Carbon Black-Supported Single-Atom Co?N?C as an Efficient Oxygen Reduction Electrocatalyst for H2O2 Production in Acidic Media and Microbial Fuel Cell in Neutral Media

Single metal atom isolated in nitrogen-doped carbon materials (M N C) are effective electrocatalysts for oxygen reduction reaction (ORR), which produces H₂O₂ or H₂O via 2-electron or 4-electron process. However, most of M N C catalysts can only present high selectivity for one product, and the selectivity is usually regulated by complicated structure design. Herein, a carbon black-supported Co N C catalyst (CB@Co N C) is synthesized. Tunable 2-electron/4-electron behavior is realized on CB@Co-N-C by utilizing its H₂O₂ yield dependence on electrolyte pH and catalyst loading. In acidic media with low catalyst loading, CB@Co N C presents excellent mass activity and high selectivity for H₂O₂ production. In flow cell with gas diffusion electrode, a H₂O₂ production rate of 5.04 mol h⁻¹ g⁻¹ is achieved by CB@Co N C on electrolyte circulation mode, and a long-term H₂O₂ production of 200 h is demonstrated on electrolyte non-circulation mode. Meanwhile, CB@Co N C exhibits a dominant 4-electron ORR pathway with high activity and durability in pH neutral media with high catalyst loading. The microbial fuel cell using CB@Co N C as the cathode catalyst shows a peak power density close to that of benchmark Pt/C catalyst.     

Regulating Fe Aggregation State via Unique Fe?N?V Pre-Coordination to Optimize the Adsorption-Catalysis Effect in High-Performance Lithium-Sulfur Batteries

Lithium-sulfur batteries (LSBs) suffer from uncontrollable shuttling behavior of lithium polysulfides (LiPSs: Li₂S_x, 4 ≤ x ≤8) and the sluggish reaction kinetics of bidirectional liquid-solid transformations, which are commonly coped through a comprehensive adsorption-catalysis strategy. Herein, a unique Fe N V pre-coordination is introduced to regulate the content of “dissociative Fe³⁺” in liquid phase, realizing the successful construction of N-doped micro-mesoporous “urchin-like” hollow carbon nanospheres decorated with single atom Fe-N₄ sites and VN nanoparticles (denoted as SA-Fe/VN@NMC). The strong chemisorption ability toward LiPSs and catalyzed Li₂S decomposition behavior on VN, along with the boosted reaction kinetics for sulfur reduction on SA-Fe sites are experimentally and theoretically evidenced. Moreover, the nanoscale-neighborhood distribution of VN and SA-Fe active sites presents synergistic effect for the anchoring-reduction-decomposition process of sulfur species. Thus SA-Fe/VN@NMC presents an optimized adsorption-catalysis effect for the whole sulfur conversion. Therefore, the SA-Fe/VN@NMC based Li-S cells exhibit high cyclic stability (a low decay of 0.024% per cycle over 700 cycles at 1 C, sulfur content: 70 wt%) and considerable rate performance (683.2 mAh g⁻¹ at 4 C). Besides, a high areal capacity of 5.06 mAh cm⁻² is retained after 100 cycles under the high sulfur loading of 5.6 mg cm⁻². This work provides a new perspective to design the integrated electrocatalysts comprising hetero-formed bimetals in LSBs.     

液体火箭发动机喷雾液滴内部流动及传热数值模拟

液体火箭发动机喷雾液滴在表面剪切力的作用下形成内部环流,影响液滴内部传热特性,进而影响喷雾蒸发燃烧过程.将一种基于光滑压力修正的非交错网格sIMPLE算法推广到一般曲线坐标系,并对液滴表面特殊边界条件进行数值处理,然后采用代数法生成正交贴体结构网格,求解气相及液相轴对称不可压流动控制方程,得到运动液滴内部稳态流场及其温...     

航天级双读数多圈绝对式光电编码器设计

利用多圈光电编码器具有体积小、量程大以及数字量输出等优点,设计了基于双读数系统的航天级多圈绝对式光电编码器。根据航天相机的精度要求,采用精度高、分辨率高的绝对式矩阵玻璃码盘作为一级码盘完成角度测量;根据电机转动的计数要求,采用重量轻,体积小的绝对式矩阵金属码盘作为二级码盘完成对一级码盘的转动圈数计数;其具有的双狭缝及双读数系统可实现信号处理电路冷备份。按照鉴定级航天产品要求,通过热学环境实验和力学环境实验对编码器性能进行了验证。实验结果表明,所设计的编码器精度范围为±100″内、分辨率为80″、测量圈数为16圈、外形尺寸为φ50 mm×50 mm、重量为270 g,稳定性高、可靠性强,且满足高分辨率航天设备设计指标。     

