Low‐temperature plasma processing for the enhancement of surface properties and dyeability of wool fabric

In the present investigation, wool fabric was treated with a low‐temperature air plasma. The plasma discharge power and treatment time were varied. The effect of plasma treatment on various fabric properties such as wettability, wickability, dyeability, crease recovery angle, breaking strength, and elongation at break was investigated. Surface morphology was studied using SEM micrographs. The fabric became substantially hydrophilic even with a short duration of air plasma treatment of 30 s with improvement in dye uptake and in the rate of dyeing when dyed at a lower temperature. Under these treatment conditions, aging was almost nil in a dry environment, even after 45 days, whereas some aging was observed in a humid (75% relative humidity) environment. A 20% increase in the breaking strength and 24% increase in the elongation at break were observed with reduction in wrinkle recovery angle to 133–144° from 169° for untreated fabric. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 43097.     

Effect of combining ethylene/methyl acrylate/glycidyl methacrylate terpolymer and an organoclay on the toughening of poly(lactic acid)

Blends of poly(lactic acid) (PLA) and ethylene/methyl acrylate/glycidyl methacrylate terpolymer (EMA‐GMA) with and without the addition of an organoclay were prepared by melt mixing in a twin screw extruder. Mechanical, morphological, structural, and rheological properties of the systems have been investigated as function of its compositions. The impact strength (IS) of PLA increased with the addition of EMA‐GMA. Furthermore, the addition of 2.5 wt% of organoclay to the PLA/EMA‐GMA blend promoted improvements in the mechanical properties, such as IS, tensile strength, and strain‐at‐break. Further addition of organoclay, 5 wt%, led to a formation of a double percolated network, where the clay particles form bridges across EMA‐GMA droplets and glue them together, however, without coalescence. In addition, morphological and wide‐angle X‐ray scattering analyses evidenced that the clay presents a partially exfoliated structure and that remains inside the EMA‐GMA droplets, probably as a consequence of the approach used to produce the systems. POLYM. ENG. SCI., 54:1922–1930, 2014. © 2013 Society of Plastics Engineers     

Mining the Wheat Grain Proteome

Bread wheat is the most widely cultivated crop worldwide, used in the production of food products and a feed source for animals. Selection tools that can be applied early in the breeding cycle are needed to accelerate genetic gain for increased wheat production while maintaining or improving grain quality if demand from human population growth is to be fulfilled. Proteomics screening assays of wheat flour can assist breeders to select the best performing breeding lines and discard the worst lines. In this study, we optimised a robust LC–MS shotgun quantitative proteomics method to screen thousands of wheat genotypes. Using 6 cultivars and 4 replicates, we tested 3 resuspension ratios (50, 25, and 17 µL/mg), 2 extraction buffers (with urea or guanidine-hydrochloride), 3 sets of proteases (chymotrypsin, Glu-C, and trypsin/Lys-C), and multiple LC settings. Protein identifications by LC–MS/MS were used to select the best parameters. A total 8738 wheat proteins were identified. The best method was validated on an independent set of 96 cultivars and peptides quantities were normalised using sample weights, an internal standard, and quality controls. Data mining tools found particularly useful to explore the flour proteome are presented (UniProt Retrieve/ID mapping tool, KEGG, AgriGO, REVIGO, and Pathway Tools).     

Low-Temperature Sintering of La(Ca)CrO3 Powder Prepared through the Combustion Process

Ultrafine La(Ca)CrO₃ (LCC) powder was prepared through the glycine–nitrate gel combustion process. It was shown for the first time that the use of relatively inexpensive CrO₃ as a starting material for chromium has potential for the bulk preparation of sinter-active LCC powder. As-prepared powder, when calcined at 700°C, resulted in LCC along with a small amount of CaCrO₄. The calcined powder was found to be composed of soft agglomerates with a particle size of ≈70–290 nm. The cold pressing and sintering of the calcined powder at 1200°C resulted in the mono-phasic La_0.7Ca_0.3CrO₃ with density ≈98% of its theoretical value. This is the lowest sintering temperature ever reported for La_0.7Ca_0.3CrO₃. The conductivity of the sintered La_0.7Ca_0.3CrO₃ at 1000°C was found to be ≈57 S/cm in air. The sintering and electrical behavior achieved for La_0.7Ca_0.3CrO₃ may find application as an interconnect material for high-temperature solid oxide fuel cells if problems with chemical expansion and poor conductivity in fuel can be overcome.     

Experimental and FE analysis of submerged arc weld induced residual stress and angular deformation of single and double sided fillet welded joint

Submerged arc welding is well-known for its very high deposition rate and thus the capability to join very high thickness metal pieces in large structural applications. Fillet joints are mostly used in structural applications which can be extensively seen in shipbuilding, bridge construction, house buildings, automobile or any other large structures. Thermal stresses generates in a fusion welded joint due to high temperature gradient, which is the cause of the residual stresses upon cooling followed by the angular deformation and failure of the welded structure. As an effect of the thermal gradient, the induced longitudinal, transverse residual stress & angular distortion can vary in single sided and double sided submerged arc welded fillet joints, during designing & manufacturing welded structures which should be taken into account. The main objective of this paper is to quantify the amount of residual stresses and angular deformation in a fillet welding joint. An elasto-plastic thermomechanical model has been developed for predicting residual stresses. A comparison of the residual stress and angular deformation between single and double sided fillet weld joint has been made. The simulation results reveal that the amount of residual stress present in the single sided fillet weld is more and unbalanced in both side of the center of weld line compared to the double sided fillet weld and the predicted results have been matched with the experiments as well as published literatures.     

