Effect of voltage sweep direction on the performance evaluation of P3HT : PCBM solar cells

Investigations on the effect of direction of voltage sweeps, on the current density–voltage (J–V) characteristics in polymer bulk‐heterojunction solar cells, based on the blend of poly(3‐hexylthiophene) (P3HT) and phenyl [6,6] C₆₁ butyric acid methyl ester (PCBM), are reported with time. On the freshly prepared device, the direction of the voltage sweep did not have any effect; however, as the device started degrading, the change in direction of the voltage sweep resulted into different characteristics. Analysis beyond complete degradation, when all the photovoltaic parameters reduced to zero, revealed some interesting results. The J–V characteristics, measured with voltage sweep from −ve to +ve voltage, both in the dark and under illumination, were observed to pass through the second quadrant. On the other hand, with the change in the direction of voltage sweep, viz. from +ve to −ve voltage, the characteristics both in the dark and under illumination passed through the fourth quadrant. These results have been explained on the basis of polarization of the degraded active layer due to applied external voltage. This is an important effect and is observed to depend on the applied voltages during performance evaluation and becomes more prominent with time. This effect puts a question mark on the correctness of the method for calculation of the parameters of a degraded device. Studies on degradation of P3HT : PCBM solar cells showed that both the short circuit current density (J_sc) and the power conversion efficiency (η) decay exponentially, whereas the open circuit voltage (V_oc) decays almost linearly with time. Copyright © 2012 John Wiley & Sons, Ltd.     

Phytofiltration of cadmium from water by Limnocharis flava (L.) Buchenau grown in free-floating culture system

A hydroponics experiment was conducted to examine the phytofiltration of Cd by Limnocharis flava (L.) Buchenau grown in low-level Cd-contaminated water. For this, 45 d old seedlings of L .flava were transferred to a floating-support culture system containing nutrient solution spiked with four levels of Cd (0.5, 1, 2 and 4 mg l⁻¹) and were separately harvested after 3, 7, 21 and 30 d. After 30 d harvesting, the percentage removal of Cd from the above four treatments reached up to 98, 96, 95 and 93%, respectively. Interestingly, all treatments had higher growth rate than control at 95% confidence level and plants still remained healthy at 4 mg l⁻¹ Cd exposure. The bioaccumulation study showed a linear relationship of Cd (R² = 0.896–0.999) in all plant parts with the exposure time (3–30 d) and Cd concentrations in hydroponics system (0.5–4 mg l⁻¹). Although, the root of L. flava had higher Cd concentration than leaf and peduncles, the total Cd concentrations in aerial plant parts were higher than the roots. The maximum bioconcentration factor (BCF) and translocation factor (TF) value of L. flava were calculated as 984.42 and 1.43, respectively. Estimated Cd accumulation capacity of L. flava per unit area (m²) was found to be in the range of 218. 35–1698.92 mg m⁻².The experimental results demonstrated that L. flava is a suitable candidate for the phytofiltartion (>93%) of Cd from low-level Cd-contaminated water.     

Analysis of dispatching rules in a stochastic dynamic job shop manufacturing system with sequence-dependent setup times

Stochastic dynamic job shop scheduling problem with consideration of sequence-dependent setup times are among the most difficult classes of scheduling problems. This paper assesses the performance of nine dispatching rules in such shop from makespan, mean flow time, maximum flow time, mean tardiness, maximum tardiness, number of tardy jobs, total setups and mean setup time performance measures viewpoint. A discrete event simulation model of a stochastic dynamic job shop manufacturing system is developed for investigation purpose. Nine dispatching rules identified from literature are incorporated in the simulation model. The simulation experiments are conducted under due date tightness factor of 3, shop utilization percentage of 90 % and setup times less than processing times. Results indicate that shortest setup time (SIMSET) rule provides the best performance for mean flow time and number of tardy jobs measures. The job with similar setup and modified earliest due date (JMEDD) rule provides the best performance for makespan, maximum flow time, mean tardiness, maximum tardiness, total setups and mean setup time measures.     

Service profit chain and throughput orientation: a manager-employee-customer triad perspective in services

Building on the Theory of Constraints (TOC) in the service context and drawing on internal and external service profit chain literature, we explore the role of throughput orientation at the manager-employee-customer triad level. Controlling for archival performance data at the branch level of banks, in a sample of 136 triads of managers-frontline employees-customers at 37 branches from a bank in a northern state in India, we find that throughput orientation is positively associated with external service profit chain; and this association is further strengthened under stronger internal service profit chain. By integrating a service-operations based perspective of service employees at a triadic level, we demonstrate the importance of throughput orientation in service profit chains.     

