pure enantiomer _o, is deduced from NMR measurements in the presence of chiral solvent. The structure of polymers is discussed on the basis of NMR results.     

Identification of intra-individual variation in intracranial arterial flow by MRI and the effect on computed hemodynamic descriptors

Magnetic Resonance Materials in Physics, Biology and Medicine - To determine the intra-individual flow variation in serially acquired studies, and the influence of this variation on subsequent...     

Korrosion von ölgefeuerten Zentralheizungskesseln

Corrosion of oil-fired domestic boilers Depending on the surface temperature of the flue gas side the corrosion of oil fired domestic boilers proceeds either mainly by acid corrosion or by oxygen corrosion:

• – At surface temperatures of 60°C and higher the corrosion mechanism of acid corrosion prevails and the corrosion rates amount to 0.1–0.3 mm/year (values referred to continuous burner operation). The corrosion products consist of soluble iron(II)- and iron(III)sulfates. Higher corrosion rates can be attributed to an appreciable catalytic formation of sulfur trioxide on the corrosion products formed on the convective heating surfaces.
• – At surface temperatures of 40°C the mechanism of oxygen corrosion already dominates and the corrosion rates are about ten times higher (1.5–3 mm/year, referred to continous burner operation). The high portion of ioron oxide hydrates, especially goethit (α-FeOOH), makes the corrosion products difficult to remove.
• – Distinctly reduced service lives are also expected for the so called reduced temperature boilers (“Niedertemperaturkessel”) and low temperature boiers (“Tieftemperaturkessel”): According to the manufacturers these boilers may be operated at boiler water temperatures well below 60°C, as they are equipped with constructive measures to enhance the surface temperature on the flue gas side. However, these measures are only fully effective under stationary conditions.

Some of the results were obtained from weight loss measurements on test specimen made from St 35.8 and gray cast iron, that were exposed to the flue gases of an oil fired experimental boiler. Other important results come from field measurements of the sulfuric acid content of about 30 boilers that are in practical use.     

Fracture and mechanical properties of P100 Gr/6061 Al composite

The effects of heat treatments on the mechanical and fracture properties of continuous fiber Pitch 100 graphite/6061 aluminum (P100 Gr/6061 Al) composite were evaluated by varying solution temperature and aging time. All heat treatments resulted in decreased mechanical properties due to the reaction at the fiber/matrix interface during solution treatments. SEM analysis of the fractured samples showed a large degree of fiber pullout, interface failure, and matrix cracking.     

Debugging mixed‐environment programs with Blink

Programmers build large‐scale systems with multiple languages to leverage legacy code and languages best suited to their problems. For instance, the same program may use Java for ease of programming and C to interface with the operating system. These programs pose significant debugging challenges, because programmers need to understand and control code across languages, which often execute in different environments. Unfortunately, traditional multilingual debuggers require a single execution environment. This paper presents a novel composition approach to building portable mixed‐environment debuggers, in which an intermediate agent interposes on language transitions, controlling and reusing single‐environment debuggers. We implement debugger composition in Blink, a debugger for Java, C, and the Jeannie programming language. We show that Blink is (i) simple: it requires modest amounts of new code; (ii) portable: it supports multiple Java virtual machines, C compilers, operating systems, and component debuggers; and (iii) powerful: composition eases debugging, while supporting new mixed‐language expression evaluation and Java native interface bug diagnostics. To demonstrate the generality of interposition, we build prototypes and demonstrate debugger language transitions with C for five of six other languages (Caml, Common Lisp, C#, Perl 5, Python, and Ruby) without modifications to their debuggers. Using real‐world case studies, we show that diagnosing language interface errors require prior single‐environment debuggers to restart execution multiple times, whereas Blink directly diagnoses them with one execution. Copyright © 2014 John Wiley & Sons, Ltd.     

A wireless embedded tongue tactile biofeedback system for balance control

We describe the architecture of an original biofeedback system for balance improvement for fall prevention and present results of a feasibility study. The underlying principle of this biofeedback consists of providing supplementary information related to foot sole pressure distribution through a wireless embedded tongue-placed tactile output device.Twelve young healthy adults voluntarily participated in this experiment. They were asked to stand as immobile as possible with their eyes closed in two conditions of no-biofeedback and biofeedback. Centre of foot pressure (CoP) displacements were recorded using a force platform. Results showed reduced CoP displacements in the biofeedback relative to the no-biofeedback condition.On the whole, the present findings evidence the effectiveness of this system in improving postural control on young healthy adults. Further investigations are needed to strengthen the potential clinical value of this device.