炭/炭复合材料制造硅晶体生长坩埚初探

多晶硅用直拉法(CZ)或磁场直拉法(MCZ)拉制成单晶硅棒。晶体生长炉热场零件中的石墨发热体、坩埚等在机械应力和热应力的综合作用下发生变形或损坏造成失效,更换频繁。选用纯度高的炭纤维制成待制件的多孔坯体,经过增密、纯化处理制成炭／炭复合材料坩埚。试制的两体12″炭／炭复合材料坩埚进行了工业性试验。炭／炭复合材料机械强度高、耐热冲击性能和化学稳定性好,其使用寿命大大高于高纯石墨坩埚。两体的连接止口的氧化侵蚀限制了坩埚的使用寿命。单晶硅设备的大型化、炭／炭复合材料势必成为晶体生长炉热场零件的必选材料。     

Effects of ion group content and polyol molecular weight on physical properties of HTPB‐based waterborne poly(urethane‐urea)s

A series of waterborne poly(urethane‐urea)s, WPUUs, based on using nonpolar hydroxyl‐terminated polybutadiene (HTPB) as the soft segment, were successfully synthesized in this article. The effects of the COOH group content and soft‐segment molecular weight (Mn_s) on the dispersion, morphology, and physical properties were investigated. Variations of the particle size, viscosity, and zeta potential were first governed by the hydrophilicity of the polymer chain, and then by the swelling derived from water. Fourier transfer infrared spectroscopy (FTIR) and differential scanning calorimetry (DSC) indicated that the degree of phase separation decreased as the COOH group content increased or as Mn_s decreased. However, the hydrogen bonding between the soft and hard segments and the two‐phase mixing could not occur in this nonpolar HTPB‐based WPUU system, indicating that the hard segments tended to form smaller domains and to pack more loosely. It was attributed to the fact that the presence of bulky ionic salt groups destroyed the ordered arrangement of the hard segments. In this case, the increases of the interface area between the soft and hard phases resulted in that the present behaviors were similar to the phase mixing. In tensile properties, HTPB‐based WPUUs exhibited higher tensile stress, elongation at break, and modulus as the COOH group content decreased or as Mn_s decreased. In thermal degradation, the introduction of HTPB polyol improved the thermal stability of WPUU. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2007     

原材料价格波动下钢铁生产库存多期优化模型

考虑钢铁企业钢材生产受钢材需求和生产变动成本波动的双重影响,在预测基础上,建立钢材生产库存多期动态优化模型。由于模型涉及多种钢材及多个时段,属于大规模问题,求解困难,且为了避免粒子群算法陷入局部最优,提出采用模拟退火与粒子群组合智能算法对模型进行求解。最后通过钢铁企业L的案例,结果表明算法具有较强的收敛性和适用性,模型可用于解决钢铁企业多期生产实际问题。     

Identification of new sesquiterpenoids in cephalic secretion of cuckoo bee,Nomada lathburiana (Apoidea,Anthophoridae)

A series of new sesquiterpene ketones and norsesquiterpene ketones could be identified from the cephalic secretion of females of the cuckoo bee,Nomada lathburiana (K.). The major component proved to be 2,6,10-trimethylundeca-(5E)-2,5,9-trien-4-one. Large amounts of high-boiling-point straight-chain hydrocarbons serve as solvents for the volatile, unstable ketones.     

取代2-四氢萘酮的一步合成新方法研究

本文介绍了一步法制备取代2-四氢萘酮的新方法,与常规合成方法相比,该法具有明显的优点:不需要先将羧酸转化成酰氯,避免了三氯化铝以及含氯溶剂的应用,并使催化剂得以循环利用。因此,该方法安全、环保,有望取代常规的付-克反应在工业上的应用。     

Modification of a carbon/carbon composite with a thermosetting resin precursor as a matrix by the addition of carbon black

Carbon/carbon composites were made through the pyrolysis of stabilized PAN felt and phenolic resin with the addition of 5 or 10 wt % carbon black to the matrix and then heat treatment at 600–2500°C. The effects of adding carbon black to the matrix precursor on the physical properties, microstructure, and mechanical properties of the resultant composites were investigated. Adding carbon black not only reduced the weight loss but also limited the shrinkage of the resultant composites. Adding carbon black also accelerated the formation of carbon basal planes in the matrix. At 2500°C, the crystalline stacking height in the composite with 10 wt % added carbon black was 200% greater than that with no additive. The flexural strength of the composite also increased from 15 to 42 MPa (almost 300%). © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 333–337, 2006     

基于WPF MVVM的甘蔗种植管理系统

针对甘蔗种植信息化管理的需求,在模型．视图-视图模型（MVVM）设计模式下,运用Windows Presentation Founda-tion（WPF）技术开发基于农业物联网的甘蔗种植管理系统的后台管理软件,拟实现甘蔗种植地图管理、采集数据查询、田地信息管理和种植户管理等功能。重点描述后台管理系统的设计架构和MVVM框架在系统搭建时的运用,并对实现过程中的MVVMLight运用,NHibernate实现对象与数据库映射等关键技术进行解析。系统能正常稳定运行,有较好的稳定性和适用性,可为种植甘蔗提供科学依据。     

十二烷基－二甲基（2－羟基）乙基氯化铵系列季铵盐的缓蚀性能

通过失重法和极化曲线、线性极化两种电化学方法，研究了十二烷基二甲基（２－羟基）乙基氯化铵（１２２）、十四烷基二甲基（２－羟基）乙基氯化铵（１４２）和十六烷基二甲基（２－羟基）乙基氯化铵（１６２）对２０＃碳钢在５％盐酸中的缓蚀作用。并与新洁尔灭（十二烷基二甲基苄基溴化铵）进行了比较。结果表明，它们在酸性介质中具有很好的缓蚀作用。     

TAF-10环氧沥青混合料动态弹性模量及路用性能试验研究

近些年来,环氧沥青混合料以其耐久性好、强度高、冲击韧性优越等特点,广泛地应用于大型桥梁桥面铺装之中.以TAF-10型环氧沥青混合料为研究对象,对其进行不同温度与频率下的动态模量试验,结合时温等效原理,通过Origin数学计算软件,采用西格摩德(Sigmoidal)模型对试验结果进行非线性拟合;并通过高温车辙试验、小梁弯曲试验及冻融劈裂试验,对其高温稳定性、低温抗裂性、水稳定性等路用性能进行检测.结果表明:随着加载频率的增大,TAF-10环氧沥青混合料的动态模量不断增大,而随试验温度的升高其值不断减小;拟合所得到的主曲线方程,可以对任何给定温度与加载频率下该种混合料的动态模量进行有效预估;TAF-10环氧沥青混合料的高温稳定性、低温抗裂性及水稳定性等性能均超出规范要求,满足桥面铺装要求.研究成果可以为TAF-10环氧沥青混合料桥面铺装的动态设计提供参考.     

喷墨技术进展及在电子元件中的应用

喷墨印刷可称之为当前发展最快的印刷技术。为了提高喷墨印刷的质量和扩大喷墨印刷的适用范围,人们正在进行大量的研究和开发工作。本文概要介绍喷墨技术的特点及原理;阐述了喷墨墨滴的产生方法、喷墨油墨以及喷墨介质的性能要求;同时指出了喷墨技术的新进展及其在电子元件中的应用。