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41.
When localized transverse loading is applied to a sandwich structure, the facesheet locally deflects and the core crushes. A residual dent induced by the core crushing significantly degrades the mechanical properties of the sandwich structure. In a previous paper, the authors established a “segment-wise model” for theoretical simulation of barely visible indentation damage in honeycomb sandwich beams with composite facesheets. Honeycomb sandwich beam was divided into many segments based on the periodic shape of the honeycomb and complicated through-thickness characteristics of the core were integrated into each segment. In this paper, the new model is validated by experiments using specimens with different types of honeycomb cores. In addition, the damage growth mechanism under indentation load was clarified from the viewpoint of the reaction force from the core to the facesheet. The applicability of the model to other types of core materials is also discussed. 相似文献
42.
Ryo Toda Yuki Matsushita Mitsunori Hieda Taku Matsushita Nobuo Wada 《Journal of Low Temperature Physics》2007,148(5-6):785-790
We have measured the heat capacity of 3He adsorbed on three-dimensionally connected nanopores, 2.7 nm in diameter, preplated with about 1.3 atomic layers of 4He. At low coverages of 3He, the 3He heat capacity is roughly constant at the measured temperatures between 0.1 and 1 K. Its molar heat capacity is on the order
of the gas constant R, between 1.1R and 1.8R. This suggests a Boltzmann gas state of the adsorbed 3He. At high coverages, the heat capacity is likely approaching linear in T at low temperatures, which suggests a degenerate state at further lower temperatures. 相似文献
43.
Nobuhiro Kumada Nobuo Ozawa Nobukazu Kinomura Fumio Muto 《Materials Research Bulletin》1985,20(5):583-589
Pyrochlores of A1?xHxTaO3·nH2O (A=Na,K) were prepared under the hydrothermal conditions. The values of x for these compounds were increased from 0.3 to 0.5 for A=Na and from 0.2 to 0.5 for A=K by treatment with the distilled water. The compounds with x<0.5 were decomposed to a mixture of NaTaO3 and Na2Ta4O11 for A=Na, or to a mixture of KTaO3 and a tetragonal tungsten bronze phase, and those with x=0.5 to a single phase of A2Ta4O11 at elevated temperatures. Below the decomposition temperatures, defect pyrochlores with oxygen vacancies, , were produced. They were hygroscopic, and in the case of A=K and x=0.5 the original phase was recovered by leaving in air for several hours. 相似文献
44.
Tomotaka Hashimoto Nobuo Ishizawa Nobuyasu Mizutani Masanori Kato 《Journal of Materials Science》1988,23(3):1102-1105
The temperature dependence of the electrical resistivity and Seebeck coefficient was measured on single crystals of La1–x
Ca
x
MnO3(0 <x 0.3) and La1–x
Sr
x
MnO 3 (0 <x 0.4) grown by the arc-image floating zone method. The electrical conduction for La1–x
crystals withx 0.2 was of the activation type aboveT
c and of the degenerate type belowT
c, while that for the crystal withx = 0.1 was of the activation type over the whole measured temperature range between –170 and 400°C. The conduction behaviour of La1–
x
Sr
x
MnO3 was essentially the same as that of La1–x
Ca
x
MnO3 except that the conduction of the crystals withx = 0.3 and 0.4 was of the degenerate type aboveT
c. A distinct difference in Seebeck data was observed between the calcium and the strontium compounds. 相似文献
45.
Formaldehyde (HCHO) emitted from the furniture and the walls in the rooms injures the eyes, nose, and respiratory organs and causes allergies, which is called sick house syndrome. We designed and synthesized novel colorimetric HCHO-sensing molecules (KD-XA01 and KD-XA02) which possess an enaminone structure and developed a hand-held instrument to monitor indoor HCHO gas with the use of KD-XA01. These sensing molecules produced speedy color changes from colorless to yellow under mild conditions, which was caused by the fact that the enaminone structure in the reagent reacts with HCHO to give a lutidine derivative. This reaction took place not only in the solution phase but also in the solid phase (surface of the cellulose paper). To take advantage of this phenomena, a handy and rapid monitoring system has been developed for detecting indoor HCHO gas using a highly sensitive and selective detection tablet constructed from the porous cellulose paper that contains silica gel as an adsorbent, KD-XA01, and phosphoric acid under optimum conditions. This instrument detected the surface color change of the tablet from white to yellow, which was monitored as a function of the intensity of the reflected light illuminated by an LED (475 nm). The response was proportional to the HCHO concentration at a constant sampling time and flow rate; 0.05 ppm HCHO, which is under the standard value set by the World Health Organization, was able to be detected in 5 min. The detection limit was 0.005 ppm. This monitoring system was not interfered by carbonyl compounds such as acetaldehyde and acetone, alcohols, hydrocarbons, and typical gases such as carbon monoxide, carbon dioxide, nitrogen dioxide, etc., which contributes to the measurement of correct HCHO concentrations. It was possible to monitor the HCHO gas in the room of a new apartment and school using this instrument; the response values were in good agreement with those obtained by the standard DNPH method. This highly sensitive, selective, and handy HCHO gas monitor is widely applicable and convenient for users who are not specialists in this field. 相似文献
46.
