Influence of nitrogen hetero-substitution on the electrochemical performance of coal-based activated carbons measured in non-aqueous electrolyte

Nitrogen-containing carbons were prepared by modification of activated carbons. The modified carbons were used as electrode materials with improved electrochemical performance. Precursor anthracite was activated by KOH (KOH: anthracite= 1:1), modified by melamine or urea and then treated at 1173 K to obtain the modified carbons. The porous structure, the chemical composition and the electrochemical characteristics of the carbons were investigated by nitrogen sorption, XPS and electrochemical methods respectively. Electrochemical experiments were performed in an organic electrolytic solution of 1 M (C2H5)4NBF4/PC.The samples modified by the different methods showed differences in chemical composition that introduced varying degrees of electrochemical performance enhancement. The presence of nitrogen enhanced the electron donor properties and the surface wettability of the activated carbons: this ensured a sufficient utilization of the exposed surface for charge storage.     

Bezier三角曲面凸性的证明

Bezier曲面造型是计算机图形学的重要研究方向,在实际工作中有着非常广泛的应用.讨论了二次及三次Bezier三角曲面凸性的充分必要条件,这些条件对于控制曲面造型中的保凸性有重要意义.     

论宫本百合子的女性自立意识——以《伸子》为例

《伸子》是以宫本百合子自身的美国留学经历为题材,描写了她自己从恋爱、结婚到离婚经历的自传性小说,被宫本百合子称作"自身的古典"。在这部小说中,伸子与母亲、伸子与丈夫佃、伸子与素子等人的关系错综交织在其中。而伸子真正的成长以及自立意识的深化,也就是在处理与这些人物关系过程中成立的。从三类人物关系着手,探寻其中伸子对自立,特别是精神自立的追求。在此基础上,从《伸子》的自传性出发,揭示了主人公和作者思想构造的内容。     

酶法制备鲍鱼脏器呈味肽及呈味氨基酸

研究了酶法制备鲍鱼脏器呈味肽及呈味氨基酸的最佳条件.鲍鱼脏器分别经中性蛋白酶、木瓜蛋白酶和胰蛋白酶水解,中性蛋白酶酶解产物的水解度和肽得率最大,鲜味氨基酸含量最高且口味最好.以中性蛋白酶为工具酶,通过单因素试验和响应面分析确定了酶解的最佳条件:酶加量3 000 U/g,温度46℃,pH 7.8,时间3 h,底物质量分数...     

水分胁迫下高羊茅幼苗的生理适应性

采用不同浓度PEG6000模拟水分胁迫处理6种高羊茅幼苗,测定了胁迫72 h后叶片叶绿素含量、相对电导率、丙二醛含量、超氧化物歧化酶和过氧化物酶活性等抗旱指标,以综合评价6种高羊茅的抗旱能力。综合分析可知,6种高羊茅的苗期抗旱能力最强的是阳光宝贝。     

Turbo码在水声OFDM通信中的应用研究

为了增强高速水声通信中信息传输的可靠性,采用了性能优越的Turbo码和OFDM相结合的方法,并与传统的卷积码进行了性能比较.仿真结果表明,在水声通信可以接受的信噪比范围内,采用Turbo码的误码性能明显优于无信道编码和卷积编码;在带宽利用率相同时使用该方案的水声通信系统性能优于无信道编码和卷积码.因此,把Turbo码与OFDM相结合的传输体制可以明显提高水声通信系统的传输速率和可靠性,从而在水声通信中具有良好的应用前景.     

Linux平台下网络入侵防御系统的研究与实现

针对防火墙和入侵检测系统在网络安全防御上存在的缺陷,本文提出了一个在Linux平台下,基于两层防御机制的网络入侵防御系统．该系统扩展了网关防火墙的入侵检测功能．实现了网关防火墙对攻击的最初防御,增加了入侵检测系统Snort的联动响应功能,Snort对逃避了网关防火墙检测的复杂攻击进行再次防御．实验结果证明,两层防御机制对大规模的蠕虫攻击起到了实时抵制作用．     

动态网络中的高效多故障诊断技术

针对已有算法复杂度较高,不适用于规模较大网络的问题,将被管系统建立成动态贝叶斯模型,并提出一种能处理多故障的近似推理算法. 通过复杂度分析,证明该近似算法时间复杂度为多项式级,远远低于精确算法的时间复杂度下限,可以用于解决大规模动态网络的故障诊断问题. 实验结果证明,新算法在准确度方面虽然略低于精确算法,但执行效率上远远高于精确算法.     

Experimental study on temperature stress calculation and temperature control optimization of concrete based on early age parameters

Temperature control curve is the key to achieving temperature control and crack prevention of high concrete dam during construction,and its rationality depends on the accurate measurement of temperature stress.With the simulation testing machine for the temperature stress,in the present study,we carried out the deformation process tests of concrete under three temperature curves：convex,straight and concave.Besides,we not only measured the early-age elastic modulus,creep parameters and stress process,but also proposed the preferred type.The results show that at early age,higher temperature always leads to greater elastic modulus and smaller creep.However,the traditional indoor experiments have underestimated the elastic modulus and creep development at early age,which makes the calculated value of temperature stress too small,thus increasing the cracking risk.In this study,the stress values of the three curves calculated based on the strain and early-age parameters are in good agreement with the temperature stress measured by the temperature stress testing machine,which verifies the method accuracy.When the temperature changes along the concave curve,the law of stress development is in consistent with that of strength.Under this condition,the stress fluctuation is small and the crack prevention safety of the concave type is higher,so the concave type is better.The test results provide a reliable basis and support for temperature control curve design and optimization of concrete dams.     

气候变化背景下流域生态需水预估−以好溪流域为例

为探究未来气候变化对流域生态需水量的影响,保障河流生态需水量,针对好溪流域进行生态需水量计算 及预测。基于好溪流域气象数据及下垫面条件建立流域生态需水模型,并根据 GF1-WFV 遥感影像数据订正后的 地表反射率和作物种植结构提升模型模拟精度。选择 CanESM2气候模式下的 RCP2.6、RCP4.5 和 RCP8.5 这 3 种 排放情景,建立气候变化背景下流域生态需水预测方法,计算现状年并预测未来年份的生态需水量及生态需水保 障程度。结果表明,基于光学遥感影像进行数据订正后,模型模拟精度有所提升,率定期的模型精度 R2从 0.80 提 升为 0.85,验证期的 R2从 0.75 提升至 0.78。应用提升精度后的模型进行生态需水预测,在 RCP2.6、RCP4.5 和 RCP8.5 情景下,2025—2100 年的年均生态需水分别增加了 0.27 亿、0.21 亿和 0.29 亿 m3,其中 RCP8.5 情景下生态 需水保障程度最高,RCP4.5 情景下生态需水保障程度最低。