Kinetic study of the hydrolysis of isocyanic acid in the gas phase

The hydrolysis of isocyanic acid in the gaseous phase has been investigated at temperatures between 553 and 613 K by mass spectrometry and evaluated to obtain the corresponding kinetic data. The reaction order and reaction constant have been determined. Finally, the influence of water on the catalysed formation of melamine from isocyanic acid under the operating conditions employed has been investigated in order to determine whether there is a need to try the process gas.     

Graphite formation on Ni film by chemical vapor deposition

Thin film formation of graphite by chemical vapor deposition using 2-methyl-1,2′-naphthyl ketone as a starting material was carried out on Ni film substrates. On Ni films directly deposited on quartz glass, the graphite films were obtained when the Ni film thickness was above 1 000 Å and above 5 000 Å at 700 °C and 1 000 °C, respectively. Depositions on thinner Ni film substrates comprise amorphous carbon (a-C) or graphite tubes which was owing to the thermal coagulation of the Ni film into droplets. On the other hand, graphite film was obtained on the Ni film with thickness 10 Å when a-C was inserted between the Ni film and the quartz glass. The coagulation of the Ni film is considered to be avoided by inserting a-C layer.     

A numerical model for the dissolution of spherical particles in binary alloys under mixed mode control

A general numerical model is described for the dissolution kinetics of spherical particles in binary systems for any combination of first order reactions at the particle-matrix interface and long distance diffusion within the matrix. The model is applicable to both finite and infinite media and handles both complete and partial particle dissolution. It is shown that interfacial reactions can have a strong effect on the dissolution kinetics, the solute concentration at the particle-matrix interface and the solute concentration profile in the matrix.     

集成对数放大器

对数放大器由于其特殊的性能而在雷达接收机，通信、遥控和激光测距系统中具有十分广泛的用途。详细叙述了对数放大器的性能，特性，介绍了几种主要的对数放大器类型及其工作原理，考查了国外对数放大器的发展情况，介绍了国内集成对数放大器的主要性能指标及其用途。。     

SOI全介质隔离与高频互补双极兼容工艺

ＳＯＩ材料的全介质隔离技术与高频互补双极工艺的结合是研制抗辐照能力强、频带宽、速度高的集成运算放大器的理想途径，从实验的角度提出了一种ＳＯＩ材料全介质隔离与高频互补双极工艺兼容的工艺途径。     

超薄SiO2层的热生长

隧道小孔中超薄ＳｉＯ２的生长是ＥＥＰＲＯＭ电路制造的关键工艺之一。采用ＳＵＰＲＥＭ－Ⅲ工艺模拟程序对超薄ＳｉＯ２的热生长进行了工艺模拟，经过大量的工艺实验及优化，确定了超薄ＳｉＯ２的最佳生长条件，生长出的ＳｉＯ２性能良好，完全可满足ＥＥＰＲＯＭ研制的要求。     

差分式连续时间电流型CMOS跨导—电容低通滤波器

应用信号流图法对电流系统传递函数直接模拟，提出了一种新颖的差分式连续时间电流模式ＣＭＯＳ跨导－电容低通滤波器的实现方案。由于采用了差分式结构和电流负反馈，整个电路方案具有差分式结构和电流型电路的优点；并且仅使用最少数量的ＯＴＡ和电容，与数字ＣＭＯＳ工艺兼容，适于全集成。面向实际电路完成了ＭＯＳ管级的计算机仿真，结果表明，所提出的电路方案正确有效     

Recrystallization/precipitation behaviour in microalloyed steels

Microalloyed high-strength low-alloy (HSLA) steels contain additions of Nb, V, Ti, or in combination, in amounts of 0.01 to 0.1 weight percent to improve mechanical properties, which are strongly dependent on the thermomechanical interaction taking place in the course of rolling mill processes. The recrystallizatian of hat-twisted austenite has been investigated in a cylindrical specimen (f 6×50 mm) machined from hat rolled plates of 0,052 wt % Niobium microalloyed steel. Continuous and interrupted torsion test were carried out in the temperature range 1123 K to 1173 K after a solution treatment of 1.5 minutes at 1423 K and torque-twist data were analysed. The various methods were discussed for obtaining results from torsion tests. The effect of precipitation kinetics was appreciated by way of connection t_p/t_p(red), where t_p is the experimental measured time for the peak stress and t_p(red) is the newly defined reduced time. The softening ratio X and time t_0.05R for start of static recrystallization were established.

The correlation between precipitation and recrystallization is presented as a graphs for chosen requirements (temperature of austenitization, carbon and niobium content and strain rate). If temperature goes below 850°C, the restoration processes are hardly suppressed, both are limited by diffusion and Nb(CN) precipitation, which are extended dynamically in the range of strains rates 10⁻² to 1 s⁻¹.

In the present paper, an attempt is made to derive the PRTT diagram and to define all mathematical equations for describing recrystallization times t_0.05R, t_0.5R, t_0.95R and t_0.05P for the start of precipitation. In real metal forming processes such as the hot rolling of plates or strips the knowledge of these parameters and results is extremely important for the the correct microstructure and sheet quality to be obtained.     

Experimental determination of thermal conductivity of apple and potato at different moisture contents

Thermal conductivity of apple and potato samples was measured by means of a specifically designed apparatus based on Fitch's method. The thermal conductivity was determined at various moisture contents at the sample mean temperature of 30 °C. As expected the conductivity decreases with the decrease in moisture content. Thermal conductivity data were correlated with moisture content using a straight line.