Kenji Goto Takuya Kawashima Nobuo Tanabe 《Solar Energy Materials & Solar Cells》2006,90(18-19):3251-3260
We developed new heat-resisting transparent conductive oxide (TCO) films with resistivity of 1.4×10−4 Ω cm, an optical transmittance of above 80% (at 550 nm) and heat-resisting temperature at above 600 °C. The TCO films consists of fluorine-doped tin oxide films coated on indium–tin oxide films. They were prepared by a spray pyrolysis deposition method on glass substrates. The 100×100 mm2 dye-sensitized solar cells (DSCs) were prepared with the TCO films. An energy conversion efficiency of the DSC was improved drastically in comparison to the case with conventional TCO films. 相似文献
47.
Kazuo Yamana Masayasu Tokonami Kohji Nobugai Nobuo Morimoto† Mitsue Koizumi Isamu Shindo 《Journal of the American Ceramic Society》1981,64(3):43-c-
A birefringence of siliceous glass, which is coexisting with mullite crystals, was studied by an optical polarizing microscope. The cause of the birefringence was assumed to be the residual stress induced by a large contraction difference between the mullite and glass on cooling. The stress has been evaluated to be as high as—0.3 GPa, and to correspond to the elastic one which began to develop at the glass transition point. 相似文献
48.
Synthesis and hydrophilic property of polypropylene-graft-poly(polyethylene glycol-methacrylate) (PP-g-P(PEGMA)) 总被引:1,自引:0,他引:1
Nobuo Kawahara Junji Saito Shingo Matsuo Hideyuki Kaneko Tomoaki Matsugi Norio Kashiwa 《Polymer Bulletin》2010,64(7):657-666
Polypropylene-graft-poly(polyethylene glycol-methacrylate) (PP-g-P(PEGMA)), which is a hydrophobic-hydrophilic graft copolymer, was synthesized by a combination of an atom transfer radical polymerization (ATRP) of PEGMA with brominated polypropylene (PP-Br), which was synthesized from PP-OH prepared by metallocene-catalyzed copolymerization. Its structure was confirmed by 1H NMR and GPC analyses. Transmission electron microscope (TEM) micrographs of PP-g-P(PEGMA) revealed the nanometer level microphase-separation morphology between the PP segment and the P(PEGMA) segment. The obtained PP-g-P(PEGMA) showed water-absorbing property as well as thermostability. 相似文献
49.
Superhydrophobic/superhydrophilic micropatterning on a carbon nanotube (CNT) film has been achieved using a laser plasma-type hyperthermal atom beam facility, which produces a small amount of damage and generates a highly anisotropic beam. Fluorination and oxidation on CNT films by exposure to fluorine-atom and oxygen-atom beams caused superhydrophobic and superhydrophilic surfaces, respectively, while maintaining the as-grown fibrous forms of the CNT films. Micropatterned oxidation on CNT films without using photoresists created superhydrophilic microdots and microchannels. 相似文献
50.
Ryuichi Sugimoto Hideyuki Kaneko Junji Saito Nobuo Kawahara Shingo Matsuo Tomoaki Matsugi 《Polymer Bulletin》2014,71(6):1421-1431
This paper introduces the new synthetic methodology of polyolefin-based block and graft copolymers with polar segments [e.g., polystyrene and poly(meth)acrylates]. Various brominated polyolefins were prepared by bromination of polyolefins with N-bromosuccinimide. The resulting brominated polyolefins were able to initiate the controlled radical polymerization of polar monomers, such as methyl methacrylate, ethyl acrylate, t-butyl acrylate, styrene and 2-(dimethylamino)ethyl acrylate, using a CuBr/N,N,N′,N″,N″-pentamethyldiethylenetriamine catalyst system, leading to a variety of polyolefin-based copolymers with a different content of the corresponding polar segment. Because of the accessible synthesis of polyolefin macroinitiators, this synthetic methodology is expected to result in the preparation of a wide range of polyolefin-based block and graft copolymers. 相似文献