Compassion Practicum: A Capstone Design Experience at the United States Military Academy

A partnership has been developed linking the United States Military Academy and Special People in the Northeast, a non-profit agency for the mentally and physically handicapped children and adults based in Philadelphia. The present work documents a student design team's design and construction of a ticket-tearing device for a young man in the advanced stages of cerebral palsy and concludes with an evaluation of the entire process.     

Mechanism and kinetics of the free radical ring-opening polymerization of cyclic allylic sulfide lactones

The polymerization of 7-, 8- and 11-membered lactones, 6-methylene-1,4-oxathiepan-7-one, 3-methylene-1,5-oxathiocan-2-one and 3-methylene-1-oxa-5-thiacycloundecan-2-one in benzene at 70, 40–70 and 40–65 °C, respectively, is presented. All polymerizations proceeded with complete ring-opening up to approximately 25% conversion, where insoluble polymer was formed. Evidence is given attributing polymer double bond loss to crosslinking, although redistribution of the molecular weights via addition to polymer double bonds followed by β-fragmentation also appears to occur for polymerizations of the 8- and 11-membered lactones. Michael adducts of lactones with 2-methyl-2-propanethiol were prepared as models for chain-transfer products of hydrogen abstraction by carbon-centred radicals. Polymerization rates were found to increase marginally with ring size. Arrhenius parameters obtained for the polymerizations of the 8- and 11-membered lactones indicated that the addition step was more important than fragmentation in determining the rate of propagation.     

Modeling and forecasting the U.S. manufacturing aggregate energy intensity

Two forecasting models are developed for forecasting the U.S. manufacturing aggregate fuel and electricity intensities. The models are both simple to apply and capable of identifying the effect of underlying forces of aggregate energy intensity change. The validation of the results provided by these models is performed by comparing these results with those rendered by conventional decomposition techniques based on economic index numbers. The results indicate that the aggregate fuel intensity is expected to decline by 3.2%yr^?1 from the year 2000 to 2010, of which 1.1%yr^?1 is due to structural effect, i.e. a share of 32.9% of aggregate fuel intensity change. The results also show that in the same period the aggregate electricity intensity is expected to decline at a rate of 1.2%yr^?1, of which 0.6%yr^?1 is due to structural effect, i.e. a share of 46.3% of aggregate electricity intensity change. Copyright © 2007 John Wiley & Sons, Ltd.     

A One-Dimensional Model for Particulate Deposition and Hydrocarbon Condensation in Exhaust Gas Recirculation Coolers

Cooled exhaust gas recirculation (EGR) is widely used in diesel engines to control engine out NO_x (oxides of nitrogen) emissions. A portion of the exhaust gases is recirculated into the intake manifold of the engine after cooling it through a heat exchanger. EGR cooler heat exchangers, however, tend to lose efficiency and have increased pressure drop as deposit forms on the heat exchanger surface. This adversely affects the combustion process, engine durability, and emissions. In this study, a 1-D model was developed to simulate soot deposition, soot removal, and condensation of several hydrocarbon (HC) species in a circular tube with turbulent gas flow at constant wall temperature. The circular tube, which makes up the computational domain in the model, represents a single channel from any EGR cooler geometry. The model takes into account soot particle deposition due to thermophoresis, diffusion, turbulent impaction, and gravitational drift. However, thermophoresis was found to be the most dominant deposition mechanism for boundary conditions at which EGR coolers typically operate. Soot removal was modeled by considering a force balance between the drag and van der Waals forces. A lognormal distribution of particles was assumed at the tube inlet. The evolution of the particle distribution in the bulk flow along the tube as well as the mass distribution in the deposit layer on the tube walls is predicted by the model. Condensation of six HC species between C₁₅-C₂₄ alkanes was also modeled. Predictions made by the model are in reasonably good agreement with experimental data obtained from a laboratory reactor under the same boundary conditions. There are several assumptions and simplifications built into the model, which can be refined further to improve it.

Copyright 2012 American Association for Aerosol Research     

Prospects for solar cooling – An economic and environmental assessment

Producing refrigeration and/or air conditioning from solar energy remains an inviting prospect, given that a typical building’s cooling load peaks within 2 or 3 h of the time of maximum solar irradiation. The attractiveness of “free” cooling obtained from the sun has spawned a wealth of research over the last several decades, as summarized in a number of review articles. Obstacles—especially high initial costs—remain to the widespread commercialization of solar cooling technologies. It is not clear at the present time if thermally driven systems will prove to be more competitive than electrically driven systems. We therefore describe a technical and economic comparison of existing solar cooling approaches, including both thermally and electrically driven. We compare the initial costs of each technology, including projections about future costs of solar electric and solar thermal systems. Additionally we include estimates of the environmental impacts of the key components in each solar cooling system presented. One measure of particular importance for social acceptance of solar cooling technologies is the required “footprint,” or collector area, necessary for a given cooling capacity. We conclude with recommendations for future research and development to stimulate broader acceptance of solar cooling. The projections made show that solar electric cooling will require the lowest capital investment in 2030 due to the high COPs of vapor compression refrigeration and strong cost reduction targets for PV technology.     

Disorders of adult attachment.

This article presents an overview of J. Bowlby's framework of attachment (e.g., 1990) for conceptualizing adult psychopathology and its application to clinical practice. The theory proposes that psychological disorders reflect an internalization of adverse attachment experiences, both current and past, and in particular those that undermine self-reliance and feelings of security. Clinical syndromes indicate intensification of anxiety, depression, and/or anger to a degree which interferes with adaptive functioning and interactions with others. The secure base of therapy provides a new model of what close relationships can be like, as well as a setting for exploring and possibly modifying the meaning given to separation and loss experiences. Issues of prevention and social policy are also discussed. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Energy conservation in compressed‐air systems

In this paper, we evaluate and quantify the energy losses associated with compressed‐air systems, and their costs to manufacturers. We also show how to reduce the cost of compressed air in existing facilities by making some modifications with attractive payback periods. Among the measures, we investigate to reduce the compressed air are: (1) repairing air leaks, (2) installing high‐efficiency motors, (3) reducing the average air inlet temperature by using outside air (4) reducing compressor air pressure. We also illustrate the potential saving associated with each measure by using realistic examples. Copyright © 2002 John Wiley & Sons, Ltd.     

Attachment, detachment and borderline personality disorder.

In an attempt to expand understanding of more severe pathology, attachment theory, developed by John Bowlby, is applied to borderline personality disorder in adults. Conceptualized as a condition of profound insecure attachment, with extreme vacillations between a desire for proximity and attachment and a dread and avoidance of engagement, borderline pathology reflects traumatic attachment experiences, beginning early in life. Besides the importance of trauma, disturbances in affect regulation and cognitive distortions are emphasized. The secure base of a therapeutic bond provides consistency, reliability, and affirmation while encouraging exploration of separation and loss experiences, both current and past, in order to modify inner working models of oneself and relationships with others. Implications for prevention are discussed. (PsycINFO Database Record (c) 2010 APA, all rights reserved)