Silicon shadow mask fabrication for patterned metal deposition with microscale dimensions using a novel corner compensation scheme

Pattern deposition of metals with controlled and microscale dimensions can be a challenging task if traditional photolithography is not a practical option. This is a particularly valid concern for the case of certain polymer substrates, which are gaining in importance in the microelectronics and related industries. Therefore, a novel design and process flow for batch fabricating low cost reusable silicon shadow masks was developed. Of note was the corner compensation scheme employed to avoid over-etching of the convex corners in the design. These shadow masks enabled deposition of metals or other suitable materials with feature sizes ranging from approximately 3 to 250 μm and were successfully utilized to form patterned metal heater lines and pads on various samples. The heaters, required for conducting thermal conductivity measurements of the underlying films/substrates using the three omega (3ω) method, showed resistance–temperature linearity, confirming theoretical estimates to within 0.2%. Moreover, the room temperature thermal conductivity of an amorphous SiO₂ film as well as a polyaniline thick film were measured, further validating the deposition through shadow mask technique.     

Effect of different polypropylenes and compatibilizers on the rheological,mechanical and morphological properties of nylon 6/PP blends

In this work, the rheological, mechanical and morphological properties of nylon 6/polypropylene compatibilized blends were investigated. Two types of polypropylene were used. One with MFI of 40 g/10 min (PP H103) and the other with MFI of 3.5 g/10 min (PP H503). The compatibilizers used were polypropylene grafted with 6% of acrylic acid (PPgAA) and polypropylene grafted with 1% of maleic anhydride (PPgMA). The blends composition was 80/20 (wt%) for the PA6/PP binary blends and 80/10/10(wt%) for the nylon 6/PPgAA/polypropylene and nylon 6/PPgMA/polypropylene ternary blends. Torque rheometry analysis showed that when PPgAA and PPgMA were added to nylon 6/polypropylene blends, there was an increase in the torque, indicating that reactive compatibilization has occurred. There is no influence of the polypropylene MFI on the mechanical properties of the uncompatibilized and compatibilized blends. The impact strength of the blends containing PPgMA were greater than those of the blends containing PPgAA. The blends containing PPgAA are unstable. SEM analysis showed that PPgMA improves considerably the adhesion between PA6/PP phases, leading to good mechanical properties.     

A two-stage framework for road extraction from high-resolution satellite images by using prominent features of impervious surfaces

The segmentation and classification of high-resolution satellite images (HRSI) are useful approaches to extract information. In recent times, roads and buildings have been classified for analysis of urban areas in a better manner. Apart from these, healthy trees are also an important factor in HRSI, i.e. adjacent to roads, and vegetation. They reflect the area in an image as land cover. Other important information, shadow, is extracted from satellite images, which indicates the presence of trees and built-up areas such as buildings, flyovers, etc. In this article, a weighted membership-function-based fuzzy c-means with spatial constraints (WMFCSC) approach for automated satellite image classification is proposed. Initially, spatially fuzzy clustering is used to classify the satellite images in healthy trees with vegetation, roads, and shadows, which includes the information of spatial constraints. The road results of the classified image are still having non-road segments. Therefore, the proposed four intermediate stages (IS) are used to extract the road information, followed by the results of road areas of the WMFCSC approach. The framework of IS helps to remove the false road segments which are adjacent to roads and renovates the segmented roads due to the shadow effect. A final step of a hybrid WMFCSC-IS approach is used to extract the road network. The results of classified images confirm the effectiveness of the WMFCSC-IS approach for satellite image classification.     

Groundwater assessment through an integrated approach using remote sensing,GIS and resistivity techniques: a case study from a hard rock terrain

Satellite data have been widely used in conjunction with Geographic Information System (GIS) techniques in groundwater resource management. Satellite data are useful for extracting various thematic maps required for groundwater assessment. In this study, Indian Remote Sensing (IRS) 1D LISS III and Landsat Thematic Mapper (TM)/Enhanced TM (ETM+) digital data, and digital elevation models (DEMs) from the Shuttle Radar Topography Mission (SRTM) along with other collateral data were analysed to create various thematic maps (geomorphology, landuse, lithology, lineament, soil, drainage density, river gradient and slope maps) required for groundwater modelling in a hard rock terrain of Bargarh district, Orissa, India. These thematic maps were assigned suitable weights and different rankings to the individual classes within each thematic map using Saaty's Analytical Hierarchy Process (AHP). A raster‐based empirical GIS model was developed for integrating the thematic maps to locate suitable groundwater prospective zones. The integrated thematic maps were in turn used to compute the Groundwater Potential Index (GWPI). GWPI values calculated in the study area were found to vary from 0.175 to 0.940. These GWPI values have been classified into various classes: very poor (<0.4), poor (0.4–0.5), moderate (0.5–0.6), good (0.6–0.7), very good (0.7–0.8) and excellent (>0.8). A final map showing very poor to excellent groundwater prospective zones was prepared. The results thus obtained were subsequently cross‐checked with resistivity survey and pumping test data. Very poor GWPI zones show low yields of 0.5 lps from weathered granite of resistivity 20–100 Ω m and thickness 0.5–6 m, while excellent GWPI zones show high yields of 5–7 lps from highly fractured granite of resistivity 100–300 Ω m and thickness 14–31 m. The results obtained from integration of the various thematic maps on the GIS platform produced a good match with the resistivity and pumping test data.