LightSheer半导体激光脱毛的疗效评价

目的:评价LightSheer半导体激光脱毛的治疗效果。方法:运用LightSheer半导体激光脱毛系统,对97名患者共113个部位进行脱毛治疗,波长800nm,能量密度24-40J/cm2,脉冲宽度30ms,分别对治疗一次、二次及三次后的有效性进行分级评价。结果:97名患者共113个部位一次治疗后均出现毛发再生减少、再生延迟,再生毛发细小、浅淡。随着治疗次数的增加有效性分级提高。二次治疗后,60%以上可达到3级(毛发减少40-59%);三次治疗后,80%以上可达到3级。腋窝和唇毛部位约50%可达到4级(毛发减少60-79%)。结论:LightSheer半导体激光脱毛系统对亚洲人是安全和有效的,80%的患者经三次治疗后毛发可减少近60%,但要达到更好的疗效需更多次治疗。     

小功率单片CMOS不间断电源

介绍了一种无工频变压器的小功率单片ＣＭＯＳ不间断电源（ＵＰＳ）。它由一片ＭＡＸ６１０构成,电路结构简单,外围元件少,体积小,稳压性能良好,而且具有欠压,过压保护和电流过流保护,适用于小型智能仪器和便携式数字仪表。     

样本容量对子孔径拼接检测精度影响的分析

应用数理统计理论及线性回归分析方法详细分析了在子孔径拼接检测中样本容量对测量精度的影响,通过计算确定了当子孔径拼接干涉检测中样本容量大于10 4时,即可保证检测精度,又能减小计算的复杂程度。     

TiO2/MXene-Assisted LDI-MS for Urine Metabolic Profiling in Urinary Disease

Cancer remains an intractable medical problem. Rapid diagnosis and identification of cancer are critical to differentiate it from nonmalignant diseases. High-throughput biofluid metabolic analysis has potential for cancer diagnosis. Nevertheless, the present metabolite analysis method does not meet the demand for high-throughput screening of diseases. Herein, a high-throughput, cost-effective, and noninvasive urine metabolic profiling method based on TiO₂/MXene-assisted laser desorption/ionization mass spectrometry (LDI-MS) is presented for the efficient screening of bladder cancer (BC) and nonmalignant urinary disease. Combined with machine learning, TiO₂/MXene-assisted LDI-MS enables high diagnostic accuracy (96.8%) for the classification of patient groups (including 47 BC and 46 ureteral calculus (UC) patients) from healthy controls (113 cases). In addition, BC patients can also be identified from noncancerous UC individuals with an accuracy of 88.3% in the independent test cohort. Furthermore, metabolite variations between BC and UC individuals are investigated based on relative quantification, and related pathways are also discussed. These results suggest that this method, based on urine metabolic patterns, provides a potential tool for rapidly distinguishing urinary diseases and it may pave the way for precision medicine.     

光纤Bragg光栅地震检波器的研究

由光纤Bragg光栅制成的地震检波器,其采集的传感信息包含在波长上,直接对波长进行调制解调,具有分辨率高、精度高、抗干扰能力强和频带宽等优点.文章研究了光纤Bragg光栅地震检波器,给出其重要参数,并提出了一种新的光纤Bragg光栅地震检波器的解调方案.为光纤Bragg光栅地震检波器的研究以及实际应用提供了依据.     

Metal Micropatterning by Triboelectric Spark Discharge

Metal micropatterns play critical roles in flexible electronics. However, the lack of versatile strategies for micropatterning of diverse metal materials on various thin, flexible or stretchable substrates has limited the rapid development of flexible electronics. Here, a metal micropatterning method by triboelectric spark discharge under atmospheric environment is developed, where a triboelectric nanogenerator (TENG) is employed to precisely and safely control the voltage, current, and frequency of the spark discharges. Micropatterns of metal films like gold, silver, copper, aluminum and platinum are successfully fabricated on substrates of polyimide, polyethylene terephthalate, polyvinyl chloride, polydimethylsiloxane, paper or latex, even on ultrathin substrates (5 μm thick) without damage, where the feature sizes of metal patterns are controllable from 20 μm to 1 mm. Experimental insights into the triboelectric spark discharge behaviors and the pattern feature sizes control are discussed. A straightforward fabrication of metal patterns on the balloon surface or human skin through “handwriting” by a pencil as discharge electrode is realized. Besides metals, extended processibility of conductive materials like carbon nanotubes, graphene, MXene, graphite, carbon fibers, and conductive polymers are also demonstrated. This work proves the possibility of microfabrication by TENG, which is of simplicity and attractiveness for flexible electronics.