Hydrogen storage in nickel catalysts supported on activated carbon

We have studied hydrogen storage in a commercial activated carbon impregnated with nickel. High-pressure (20–30 bars) hydrogen uptake at room temperature was assessed using a high-pressure volumetric adsorption–desorption system. The properties of the prepared materials were studied by means of _N2${\mathrm{N}}_2$ physisorption, X-ray diffraction, transmission electron microscopy, metal surface area, hydrogen temperature programmed reduction and hydrogen temperature programmed desorption. Various factors influencing the level of hydrogen uptake (metal precursor, metal content, method of preparation) were examined and discussed. It is concluded that the hydrogen stored is loosely chemisorbed on the carbonaceous material surface as spilt-over species through _H2${\mathrm{H}}_2$ dissociation on the metal phase then migration onto the support. This hydrogen would also be directly adsorbed on carbon acceptor sites induced by _H2${\mathrm{H}}_2$-pretreatment at 623 K. In both cases, the stored hydrogen directly desorbs from the active carbon support.     

Diffusion analysis and modeling of kinetic behavior for treatment of brine water using electrodialysis process

In this study, the removal of monovalent and divalent cations, Na⁺, K⁺, Mg²⁺, and Ca²⁺, in a diluted solution from Chott-El Jerid Lake, Tunisia, was investigated with the electrodialysis technique. The process was tested using two cation-exchange membranes: sulfonated polyether sulfone cross-linked with 10% hexamethylenediamine (HEXCl) and sulfonated polyether sulfone grafted with octylamine (S-PESOS). The commercially available membrane Nafion® was used for comparison. The results showed that Nafion® and S-PESOS membranes had similar removal behaviors, and the investigated cations were ranked in the following descending order in terms of their demineralization rates: Na⁺ > Ca²⁺ > Mg²⁺ > K⁺. Divalent cations were more effectively removed by HEXCl than by monovalent cations. The plots based on the Weber–Morris model showed a strong linearity. This reveals that intra-particle diffusion was not the removal rate-determining step, and the removal process was controlled by two or more concurrent mechanisms. The Boyd plots did not pass through their origin, and the sole controlling step was determined by film-diffusion resistance, especially after a long period of electrodialysis. Additionally, a semi-empirical model was established to simulate the temporal variation of the treatment process, and the physical significance and values of model parameters were compared for the three membranes. The findings of this study indicate that HEXCl and S-PESOS membranes can be efficiently utilized for water softening, especially when effluents are highly loaded with calcium and magnesium ions.     

Hydrogen production via steam and autothermal reforming of beef tallow: A thermodynamic investigation

A thermodynamic analysis of hydrogen production via steam and autothermal reforming of beef tallow has been carried out via the Gibbs free energy minimization method. Equilibrium calculations are performed at atmospheric pressure with a wide range of temperatures (400–1200 °C), steam-to-beef tallow ratios (1–15) and oxygen-to-beef tallow ratios (0.0–2.0).     

Intrusion detection and tolerance: A global scheme

Protecting implemented security mechanisms and trusting their output (e.g. log files) when the host, under which they are deployed, is compromised, is among the major challenges that have to be faced. To fulfil this need, recent advances in security have considered the design of storage-based intrusion detection system, which detect intrusions by looking at the low-level disk requests patterns. However, these systems neither tolerate intrusions, nor do they distinguish whether the disk requests are generated by legitimate or malicious processes; and consequently, they generate a lot of false negative and positive alerts. In this paper, we present a Cooperative Intrusion Detection and Tolerance System, called CIDTS, which takes advantage of the information that are available at the network, host operating system, and storage level to better detect intrusion attempts in their early stages, even when the host is compromised. To allow cooperation, the disk communication interface that transports requests between the storage level and the host level is extended to forward information about the processes that generate the request. The paper also provides intrusion tolerance capabilities and provides techniques to support investigation activities. Copyright © 2007 John Wiley & Sons, Ltd.     

WHOMoVeS: An optimized broadband sensor network for military vehicle tracking

With the advance of sensing technologies and their applications, advanced sensor networks are gaining increasing interest. For certain sensitive applications, heterogeneous sensors can be deployed in the monitored space to ensure scalability, high-speed communication, and long network lifetime. Hybrid sensor networks have capabilities to combine the use of both resource-rich and resource-impoverished sensor nodes. This paper proposes a heterogeneous broadband sensor network architecture for military vehicle tracking. Powerful sensor devices with good bandwidth and energy capabilities are used as a communication backbone while energy sensors are used to track moving targets. Copyright © 2007 John Wiley & Sons, Ltd.     