Analytic models for the primary site approach to fault-tolerance

Summary A common approach for supporting fault tolerance against node failures is the primary site approach. In this approach the service to be made fault-tolerant is replicated at many nodes, one of which is designated as primary and the others as backups. All the requests for the service are sent to the primary site. The primary site periodically checkpoints its state on the backups. If the primary fails, one of the backups takes over as primary, and to maintain consistency, it first re-executes all the requests performed by the previous primary since the last checkpoint. Two important issues that effect performance of this approach are the frequency of checkpointing and the degree of replication of the service. If the checkpointing interval is decreased the overhead of reexecuting old requests decreases, but the overhead for checkpointing increases. If the degree of replication increases, on the one hand, the availability of the system for user services increases since the reliability of the system increases. On the other hand, the checkpointing time increases, which reduces the availability of the system. In this paper, we present an analytic model to study the optimum checkpointing interval, and a queuing model to study the optimum degree of replication for a service in a primary site system. The reliability of a primary site system is also studied.This work was supported by the NFS grant DC1-861033. P. Jalote has a joint appointment with Institute of Advanced Computer Studies     

Distributed optimistic concurrency control with reduced rollback

Concurrency control algorithms have traditionally been based on locking and timestamp ordering mechanisms. Recently optimistic schemes have been proposed. In this paper a distributed, multi-version, optimistic concurrency control scheme is described which is particularly advantageous in a query-dominant environment. The drawbacks of the original optimistic concurrency control scheme, namely that inconsistent views may be seen by transactions (potentially causing unpredictable behavior) and that read-only transactions must be validated and may be rolled back, have been eliminated in the proposed algorithm. Read-only transactions execute in a completely asynchronous fashion and are therefore processed with very little overhead. Furthermore, the probability that read-write transactions are rolled back has been reduced by generalizing the validation algorithm. The effects of global transactions on local transaction processing are minimized. The algorithm is also free from dedlock and cascading rollback problems. Divyakant Agrawal is currently a graduate student in the Department of Computer Science at the State University of New York at Stony Brook. He received his B.E. degree from Birla Institute of Technology and Science, Pilani, India in 1980. He worked with Tata Burroughs Limited, from 1980 to 1982. He completed his M.S. degree in Computer Science from SUNY at Stony Brook in 1984. His research interests include design of algorithms for concurrent systems, optimistic protocols and distributed systems. Arthur Bernstein is a Professor of Computer Science at the State University of New York at Stony Brook. His research is concerned with the design and verification of algorithms involving asynchronous activity and with languages for expressing such algorithms. Pankaj Gupta is currently a graduate student in the Department of Computer Science at the State University of New York at Stony Brook. He received M.S. degree in Electrical Engineering from SUNY at Stony Brook in 1982 and M.S. degree in Computer Science from SUNY at Stony Brook in 1985. His research interests include distributed systems, concurrency control, and databases. Soumitra Sengupta is currently a graduate student in the Department of Computer Science at the State University of New York at Stony Brook. He received his B.E. degree from Birla Institute of Technology and Science, Pilani, India in 1980. He worked with Tata Consultancy Services, from 1980 to 1982. He completed his M.S. degree in Computer Science from SUNY at Stony Brook in 1984. His research interests include distributed algorithms, logic databases and concurrency control.This work was supported by the National Science Foundation under grant, DCR-8502161 and the Air Force Office of Scientific Research under grant AFOSR 810197     

Development of coded-cooperation based multi-relay system for cognitive radio using mathematical modeling and its performance analysis

Coded cooperation is a cooperative relaying technique which is bandwidth efficient and can provide better connectivity when used with cognitive radio. Earlier cognitive radio is implemented with cooperative schemes like decode and forward, amplify and forward, compress and forward, etc., which gives moderate spectrum efficiency and diversity with reduced fading problem of wireless communication. But these techniques are not bandwidth efficient so need huge bandwidth for transmission. In this paper, we have developed a mathematical model of new coded-cooperation based multi-relay system for cognitive radio and its outage probability is analytically derived for underlay mode. The performance analysis of proposed system is carried out in terms of interference temperature constraint, channel gain, number of relays through outage probability for single and multilink relays at the primary node for Rayleigh channel. The proposed system shows that the cognitive radio with coded cooperation outperforms the already existing techniques in terms of diversity, bandwidth, spectrum utilization efficiency and improve the communication quality. In addition, the theoretical analysis of the outage probability is validated by asymptotic analysis.     

Influence of the Nature of A Cation on Dynamics of Charge Transfer Processes in Perovskite Solar Cells

The electronic processes occurring within the perovskite solar cells (PSCs) are strongly influenced by the nature of the organic A cations present within the inorganic framework. In this study, the impact of FA (CH(NH₂)₂⁺) and Cs⁺ cations on the intrinsic and interfacial properties in the FAPbBr₃ and CsPbBr₃ PSCs is investigated. The analysis of current density ( J _SC) and photovoltage ( V _OC) as a function of illumination intensity establishes that the interfacial charge transport is more rapid in FAPbBr₃ devices. Small perturbation measurements including intensity modulated photocurrent and photovoltage spectroscopy are applied to explore the resistive and capacitive elements. Furthermore, electrochemical impedance spectroscopy measurements are found to correlate well with the photovoltaic characteristics of FAPbBr₃ and CsPbBr₃ PSCs. Overall, the in‐depth analysis of various phenomena occurring within the bromide PSCs allows to underline the working principle, which provides a key to optimize the device performance. The present protocol is not only valid for PSCs but can also be extended to devices based on alternative light harvesters.     

Measurement of O and Ti atom displacements in TiO2 during flash sintering experiments

In‐situ flash experiments on rutile TiO₂ were performed at the synchrotron at the Brookhaven National Laboratory. Pair distribution function analysis of total X‐ray scattering measurements yielded mean‐square atomic displacements of oxygen and titanium atoms during the progression of the 3 stages of flash. The displacements are measured to be far greater for oxygen atoms than for titanium atoms. These large displacements may signal an “elastic softening” of the lattice, which, recently, has been predicted as a precursor to the onset of flash.