A system for the analysis of fire reports, and its application to health care buildings

A system of analysing fire reports is described, which evaluates the success of failure of the building elements and occupants in mitigating the consequencies of ignition. To handle fire reports a method of categorising the fire growth sequence in terms of both flame and smoke spread was developed. Three tactics (ignition prevention, fire control and evacuation) which mitigate the consequencies of ignition were derived from a hierarchy of fire safety and their interrelationship was examined. The application of this analysis method to two sets of the reports of fires in health buildings was undertaken and its success validated the proposed methodology.     

A kinetic investigation into the removal of carbobenzyloxy group from protected amines via hydrogenolysis reaction

Hydrogenolysis of a carbobenzyloxy group (CBz) was studied utilizing molecular hydrogen in the presence of carbon-supported palladium catalyst. It was demonstrated that the kinetics of the reaction are greatly influenced by the presence of the CO₂ by-product. It was found out that the presence of CO₂ determines whether the reaction is first or zero order since it causes deactivation of the catalyst via inhibition. The effect of potassium carbonate (K₂CO₃) and triethylamine (TEA) as additives was investigated. A considerable solvent effect was also observed that may be explained by the variation of dispersion of the catalyst from one solvent to another.     

Traffic officers'' attitudes toward blood alcohol law enforcement

Research findings in other countries suggest that drinking driving laws could be much better enforced even without resorting to special patrols or random checks. It has been reported that law enforcement officers apprehend or breath test only a small fraction of the potentially impaired drivers that they normally encounter on patrol. This survey of New Zealand traffic officers was designed to determine the extent to which this was the case here, and what were the major disincentives to breath testing. Traffic officer responses, obtained on an anonymous questionnaire, suggested that there were not so many missed opportunities as had been suggested by others, but that there was a great deal of variability in the number of drinking drivers detected by different officers. This was confirmed by the actual distribution of breath testing activity, which was markedly different in shape (positively skewed) compared to the distribution of traffic enforcement activities in general. Several clues from the disincentives cited on the questionaire suggested that there are major deterrents to a greater degree of alcohol enforcement activity on the part of most officers. These are discussed in terms of potential legislative changes, and in relation to the changes introduced in the 1978 Transport Act Amendment.     

Behavioural research in telematics.

Discusses telematics, a new field of behavioral research in Canada that has grown with the technical developments in which computers and telecommunications have been combined. Three domains of behavioral research reflect relationships between humans and the technology and use the evidence and methods of different areas of psychology: (1) interface studies address perception and performance questions, (2) dialog studies focus on cognitive processes, and (3) impact studies investigate social relations and how institutions and individuals are affected by telematics. Studies conducted during the past 5 yrs by the Behavioural Research and Evaluation division of the Department of Communications, Government of Canada, are described in each of these 3 domains. Behavioral research in telematics is expected to be an increasingly important activity in which psychologists may play an active part as the technology disseminates. (French abstract) (47 ref) (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Phase behavior of polycarbonate blends with selected halogenated polymers

Bisphenol A polycarbonate is shown to be miscible with a vinylidene chloride based polymer containing 13.5% by weight of vinyl chloride. On the other hand, polycarbonate is found to be immiscible with poly(vinyl chloride), poly(vinylidene fluoride), and polyepichlorohydrin.     

Increasing Reliability in Cable-Free Radio LANs Low Level Forwarding in HIPERLAN

Radio LANs are emerging in the computing world. They are supported by distinct configurations: on the one hand radio LANs with base stations and a wired backbone, on the other hand radio LANs implementing Intra-forwarding. Adding a new node in a radio LAN with Intra-forwarding, increases the reliability, while this reliability decreases with ad hoc or hub configurations. This advantage of Intra-forwarding is quantified. Intra-forwarding, as defined in the HIPERLAN standard, is based on a hop-by-hop policy and link check procedures. It is shown how point-to-point packets and broadcast packets are forwarded. The three basic components of Intra-forwarding needed to build and update the Intra-forwarding database are described. The originality of this approach is the use of multipoint relays which enable better scalability. The correctness of the Intra-forwarding protocol is proved and its cost is evaluated.     

Nonepitaxial Orientation in Sol–Gel Bismuth Titanate Films

Control over crystallographic orientation in ceramic thin films is important for highly anisotropic structures. Layered perovskites, like Bi₄Ti₃O₁₂, have interesting properties associated with their ferroelectric nature, which may be fully exploited only when films are highly textured. Textured films of this titanate were fabricated via a sol–gel technique without using epitaxial growth. Orientation in the film is confirmed by XRD and SEM, and supported by refractive index and dielectric measurements. In an attempt to explain the orienting effect, light scattering experiments were conducted to yield information about the molecular size, shape, and conformation of macromolecules as the sol–gel solution ages and condensation reactions proceed. These experiments clearly show an increase in the size of molecular clusters with time. We believe that it is the organization of these large clusters during spin coating, and the relationship of the backbone chemistry to the crystal structure of Bi₄Ti₃O₁₂, that are responsible for the observed orientation.     

Phase stability of ternary blends

The phase behavior of ternary blends of tetramethyl polycarbonate (TMPC), polycarbonate (PC), and styrenic polymers has been examined by experiment and analyzed in terms of thermodynamic theories. The phase boundaries were predicted using both the modified Flory-Huggins theory and the lattice fluid theory. The boundaries predicted using the lattice fluid theory agree best with the experimental results. The experimental phase behavior of ternary blends was compared with binary blends having exactly the same chemical components and compositions except that the TMPC and PC units were present in the form of a copolycarbonate in the binary. The miscible region of these ternary blends is much narrower than that of the corresponding binary blends, even though the entropic and energetic terms of such ternary blends are more favorable than those of the binary blends. It is shown that a negative value of noncombinatorial free energy in multicomponent systems is not a sufficient condition for miscibility, because of asymmetries of mer-mer interactions. A comparison of the stability conditions for these binary and ternary blends shows that increasing the degrees of freedom tends to destabilize the mixture.