Development of Low-Oxide MCrAlY Coatings for Gas Turbine Applications

Advanced high-energy plasma systems are being used to achieve the benefits of the high-velocity oxy-fuel (HVOF) system without losing the inherent advantages of plasma for coating of gas turbine parts. MCrAlY coatings play a very important role in the performance and reliability of gas turbine components. One of the important considerations for next generation of gas turbines, which have more demanding conditions and need to withstand ever increasing operating temperatures, is that they should possess very low oxygen content levels in the coating. Low oxygen content coatings are applied by the expensive low-pressure plasma spray (LPPS)/vacuum plasma spray (VPS) technique for critical components in aero- and land-based gas turbines. This work deals with the development of low-cost LPPS equivalent coatings (having low oxygen content) using the high-energy high-velocity plasma spray (HEHVPS) gun and inert gas shroud. A comparison has also been made with CoNiCrAlY coatings by HVOF.     

An investigation of phase transformation behavior in sputter-deposited PtMn thin films

Sputter-deposited, equiatomic PtMn thin films have application in giant magnetoresistive spin valves, tunneling magnetoresistive spin valves, and magnetic random access memory. However, the as-deposited films are found to be a disordered A1 phase in a paramagnetic state rather than an antiferromagnetic phase with L1₀ structure, which is needed for device operation. Therefore, a postannealing step is required to induce the phase transformation from the asdeposited A1 face-centered-cubic phase to the antiferromagnetic L1₀ phase. The A1 to L1₀ metastable transformation was studied by x-ray diffraction and differential-scanning calorimetry. An exothermic transformation enthalpy of −12.1 kJ/mol of atoms was determined. The transformation kinetics were simulated using the Johnson-Mehl-Avrami analysis.     

Refurbishment and safety upgradation of research reactor Cirus

Cirus, a 40 MW t, vertical tank type research reactor, having wide range of research facilities, was commissioned in the year 1960. This research reactor, situated at Mumbai, India has been operated and utilized extensively for isotope production, material testing and neutron beam research for nearly four decades. With a view to assess the residual life of the reactor, detailed ageing studies were carried out during the early 1990s. Based on these studies, refurbishment of Cirus for its life extension was taken up. During refurbishment, additional safety features were incorporated in various systems to qualify them for the current safety standards. This paper gives the details of the operating experiences, utilization of the reactor along with methodologies followed for carrying out detailed ageing studies, refurbishment and safety upgradation for its life extension.     

Nerve conduction velocity and H-reflex recovery in bipolar illness

Bipolar illness may be characterized by dysregulation and dysfunction of biologically active ions and ion pumps, respectively. In an effort to examine whether purported physiologic abnormalities may have functional counterparts, nerve conduction velocities (NCVs) and H-reflex recovery were examined in 7 acutely manic, 11 euthymic bipolar, 13 remitted schizophrenic, and 6 normal control individuals. All electrophysiologic tests were clinically normal. However, euthymic bipolar patients had significantly slower NCVs than either manic or normal individuals. Percent decrement of H-reflex recovery was nonsignificantly increased in manic versus euthymic bipolar subjects. Data analysis suggests lithium was not responsible for these changes. These data indicate that different mood states in bipolar illness are associated with alterations in electroneurophysiologic function.     

A new nitrogen alloying technique - a way to distinctly improve the properties of austenitic steel

The paper presents a new process for nitrogen alloying austenitic steels beyond solubility limit in a pressurized electroslag remelting furnace using Si₃N₄ as nitrogen source. With the aid of this process it is possible to attain nitrogen percentages far beyond the solubility limit at atmospheric pressure. These high nitrogen contents impart a distinct improvement to the properties of the material. Yield strengths R_p0.2>600 N/mm² at ambient temperature are achieved. The high tensile values are attributable to the lattice expanding effect of force-dissolved nitrogen. A reduction in forming characteristics A₅ and Z normally associated with a distinct increase in tensile strength is not noticeable. The tests at ambient temperature have further shown that nitrogen alloyed steels display high fatigue strength values. If results of the fatigue tests are evaluated on the basis of the empirical relation 0.30 < σ_zdw/R_m<0.45 it is found that the values of the steels tested are generally at the upper limit of this value or even above it. The very good creep test results of nitrogen alloyed steels deserve emphasis. Up to 800°C they are comparable to the creep values of high temperature alloys. This is attributable to the precipitation behaviour of the steels caused by the presence of nitrogen. Embrittlement occurs only to a very small extent and precipitates, in particular Cr₂N, enhance creep resistance owing to their favourable arrangement. The new technique of nitrogen alloying beyond the solubility limit opens up favourable opportunities for nitrogen alloyed austenitic steels in new applications. This development offers further advantages in that considerable savings in nickel as an alloying element can be made and that material can be much better utilized in the design of components.     

干性含颗粒气体介质旋转轴——凸轮粉碎机轴端密封的设计

本文介绍了一种在干燥、含固体颗粒气体介质条件下旋转轴密封的新设计。经实践证明:该密封用于转速在960r/min以上、介质压力为0～4.9kPa时,效果较理想。     

Fabrication of highly porous poly (ε-caprolactone) microfibers via electrospinning

Highly porous Poly (ε-caprolactone; PCL) microfibers were successfully fabricated by collecting the fibers into a water bath during electrospinning. The morphology of the fibers collected with and without the water bath was investigated. We observed that altering the pH of the water bath affected both the fiber diameter and the size of pores on the fibers. Acidic or basic condition was found to be more favorable than neutral conditions for the formation of well-porous fibers. The morphology and pore size of the microfibers were characterized by scanning electron microscopy (SEM) and atomic force microscopy (AFM). The average diameter of the fibers and the pore size on the surface of the microfibers were found to be 12–14.5 and 0.3–0.7 μm, respectively. The crystallinity and thermal properties of the PCL mats were investigated by DSC. This highly porous nature of the microfibers makes PCL less crystalline and increases the surface to volume ratio of the mat. Therefore, the PCL mat obtained by water bath electrospinning may be more effective for tissue scaffolds and drug delivery than the mat obtained without water bath.