Efficient Realization of Large Size Two’s Complement Multipliers Using Embedded Blocks in FPGAs

This paper presents an optimized design approach for two’s complement large size multipliers using smaller size embedded multiplier blocks available as resources in field programmable gate arrays (FPGAs). The realization is based on the Baugh–Wooley algorithm, which segments the multiplication into unsigned and signed components. To achieve efficient implementation results, a set of optimized schemes for the realization of the additions required for the unsigned multipliers and for combining the unsigned and signed components is proposed. The implementations of the multipliers have been carried out for operands with sizes ranging from 20 to 128 bits. The designs are synthesized and implemented on Xilinx’s Spartan-3 in the ISE 8.1 design platform and compared with three other realizations using the following approaches: (1) conventional sign-extension approach, (2) Xilinx’s IP-Core generator, and (3) sign-and-magnitude-based approach. The experimental results indicate that our proposed method outperforms the other techniques.     

Adsorption property and affinity chromatography of polystyrene derivative sorbent towards cow's milk xanthine oxidase

On the basis of the biospecific molecular recognition between complementary chemical groups of xanthine oxidase (XO) and their ligands particularly sulphated glycoaminoglycans and heparin. Poly (styrene chlorosulfonyl) particles modified by sulfonate sodium groups was synthesized and its adsorption property towards cow's milk XO was established. The adsorption of XO onto this functional polymer was performed in batch at 4 °C and at pH 6.0 during 30 min. of incubation. The adsorbed XO content at the interface allows establishing the chemisorption isotherm curve. The affinity association estimated from this adsorption isotherm according to the Langmuir equation was found to be significantly high in the magnitude of 1.25 × 10⁶ M^? 1. Affinity chromatography on column using this functional polymer as a stationary phase confirms its high ability to adsorb XO at low ionic strength. In fact, the xanthine oxidase of the crude extract is strongly adsorbed onto the sorbent and is eluted at high ionic strength with out any significant loss of its biological activity. The purified enzyme possesses a protein flavin ratio (PFR) of 6.05 with a specific activity of 1.78 UI/mg. On the other hand, the electrophoresis of XO fraction showed a single band with a molecular weight of about 150 kDa. Thus, the synthesized beads functionalized by sulfonate group could be used efficiently and advantageously in the purification of XO instead of other conventional chromatographic methods which need several steps.     

Inhibitive Effect of Molybdate Ions on the Electrochemical Behavior of Steel Rebar in Simulated Concrete Pore Solution

Metallurgical and Materials Transactions A - Several compounds tested as corrosion inhibitors have proven to possess good effectiveness in protection of steel rebar in concrete. However, most of...     

Characterization of the absorption of theophylline from immediate- and controlled-release dosage forms with a numerical approach using the in vitro dissolution-permeation process using caco-2 cells

After oral administration, drug absorption rate is recognized to be dependent on two major factors: dissolution and intestinal cells permeability. Caco-2 monolayer cells have been largely used as a permeation study model. In this study, a numerical approach funded on an exponential first-order time relationship was tested to compare immediate- and controlled-release tablets of theophylline using a dissolution-permeation system. The dissolution performance using USP II paddle apparatus was coupled to the permeability studies investigated in Caco-2 cell monolayers. The dissolved samples were taken at different times; their pH and osmolarity were adjusted to render them suitable to Caco-2 permeability studies (osmolarity = 300 mosm, pH = 7.4). The experimental data show that the dissolution fits the exponential first-order relationship rate. The permeability values were in a range of 4.45 10(- 6)-5.28 10(- 6) cm/s, and percentages of absorbed drug dose were dependent on the fraction initially present in the donor compartment, indicating that absorption of theophylline was dissolution rate limited. Plotting experimental absorbed fractions (F(a)) against experimental dissolved fractions (F(d)) show that permeation is the rate-limiting step in drug absorption process in the extended release form of theophylline. Our results demonstrate a general agreement between observed F(a)/F(d) relationships and theoretical F(a)/F(d) relationships obtained with our approach funded on dissolution and permeation behavior. We concluded that the couple dissolution-caco-2 system could be a useful tool to characterize intestinal permeation for a new formulation of a drug compared with the conventional one.